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Safety Data Sheet EN

DGT® SolventGlue EC.7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DGT® SolventGlue EC.7

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Solvent action glue for the gluing of the polymethylmetacrylate (PMMA).

Uses advised against

All uses not indicated in the identified uses.

Manufacturers & Suppliers

D

DeskGlueTech S.r.l.

manufacturer

Via Edilizia 25/27, 20026 Novate Milanese (MI), Italia

+39 02 89767530

Emergency Contacts

Emergency Contact

+43 14064343

Emergency Contact

+32 070245245

Emergency Contact

+359 29154233

Emergency Contact

1401

Emergency Contact

+45 82121212

Emergency Contact

+34 915620420

Emergency Contact

+385 12348342

Emergency Contact

+372 7943794

Emergency Contact

16662

Emergency Contact

+358 800 147111

Emergency Contact

+33 (0) 145425959

Emergency Contact

112

Emergency Contact

+30 2107793777

Emergency Contact

+353 (01) 8092166

Emergency Contact

+354 5432222

Emergency Contact

+371 67042473

Emergency Contact

+370 (85) 2362052

Emergency Contact

+352 80025500

Emergency Contact

2545 0000

Emergency Contact

+47 22591300

Emergency Contact

+31 (0) 887558000

Emergency Contact

+351 800250250

Emergency Contact

+420 224919293

Emergency Contact

+40 212308000

Emergency Contact

+421 254774166

Emergency Contact

+36 80201199

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Carc. Cat. 2 H351
Eye Dam. Cat. 1 H318
Skin Irrit. Cat. 2 H315
STOT SE Cat. 3 H336

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing dust / fume / gas / mist / vapours / spray.
P280 Wear protective gloves/ protective clothing / eye protection / face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER / doctor.
P370 + P378 In case of fire: use carbon dioxide / foam / powder to extinguish.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Contains various chemical components.

Chemical Name CAS Number Concentration Hazardous
DICHLOROMETHANE EC: 200-838-9 75-09-2 25 - 50% Yes
NITROETHANE EC: 201-188-9 79-24-3 20 - 30% Yes
ETHYL ACETATE EC: 205-500-4 141-78-6 10 - 15% Yes
2-PHENOXYETHANOL EC: 204-589-7 122-99-6 5 - 10% Yes
ETHANOL EC: 200-578-6 64-17-5 2.5 - 5% Yes
NITROMETHANE EC: 200-876-6 75-52-5 2.5 - 5% Yes
METHYL METHACRYLATE EC: 201-297-1 80-62-6 0.5 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention immediately.

Skin contact

Remove contaminated clothing. Rinse skin with a shower immediately. Wash contaminated clothing before using it again.

Eye contact

Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice.

Ingestion

Get medical advice/attention immediately. Do not induce vomiting. Do not administer anything not explicitly authorised by a doctor.

Immediate Medical Attention

Get medical advice/attention immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can be used to disperse flammable vapours and protect those trying to stem the leak.

Unsuitable media

Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent explosions.

Specific hazards

Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. Heat may cause the product to polymerise, which could lead to explosion.

Instructions

Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent explosions.

Firefighter Protection

Always wear full fire prevention gear. Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Block the leakage if there is no hazard.

Environmental

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

Cleanup methods

Absorb the remainder with inert absorbent material.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Avoid bunching of electrostatic charges. When performing transfer operations involving large containers, connect to an earthing system and wear antistatic footwear. Vigorous stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they may be pressurised.

Storage

Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a cool and well ventilated place, keep far away from sources of heat, naked flames and sparks and other sources of ignition.

Hygiene

Do not eat, drink or smoke during use.

Fire prevention

Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Avoid bunching of electrostatic charges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration.

Hands

Protect hands with category III work gloves (see standard EN 374). The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use.

Eyes

Wear airtight protective goggles (see standard EN 166).

Respiratory

If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a type AX filter, whose limit of use will be defined by the manufacturer (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.

Skin/Body

Wear category II professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body with soap and water after removing protective clothing. Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion.

Environmental

The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
colourless
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
---
Ph
7 - 8 (Concentration: 1 %)
Melting Point
-90 °C
Boiling Point
> 40 °C
Flash Point
< 60 °C
Freezing Point
-90 ℃
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
not available
Vapor Density
---
Relative Density
1,15 g/cm3
Bulk Density
---
Density
1,15 g/cm3
Flammability
flammable liquid
Upper Explosive Limit
not available
Lower Explosive Limit
not available
Explosive Limits
---
Auto Ignition Temperature
not available
Decomposition Temperature
not available
Solubility
soluble in water
Partition Coefficient
not available
Solubility In Water
soluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
62,60 % - 719,90 g/litre
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
> 500 mm2/s (Temperature: 20 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable in normal conditions of use and storage.

