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Safety Data Sheet EN

Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL
Chemical Name
Not Applicable
Synonyms
Not Available

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Battery. NOTE: Battery presents no chemical hazards during the normal operation provided the recommendations for handling, storage, transport and usage are observed. If the battery is broken and the internal components exposed, health hazards exist which require careful attention. NOTE: The chemical hazards relate to the released contents. Undamaged sealed Lead-acid batteries normally present a low hazard, however damaged batteries may release highly corrosive and toxic contents. Disassembly, abuse or destruction of battery cell may cause violent explosion with scattering of contents. Heating may cause bursting with release of contents.

Manufacturers & Suppliers

Ramcar Australia & New Zealand logo

Ramcar Australia & New Zealand

distributor

Unit A, 1 Reconciliation Rise Pemulwuy NSW 2145 Australia

+61 2 9840 2800

www.independentbatterydistributors.com.au; www.lionbatteries.com.au

Emergency Contacts

CHEMWATCH EMERGENCY RESPONSE

+61 2 9186 1132

CHEMWATCH EMERGENCY RESPONSE

+61 1800 951 288

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1A
Eye Dam. Cat. 1
Acute Tox. Cat. 4
Lact.
Aquatic Chronic Cat. 1
Acute Tox. Cat. 4

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
H362 May cause harm to breast-fed children.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P260 Do not breathe dust/fume.
P263 Avoid contact during pregnancy and while nursing.
P264 Wash all exposed external body areas thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Contains various components including lead, lead dioxide, sulfuric acid, and polymers.

Chemical Name CAS Number Concentration Hazardous
Sealed container with electrochemical contents typically --- --- No
lead 7439-92-1 50 - 80% No
lead dioxide 1309-60-0 15 - 40% No
electrolyte (hydrogel) --- --- No
sulfuric acid 7664-93-9 5 - 30% No
case material as --- --- No
polypropylene 9003-07-0 10% No
styrene/ butadiene/ acrylonitrile copolymer 9003-56-9 10% No
separator --- 5% No
tin 7440-31-5 2% No
calcium 7440-70-2 1% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Generally not applicable.

Skin contact

For thermal burns: Decontaminate area around burn. Hold burned skin under cool (not cold) running water or immerse in cool water until pain subsides. Use compresses if running water is not available. Cover with sterile non-adhesive bandage or clean cloth. For second-degree burns: Cool the burn by immerse in cold running water for 10-15 minutes. Protect burn by cover loosely with sterile, nonstick bandage and secure in place with gauze or tape. For third-degree burns: Protect burn area cover loosely with sterile, nonstick bandage or, for large areas, a sheet or other material that will not leave lint in wound. Separate burned toes and fingers with dry, sterile dressings. Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping.

Eye contact

Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjunctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT use neutralising agents or any other additives. Several litres of saline are required.

Ingestion

Immediate dilution (milk or water) within 30 minutes post ingestion is recommended. DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury. Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult.

Immediate Medical Attention

Seek immediate medical or emergency assistance for third-degree burns.

Medical Treatment

Treat symptomatically. For strong acids: 100% oxygen, cricothyroidotomy, IV lines. For skin: copious saline irrigation, non-adherent gauze, topical silver sulfadiazine for deep second-degree burns. For eyes: cycloplegic drops, antibiotic drops, vasoconstrictive agents or artificial tears.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray or fog. Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Specific hazards

Slight hazard when exposed to heat, flame and oxidisers. Non combustible. Not considered to be a significant fire risk. Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Heating may cause expansion or decomposition leading to violent rupture of containers. May emit corrosive, poisonous fumes. May emit acrid smoke. Articles and manufactured articles may constitute a fire hazard where polymers form their outer layers or where combustible packaging remains in place. Certain substances, found throughout their construction, may degrade or become volatile when heated to high temperatures. This may create a secondary hazard.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Use fire fighting procedures suitable for surrounding area. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use.

Firefighter Protection

Wear full body protective clothing with breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Stop leak if safe to do so.

Small spill

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Secure load if safe to do so. Bundle/collect recoverable product. Collect remaining material in containers with covers for disposal.

Large spill

Remove combustible materials and all ignition sources. Acid spills may be neutralised with soda ash. Clean up all spills immediately. Wear protective clothing, safety glasses, dust mask, gloves. Secure load if safe to do so. Bundle/collect recoverable product. Use dry clean up procedures and avoid generating dust. Vacuum up (consider explosion-proof machines designed to be grounded during storage and use). Water may be used to prevent dusting. Collect remaining material in containers with covers for disposal. Flush spill area with water. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Neutralise/decontaminate residue. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.

Environmental

Prevent, by any means available, spillage from entering drains or water course.

