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Pi

Picric acid

DANGER solid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Picric acid
Product Code
197378

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Identified Uses
Laboratory chemicals, Synthesis of substances

Overview

Picric acid is a solid substance commonly used laboratory chemicals, synthesis of substances.

Manage Your Safety Data Sheets

Organize and access your chemical safety data with ease.

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Flam. Sol. Category 1 H228
Acute Tox. Category 4 H302
Acute Tox. Category 3 H331
Acute Tox. Category 3 H311

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS06 GHS Hazard Pictogram: Acute toxicity hazard - Poisonous materials that can cause death or serious harm

GHS06

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H228: Flammable solid.
  • H302: Harmful if swallowed.
  • H311: Toxic in contact with skin or if inhaled.
  • H331: Toxic in contact with skin or if inhaled.

Precautionary Statements

  • P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
  • P240: Ground/bond container and receiving equipment.
  • P241: Use explosion-proof electrical/ ventilating/ lighting/ equipment.
  • P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
  • P264: Wash skin thoroughly after handling.
  • P270: Do not eat, drink or smoke when using this product.
  • P271: Use only outdoors or in a well-ventilated area.
  • P280: Wear protective gloves/ eye protection/ face protection.
  • IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
  • IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell.
  • IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
  • P362: Take off contaminated clothing and wash before reuse.
  • P370+P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
  • P403+P233: Store in a well-ventilated place. Keep container tightly closed.
  • P405: Store locked up.
  • P501: Dispose of contents/ container to an approved waste disposal plant.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Sigma-Aldrich

manufacturer

๐Ÿ“

3050 Spruce Street SAINT LOUIS MO 63103 USA

๐ŸŒ

US

๐Ÿ“ž

+1 800-325-5832

๐Ÿ“ 

+1 800-325-5052

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

CHEMTREC

๐Ÿ“ž

+1-703-527-3887

๐ŸŒ

US

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
2,4,6-Trinitrophenol 88-89-1 60-65% โš ๏ธ Hazardous
2,4,6-Trinitrophenol 88-89-1 50-70% โš ๏ธ Hazardous

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

๐Ÿซ Inhalation Exposure

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

๐Ÿ–๏ธ Skin Contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

๐Ÿ‘๏ธ Eye Contact

Flush eyes with water as a precaution.

๐Ÿฝ๏ธ Ingestion/Swallowing

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Fire Fighting Measures & Emergency Response

Fire suppression methods, extinguishing media, and firefighting safety procedures

โœ… Suitable Extinguishing Media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

๐Ÿ”ฅ Fire Fighting Instructions

Wear self-contained breathing apparatus for firefighting if necessary.

Accidental Release Measures & Spill Response

Emergency spill cleanup procedures, containment methods, and environmental protection

๐Ÿšจ Emergency Procedures

Evacuate personnel to safe areas.

๐ŸŒ Environmental Precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

๐Ÿงน Cleanup Methods

Sweep up and shovel.

Cleanup Materials:

Collect with an electrically protected vacuum cleaner or by wet-brushing.

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

๐Ÿงช Physical State
solid
Critical Property
๐Ÿ“Š Physical State Data
solid
๐Ÿ“Š State Under Standard Conditions
Not available
๐Ÿ‘๏ธ Appearance
solid
๐ŸŽจ Colour
yellow
๐Ÿ“Š Colour Intensity
Not available
๐Ÿ“Š Form
solid
๐Ÿ‘ƒ Odor
No data available
๐Ÿ“Š Odor Threshold
No data available
๐Ÿงช Ph
No data available
๐ŸงŠ Melting Point
121 โ„ƒ (250 ยฐF)
Critical Property
๐Ÿ’จ Boiling Point
No data available
Critical Property
๐Ÿ”ฅ Flash Point
150 ยฐC (302 ยบF) - closed cup
Critical Property
๐Ÿ“Š Freezing Point
Not available
๐Ÿ“Š Softening Point
Not available
๐Ÿ“Š Solidification Point
Not available
๐Ÿ“Š Cloud Point
Not available
๐Ÿ“Š Crystallisation Point
Not available
๐Ÿ“Š Relative Evaporation Rate
Not available
๐Ÿ’จ Evaporation Rate
No data available
๐Ÿ’จ Vapor Pressure
1 hPa (1 mmHg) at 195 โ„ƒ (383 ยบF)
๐Ÿ“Š Vapor Density
No data available
๐Ÿ“Š Relative Density
1.800 g/cm3 at 20 ยฐโ„ƒ (68 ยบF)
๐Ÿ“Š Bulk Density
Not available
โš–๏ธ Density
Not available
๐Ÿ”ฅ Flammability
The substance or mixture is a flammable solid with the category 1.
๐Ÿ“Š Upper Explosive Limit
No data available
๐Ÿ“Š Lower Explosive Limit
No data available
๐Ÿ“Š Explosive Limits
Not available
๐Ÿ“Š Auto Ignition Temperature
Not available
๐Ÿ“Š Decomposition Temperature
No data available
๐Ÿ’ง Solubility
soluble
๐Ÿ“Š Partition Coefficient
log Pow: 1.33
๐Ÿ“Š Solubility In Water
soluble
๐Ÿ“Š Solubility In Fat
Not available
๐Ÿ“Š Molecular Weight
Not available
๐Ÿ“Š Voc Content
Not available
๐Ÿ“Š Metal Corrosion
Not available
๐Ÿ“Š Dynamic Viscosity
Not available
๐Ÿ“Š Kinematic Viscosity
Not available
๐Ÿ“Š Properties Status
Not available

Safe Handling & Storage Procedures

Industrial handling precautions, storage conditions, and workplace safety requirements

โš ๏ธ Handling Precautions

โ€ข Avoid contact with skin and eyes.

