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Safety Data Sheet EN

Citric Acid Anhydrous

CAS 77-92-9
EC 201-069-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Citric Acid Anhydrous

Regulatory Identifiers

CAS Number
77-92-9 Check regulations →
EC Number
201-069-1 Check regulations →
REACH No.
01-2119457026-42-0022

Identified Uses

Intermediate, Formulation, Detergents and cleaning products, Agricultural applications, Personal care products, Paper industry, Construction products, Polymers and plastics, Oil industry, Textile industry, Paints and coatings, Photography products, Laboratory reagents, Water treatment, Treatment of metal surfaces, Medical devices

Manufacturers & Suppliers

L

LAIWU TAIHE BIOCHEMISTRY CO.LTD

manufacturer

NO.89 CHANGJIANG STREET,LAIWU,SHANDONG, CHINA

0086-634-8808564

B-Lands Consulting logo

B-Lands Consulting

WTC, 5 Place Robert Schuman, BP 1516, 38025 Grenoble, FRANCE

+33 476 295 869

http://www.reachteam.eu

Emergency Contacts

NHS Direct

111

NHS Direct

0845 46 47

National Poisons Information Centre

+353 1 8379964

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H319 Causes serious eye irritation.

Precautionary Statements

P264 Wash thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Citric Acid Anhydrous EC: 201-069-1 77-92-9 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move patient to fresh air, if symptoms persist consult a doctor.

Skin contact

If skin irritation continues, consult a doctor.

Eye contact

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Symptoms: Eye Irrit. 2

Ingestion

Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately.

Immediate Medical Attention

call for medical help immediately

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Specific hazards

Carbon dioxide (CO2), Carbon monoxide (CO)

Firefighter Protection

Wear fully protective suit. Wear self-contained respiratory protective device.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Prevent further leakage or spillage if safe to do so.

Cleanup methods

Retrieve the product by mechanical means.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing vapours. Do not get in eyes, on skin, or on clothing. Use only in well ventilated areas. Provide suction extractors if dust is formed. Do not inhale dust / smoke / mist.

Storage

Store in a cool and dry place. Provide ventilation for receptacles. Store only in the original receptacle. Keep container tightly sealed.

Fire prevention

No special measures required.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Rubber, PVC or neoprene gloves recommended. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Select the glove material based on a consideration of the penetration times, rates of diffusion and the degradation. The determined penetration times according to EN 374 part III are not performed under practical conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended. The exact break through time must be determined by the manufacturer of the protective gloves.

Eyes

Tightly sealed goggles (EN 166).

Respiratory

Suitable respiratory protective device recommended.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Solid. Crystalline White.
Colour
Crystalline White.
Colour Intensity
---
Form
Solid.
Odor
Odourless.
Odor Threshold
Not determined.
Ph
1.7
Melting Point
153 °C
Boiling Point
Decomposes before boiling
Flash Point
Not applicable.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Vapor Pressure
2.21*10-6 Pa
Vapor Density
Not applicable.
Relative Density
1.665
Bulk Density
---
Density
Not determined.
Flammability
Product is not flammable.
Upper Explosive Limit
Not determined.
Lower Explosive Limit
Not determined.
Explosive Limits
---
Auto Ignition Temperature
Not applicable.
Decomposition Temperature
Not determined.
Solubility
Alcohols: Partly soluble.
Partition Coefficient
-0.2 to -1.8 log POW
Solubility In Water
590 g/l
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not applicable.
Kinematic Viscosity
Not applicable.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable up to melting point.

Reactivity

No data available.

Hazardous reactions

Reacts with alkali (lyes).

Avoid

Keep away from heat and direct sunlight. Strong oxidizing agents.

Incompatible

Protect from moisture. Avoid strong oxidants, strong alkalis and strong acids. Sodium nitrite, potassium nitrite

Decomposition

Carbon dioxide, Carbon monoxide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.2 Persistence and degradability

Easily biodegradable

Easily biodegradable

12.1 Toxicity

Aquatic toxicity: LC50/24h 1535 mg/L (Daphnia Magna) LC50/48h 440 mg/L (Fish) (OECD 203) NOEC 425 mg/L (Algae)

12.3 Bioaccumulative potential

Does not accumulate in organisms.

Does not accumulate in organisms.

12.4 Mobility in soil pKa: 3.13, 4.76 and 6.4 at 25 °C

12.4 Mobility in soil pKa: 3.13, 4.76 and 6.4 at 25 °C

12.5 Results of PBT and vPvB assessment

PBT: No PBT. vPvB: No vPvB.

The substance is not considered to be PBT or vPvB.

12.6 Other adverse effects

No further relevant information available.

No further relevant information available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not allow product to reach sewage system.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not applicable
Shipping Name
Not applicable
Transport Class
Not applicable
Packing Group
Not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Citric Acid Anhydrous?

The signal word is warning.

What is the physical form of Citric Acid Anhydrous?

Citric Acid Anhydrous is a solid appearing as solid. crystalline white. with crystalline white. color. It has odourless. odor.

What is the solubility of Citric Acid Anhydrous?

Alcohols: Partly soluble.

What is Citric Acid Anhydrous used for?

Intermediate, Formulation, Detergents and cleaning products, Agricultural applications, Personal care products, Paper industry, Construction products, Polymers and plastics, Oil industry, Textile industry, Paints and coatings, Photography products, Laboratory reagents, Water treatment, Treatment of metal surfaces, Medical devices

What are the hazard statements for Citric Acid Anhydrous?

This substance has 1 hazard statement:

  • H319: Causes serious eye irritation.

What is the melting point of Citric Acid Anhydrous?

The melting point is 153 °C and the boiling point is Decomposes before boiling.