Cleanup methods

Vacuum up, Flush spill area with water, Wash area and prevent runoff into drains.

Materials: containers with covers, labelled containers, labelled drums

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Polyalphaslefin (PAO) dimers require bonding and grounding to prevent static hazards which could cause a fire. Electrostatic discharge may be generated during pumping - this may result in fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec). Avoid splash filling. Do NOT use compressed air for filling discharging or handling operations.

Storage

Store in a cool, dry, well-ventilated area.

Fire prevention

Bonding and grounding to prevent static hazards. Restrict line velocity during pumping.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Basic types include process controls, enclosure and/or isolation of emission source, and ventilation. Local exhaust ventilation is usually required. If risk of overexposure exists, wear approved respirator. Provide adequate ventilation in warehouse or closed storage area. Articles or manufactured items, in their original condition, generally don't require engineering controls during handling or in normal use.

Hands

Elbow length PVC gloves. No special equipment required due to the physical form of the product. Recommended materials include NATURAL RUBBER, NATURAL+NEOPRENE, NEOPRENE, NEOPRENE/NATURAL, NITRILE, PE, PVC, SARANEX-23 (CPI: A).

Eyes

No special equipment required due to the physical form of the product. Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. [AS/NZS 1336 or national equivalent]

Respiratory

Type AE-P Filter of sufficient capacity (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent). Respiratory protection not normally required due to the physical form of the product. If risk of overexposure exists, wear approved respirator. Supplied-air type respirator may be required in special circumstances. An approved self contained breathing apparatus (SCBA) may be required in some situations.

Skin/Body

Overalls. PVC Apron. PVC protective suit may be required if exposure severe. No special equipment required due to the physical form of the product.

Environmental

Exceptions to engineering controls may arise following extensive use and subsequent wear, during recycling or disposal operations where substances, found in the article, may be released to the environment.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Density
1.2185-1.3028 (electrolyte)
Solubility
---
Relative Evaporation Rate
---
Melting Point
Not Applicable
Evaporation Rate
<1 BuAC = 1 (electrolyte)
Vapor Density
>1 (electrolyte)
Bulk Density
---
Vapor Pressure
Not Applicable
State Under Standard Conditions
---
Ph
Not Applicable
Decomposition Temperature
Not Available
Flash Point
Not Applicable
Metal Corrosion
---
Voc Content
---
Auto Ignition Temperature
Not Applicable
Explosive Limits
---
Cloud Point
---
Crystallisation Point
---
Colour Intensity
---
Colour
---
Freezing Point
Not Applicable
Physical State
Manufactured
Appearance
Manufactured article; insoluble in water.
Softening Point
---
Solubility In Water
Immiscible
Odor
Not Available
Boiling Point
108-114 (electrolyte) °C
Kinematic Viscosity
Not Applicable
Odor Threshold
Not Available
Molecular Weight
Not Applicable
Solidification Point
---
Physical State Data
solid
Partition Coefficient
Not Available
Lower Explosive Limit
4.1 (H2 gas in air) %
Form
---
Solubility In Fat
---
Density
---
Properties Status
---
Dynamic Viscosity
---
Upper Explosive Limit
74.2 (H2 gas in air) %
Flammability
Not Applicable
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

- Unstable in the presence of incompatible materials ▸ Contact with alkaline material liberates heat

Reactivity

See section 7

Hazardous reactions

See section 7

Avoid

See section 7

Incompatible

See section 7

Decomposition

See section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Treat and neutralise at an approved treatment plant. Treatment should involve: Mixing or slurrying in water; Neutralisation followed by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible material)

Disposal

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2800
Shipping Name
BATTERIES, WET, NON-SPILLABLE, electric storage
Transport Class
8
Packing Group
Not Applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL known by?

Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL is also known as: Not Available

What is the hazard signal word for Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL?

The signal word is danger.

What is the physical form of Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL?

Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL is a manufactured appearing as manufactured article; insoluble in water. . It has not available odor.

What is Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL used for?

Battery. NOTE: Battery presents no chemical hazards during the normal operation provided the recommendations for handling, storage, transport and usage are observed. If the battery is broken and the internal components exposed, health hazards exist which require careful attention. NOTE: The chemical hazards relate to the released contents. Undamaged sealed Lead-acid batteries normally present a low hazard, however damaged batteries may release highly corrosive and toxic contents. Disassembly, abuse or destruction of battery cell may cause violent explosion with scattering of contents. Heating may cause bursting with release of contents.

What are the hazard statements for Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL?

This substance has 5 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H332: Harmful if inhaled.
  • H362: May cause harm to breast-fed children.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Valve Regulated Battery Sealed Lead-Acid Battery VRLA GEL?

The melting point is Not Applicable and the boiling point is 108-114 (electrolyte) °C.