โ€ข Avoid formation of dust and aerosols.

โ€ข Further processing of solid materials may result in the formation of combustible dusts.

โ€ข The potential for combustible dust formation should be taken into consideration before additional processing occurs.

โ€ข Provide appropriate exhaust ventilation at places where dust is formed.

โ€ข Keep away from sources of ignition - No smoking.

โ€ข Take measures to prevent the build up of electrostatic charge.

๐Ÿช Storage Conditions

โ€ข Keep container tightly closed in a dry and well-ventilated place.

โ€ข Keep wetted with water.

โ€ข Do not allow material to become dry.

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

๐Ÿญ Engineering Controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

๐Ÿงค Hand Protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Material: Nitrile rubber. Minimum layer thickness: 0.11 mm. Break through time: 480 min. Material tested: Dermatrilยฎ (KCL 740 / Aldrich Z677272, Size M). Tested according to EN374. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves.

๐Ÿ‘๏ธ Eye Protection

Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

๐Ÿ˜ท Respiratory Protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

๐Ÿฆบ Skin/Body Protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

๐ŸŒ Environmental Exposure Controls

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Chemical Stability & Reactivity Data

Chemical stability, hazardous reactions, and incompatible materials information

โœ… Chemical Stability

Stable under recommended storage conditions. Contains the following stabiliser(s): Water (>=30 - <= 40 %)

โš—๏ธ Reactivity

No data available

โš ๏ธ Hazardous Reactions

No data available

๐Ÿšซ Conditions to Avoid

Picric acid forms salts with many metals some of which are rather sensitive to heat, friction, or impact, e.g., lead, iron, zinc, nickel, copper, etc., and should be considered dangerously sensitive. The salts formed with ammonia and amines, and the molecular complexes with aromatic hydrocarbons, etc, are in general not so sensitive. Contact of picric acid with concrete floors may form the friction-sensitive calcium salt. Dry mixtures of picric acid and aluminum powder are inert, but the addition of water causes ignition after a delay dependent upon the quantity added. Storage conditions: records of purchase dates should be maintained for each container. Material older than 2 years should be disposed. Inspect and add water every six months as needed. Rotate containers to distribute water every three months. Heat, flames and sparks.

๐Ÿงช Incompatible Materials

Strong bases, Reducing agents, Heavy metals, Heavy metal salts, Ammonia

๐Ÿ’จ Hazardous Decomposition Products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) Other decomposition products - No data available

Ecological Information & Environmental Impact

Environmental toxicity, biodegradation, bioaccumulation, and ecological effects data

๐ŸŒฑ Toxicity

No data available No data available

๐ŸŒฑ Persistence and degradability

No data available

๐ŸŒฑ Bioaccumulative potential

No data available

๐ŸŒฑ Mobility in soil

No data available

๐ŸŒฑ Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

๐ŸŒฑ Endocrine disrupting properties

No data available

๐ŸŒฑ Other adverse effects

No data available No data available

Waste Disposal & Treatment Methods

Waste disposal procedures, treatment methods, and regulatory compliance requirements

โ™ป๏ธ Waste Treatment Methods

Contact a licensed professional waste disposal service to dispose of this material. Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.

๐Ÿ—‚๏ธ Product Disposal Recommendations

Dispose of as unused product.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

๐Ÿท๏ธ UN Number

1344

๐Ÿ“ฆ Proper Shipping Name

Trinitrophenol, wetted

โš ๏ธ Transport Hazard Class

4.1

๐Ÿ“‹ Packing Group

I

Regulatory Information & Compliance

Chemical regulations, safety assessments, and regulatory compliance status

๐Ÿ“‹ Regulatory Summary

No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

โŒ Chemical Safety Assessment

No chemical safety assessment has been performed for this substance.

โ„น๏ธ Additional Regulatory Information

The following components are subject to reporting levels established by SARA Title III, Section 313.

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Picric acid?

The signal word for this substance is "danger".

What is the physical form of Picric acid?

Picric acid is a solid appearing as solid with yellow color. It has no data available odor.

What is the solubility of Picric acid?

soluble

What is Picric acid used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Picric acid?

This substance has 4 hazard statements: H228: Flammable solid. H302: Harmful if swallowed. H311: Toxic in contact with skin or if inhaled. H331: Toxic in contact with skin or if inhaled.

What is the melting point of Picric acid?

The melting point is 121 โ„ƒ (250 ยฐF) and the boiling point is No data available.