Reactivity

There are no particular risks of reaction with other substances in normal conditions of use. 2-PHENOXYETHANOL: In water at 1% reacts to form a weak acid (pH=6). ETHYL ACETATE: Decomposes slowly into acetic acid and ethanol under the effect of light, air and water. DICHLOROMETHANE: Decomposes at temperatures above 120°C/248°F. With water and alkalis it may form hydrochloric acid and attack aluminium, copper and alloys.

Hazardous reactions

The vapours may also form explosive mixtures with the air. ETHYL ACETATE: Risk of explosion on contact with: alkaline metals, hydrides, oleum. May react violently with: fluorine, strong oxidising agents, chlorosulphuric acid, potassium tert-butoxide. Forms explosive mixtures with: air. ETHANOL: Risk of explosion on contact with: alkaline metals, alkaline oxides, calcium hypochlorite, sulphur monofluoride, acetic anhydride, acids, concentrated hydrogen peroxide, perchlorates, perchloric acid, perchloronitrile, mercury nitrate, nitric acid, silver, silver nitrate, ammonia, silver oxide, ammonia, strong oxidising agents, nitrogen dioxide. May react dangerously with: bromoacetylene, chlorine acetylene, bromine trifluoride, chromium trioxide, chromyl chloride, fluorine, potassium tert-butoxide, lithium hydride, phosphorus trioxide, black platinum, zirconium (IV) chloride, zirconium (IV) iodide. Forms explosive mixtures with: air. DICHLOROMETHANE: Risk of explosion on contact with: alkaline metals, nitric acid, aluminium powder, ethanediamine, aluminium chloride, perchloric acid, dinitrogen pentoxide, sodium nitride, n-nitroso n-methylurea, potassium hydroxide. May react dangerously with: alkaline earth metals, metal powders, sodium amides, potassium tert-butylate. May form explosive mixtures with: air. METHYL METHACRYLATE: May polymerise on contact with: ammonia, organic peroxides, persulphates. Risk of explosion on contact with: dibenzoyl peroxide, diterbutyl peroxide, propionaldehyde. May react dangerously with: strong oxidising agents. Forms explosive mixtures with: air.

Avoid

Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. Ethyl Acetate: Avoid exposure to: light, sources of heat, naked flames. Ethanol: Avoid exposure to: sources of heat, naked flames. Dichloromethane: Avoid exposure to: naked flames, overheated surfaces. Methyl Methacrylate: Avoid exposure to: heat, UV rays. Avoid contact with: oxidising substances, reducing substances, acids, bases.

Incompatible

Methyl Methacrylate: oxidising substances, reducing substances, acids, bases.

Decomposition

In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. DICHLOROMETHANE: May develop: dioxins, phosgenes, hydrochloric acid. METHYL METHACRYLATE: When heated to decomposition releases: harsh fumes, zinc alloys.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation.

12.1. Toxicity

2-PHENOXYETHANOL LC50 - for Fish 344 mg/l/96h EC50 - for Crustacea 488 mg/l/48h OECD 202 EC50 - for Algae / Aquatic Plants 100 mg/l/72h OECD 201 EC10 for Algae / Aquatic Plants 46 mg/l/72h OECD 201 Chronic NOEC for Fish 24 mg/l/34d OECD 210 Chronic NOEC for Crustacea 9,43 mg/l/21d OECD 211

12.1. Toxicity

ETHYL ACETATE LC50 - for Fish 230 mg/l/96h EC50 - for Crustacea 165 mg/l/48h Chronic NOEC for Fish 6,9 mg/l QSAR Chronic NOEC for Crustacea 2,4 mg/l OECD 211

12.1. Toxicity

ETHANOL LC50 - for Fish 11200 mg/l/96h EC50 - for Crustacea 5012 mg/l/48h EC50 - for Algae / Aquatic Plants 4432 mg/l/72h Chronic NOEC for Fish 250 mg/l/5d OECD 212 Chronic NOEC for Crustacea 9,6 mg/l/10d Chronic NOEC for Algae / Aquatic Plants 280 mg/l/7d

12.1. Toxicity

DICHLOROMETHANE LC50 - for Fish 193 mg/l/96h EC50 - for Crustacea 27 mg/l/48h Chronic NOEC for Fish 83 mg/l/28d

