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Safety Data Sheet EN

Carbonyl chloride

CAS 75-44-5
EC 200-870-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Carbonyl chloride
Product Code
2500, 702500
Chemical Name
carbonyl chloride

Regulatory Identifiers

CAS Number
75-44-5 Check regulations →
EC Number
200-870-3 Check regulations →
REACH No.
01-2119946799-13

Identified Uses

Basic substance. Intermediate.

Manufacturers & Suppliers

GHC Gerling, Holz & Co. Handels GmbH logo

GHC Gerling, Holz & Co. Handels GmbH

manufacturer

Ruhrstraße 113, D-22761 Hamburg

+49 40 853 123-0

http://www.ghc.com

Emergency Contacts

Giftinformationszentrum (Poison Control Centre) Mainz

+49 6131 19240

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Press. Gas (Liq.) H280
Acute Tox. Cat. 1 H330
Skin Corr. Cat. 1B H314

GHS Pictograms

GHS04 - Compressed gas

GHS04

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H280 Contains gas under pressure; may explode if heated.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.

Precautionary Statements

P260 Do not breathe gas/vapours.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P315 Get immediate medical advice/attention.
P403 Store in a well-ventilated place.
P405 Store locked up.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Content: >= 98,5 %

Chemical Name CAS Number Concentration Hazardous
carbonyl chloride EC: 200-870-3 75-44-5 98.5% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the casualty into fresh air and keep him immobile. In case of breathing difficulties give oxygen. In the event of pulmonary irritation treat initially with corticoid spray, e.g. Ventolair- or Pulmicort- metered-dose aerosol. Seek medical treatment immediately. In case of respiratory standstill give artificial respiration by respiratory bag (Ambu bag) or respirator. Send for a doctor.

Symptoms: Respiratory tract irritation, coughing, shortness of breath.

Skin contact

In case of contact with skin wash off immediately with soap and water. In case of frostbite spray with lukewarm (not hot) water for at least 15 minutes. Do not remove clothing frozen to the skin. Thaw it with lukewarm water. Apply a sterile dressing. Obtain medical assistance. Seek medical treatment immediately.

Symptoms: Contact with liquid may cause cold burns/frostbite.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call for a doctor immediately.

Symptoms: Strong eye irritation.

Ingestion

Ingestion is not considered a potential route of exposure.

Immediate Medical Attention

If necessary, give oxygen. Pulmonary oedema prophylaxis. Monitor circulation.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Product does not burn, fire-extinguishing activities according to surrounding. Foam, Dry powder, Carbon dioxide, Water spray jet.

Unsuitable media

Full water jet

Specific hazards

In the event of fire the following can be released: Carbon monoxide (CO), Carbon dioxide (CO2), Hydrogen chloride (HCl), Chlorine (Cl2)

Firefighter Protection

Use breathing apparatus with independent air supply (isolated). Wear full protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate area. Keep people away and stay on the upwind side. Remove persons to safety.

Environmental

Collect contaminated water / firefighting water separately. Prevent spread over a wide area (e.g. by containment or oil barriers).

Cleanup methods

Clean contaminated objects and floor thoroughly under consideration of environment regulations.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only in thoroughly ventilated areas. Transfer and handle only in enclosed systems. Containers' temperature may not be increased above 50 °C. Do not heat with open flames. The working pressure in the receptacle must not exceed the saturation vapour pressure of the pure product resulting at a temperature of 50 °C. Provide good room ventilation even at ground level (vapours are heavier than air). Prevent cylinders from falling over. Ensure valve outlet cap nut or plug is correctly fitted. Ensure valve protection device is correctly fitted. Open valve slowly to avoid pressure shock. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Do not allow backfeed into the container. Suck back of water into the container must be prevented. No water to valves, flanges and other fittings. Purging of pipes and valves with inert gases - to avoid: water, solvents.

Storage

Keep container tightly closed and store at cool and aired place. Protect from heat/overheating. Prevent cylinders from falling over. Ensure valve protection device is correctly fitted.

Hygiene

At work do not eat, drink, smoke or take drugs. Wash hands before breaks and after work.

Fire prevention

Pay attention to general rules of internal fire prevention. Avoid effect of heat. Do not heat with open flames.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Transfer and handle only in enclosed systems.

Hands

Laminated gloves - PE / EVAL / PE. Leather gloves. Safety gloves according to EN 374.

Eyes

Protective goggles according to EN 166, in case of increased risk add protective face shield.

Respiratory

Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be safe. Keep self contained breathing apparatus readily available for emergency use. Short term: filter apparatus, Filter B. Respiratory protection complying with EN 137.

Skin/Body

Safety shoes with steel toe. Body covering work clothing, or chemical resistant suit at increased risk.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Gaseous / liquefied under pressure.
Physical State Data
gas
State Under Standard Conditions
---
Appearance
Gaseous / liquefied under pressure.
Colour
colourless
Colour Intensity
---
Form
---
Odor
pungent
Odor Threshold
not determined
Ph
not applicable
Melting Point
-127,8 ℃
Boiling Point
7,56 °C
Flash Point
no
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
not applicable
Vapor Pressure
1586 hPa
Vapor Density
---
Relative Density
1,403 g/cm3
Bulk Density
---
Density
---
Flammability
no
Upper Explosive Limit
no
Lower Explosive Limit
no
Explosive Limits
---
Auto Ignition Temperature
no
Decomposition Temperature
>200 °℃
Solubility
soluble in organic solvent
Partition Coefficient
not applicable
Solubility In Water
hydrolyses
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

12.1. Toxicity | Ecotoxicological effects | Value | Species | Method | Validation | | --- | --- | --- | --- | --- | | Fish | | | | Study technically not feasible. | | Daphnia | | | | Study technically not feasible. | | Algae | | | | Study technically not feasible. | | Bacteria | | | | Study technically not feasible. |

12.2. Persistence and degradability

12.2. Persistence and degradability | Elimination rate | Method of analysis | Method | Validation | | --- | --- | --- | --- | | Biological degradability | | | Study technically not feasible. |

Study technically not feasible.

12.3. Bioaccumulative potential

Not known.

Not known.

12.4. Mobility in soil

not determined

12.5. Results of PBT and vPvB assessment

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

The substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

12.6. Other adverse effects

Not known.

No adverse effects are known.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1076
Shipping Name
PHOSGENE
Transport Class
2.3 (8)
ADR

The protective measures listed in Sections 6, 7 and 8 of the Safety Data Sheet have to be considered.

IMDG

The protective measures listed in Sections 6, 7 and 8 of the Safety Data Sheet have to be considered.

IATA

The protective measures listed in Sections 6, 7 and 8 of the Safety Data Sheet have to be considered.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH)

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Carbonyl chloride?

The signal word is danger.

What is the physical form of Carbonyl chloride?

Carbonyl chloride is a gaseous / liquefied under pressure. appearing as gaseous / liquefied under pressure. with colourless color. It has pungent odor.

What is the solubility of Carbonyl chloride?

soluble in organic solvent

What is Carbonyl chloride used for?

Basic substance. Intermediate.

What are the hazard statements for Carbonyl chloride?

This substance has 3 hazard statements:

  • H280: Contains gas under pressure; may explode if heated.
  • H314: Causes severe skin burns and eye damage.
  • H330: Fatal if inhaled.

What is the melting point of Carbonyl chloride?

The melting point is -127,8 ℃ and the boiling point is 7,56 °C.