12.1. Toxicity

NITROMETHANE LC50 - for Fish 455 mg/l/96h OECD 203 EC50 - for Crustacea > 103 mg/l/48h OECD 202 EC50 - for Algae / Aquatic Plants 102 mg/l/72h OECD 201 EC10 for Algae / Aquatic Plants 3,01 mg/l/72h OECD 201

12.1. Toxicity

NITROETHANE EC50 - for Crustacea > 21,9 mg/l/48h OECD 202 EC50 - for Algae / Aquatic Plants 17,4 mg/l/72h OECD 201 EC10 for Algae / Aquatic Plants 7,11 mg/l/72h OECD 211 Chronic NOEC for Crustacea 2,44 mg/l/21d OECD 211

12.1. Toxicity

METHYL METHACRYLATE LC50 - for Fish > 100 mg/l/96h EC50 - for Crustacea 69 mg/l/48h EPA OTS 797.1300 EC50 - for Algae / Aquatic Plants > 110 mg/l/72h OECD 201 EC10 for Algae / Aquatic Plants 110 mg/l/72h OECD 201 Chronic NOEC for Fish 9,4 mg/l/35d OECD 210 Chronic NOEC for Crustacea 37 mg/l/21d OECD 211

12.2. Persistence and degradability

12.2. Persistence and degradability

2-PHENOXYETHANOL Solubility in water 28600 mg/l Rapidly degradable >99% / 28d

12.2. Persistence and degradability

ETHYL ACETATE Rapidly degradable 69% / 20d

12.2. Persistence and degradability

### ETHANOL Solubility in water 1000 - 10000 mg/l Rapidly degradable

12.2. Persistence and degradability

Solubility in water 13200 mg/l Rapidly degradable 68% / 28d, OECD 301D

12.2. Persistence and degradability

NITROMETHANE Entirely degradable 10% / 28d, OECD 301D

12.2. Persistence and degradability

NITROETHANE NOT rapidly degradable 0,1% / 28d, OECD 301D

12.2. Persistence and degradability

METHYL METHACRYLATE Solubility in water 15300 mg/l Rapidly degradable 94% / 14d OECD 301C

12.3. Bioaccumulative potential

EPY 11.4.1 - SDS 1004.14

12.3. Bioaccumulative potential

2-PHENOXYETHANOL Partition coefficient: n-octanol/water 1,2 BCF 0,3493

12.3. Bioaccumulative potential

ETHANOL Partition coefficient: n-octanol/water -0,35

12.3. Bioaccumulative potential

DICHLOROMETHANE Partition coefficient: n-octanol/water 1,25 BCF 2

12.3. Bioaccumulative potential

METHYL METHACRYLATE Partition coefficient: n-octanol/water 1,38

12.4. Mobility in soil

2-PHENOXYETHANOL Partition coefficient: soil/water 1,6 ETHANOL Partition coefficient: soil/water 0,2 QSAR METHYL METHACRYLATE Partition coefficient: soil/water 0,94

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

The product does not contain any PBT or vPvB substances in concentrations ≥ 0.1%.

12.6. Endocrine disrupting properties

Based on the available data, the product does not contain substances listed in the main European lists of potential or suspected endocrine disruptors with environmental effects under evaluation.

The product does not contain substances listed in the main European lists of potential or suspected endocrine disruptors with environmental effects under evaluation.

12.7. Other adverse effects

Information not available

Information not available

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.

Disposal

Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1133
Shipping Name
ADHESIVES
Transport Class
3
Packing Group
III
ADR

HIN - Kemler: 30 Special provision: - EMS: F-E, S-D

IMDG

HIN - Kemler: 30 Special provision: - EMS: F-E, S-D

IATA

HIN - Kemler: 30 Special provision: - EMS: F-E, S-D

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DGT® SolventGlue EC.7?

The signal word is danger.

What is the physical form of DGT® SolventGlue EC.7?

DGT® SolventGlue EC.7 is a liquid appearing as liquid with colourless color. It has characteristic odor.

What is the solubility of DGT® SolventGlue EC.7?

soluble in water

What is DGT® SolventGlue EC.7 used for?

Solvent action glue for the gluing of the polymethylmetacrylate (PMMA).

What are the hazard statements for DGT® SolventGlue EC.7?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapour.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.

What is the melting point of DGT® SolventGlue EC.7?

The melting point is -90 °C and the boiling point is > 40 °C.