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Safety Data Sheet EN

Methanol

CAS 67-56-1
EC 200-659-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methanol
Chemical Name
Methyl alcohol
Synonyms
houtgeest

Regulatory Identifiers

CAS Number
67-56-1 Check regulations →
EC Number
200-659-6 Check regulations →
REACH No.
01-2119433307-44-0135

Identified Uses

Industrial use: Distribution of substance. Formulation & (re)packing of substances and mixtures. Use as a fuel. Use in cleaning agents. Use as laboratory reagent. Water treatment chemicals, wastewater. Professional use: Use as a fuel. Use in cleaning agents. Use as laboratory reagent. Use in oil and gas field drilling and production operations. Consumer use: Use in cleaning agents.

Uses advised against

None identified

Manufacturers & Suppliers

M

Methanex Europe SA/NV

Waterloo Office Park - Building P Drve Richelle 161 - box 31 B-1410 Waterloo

+(32) 2 352 06 70

Emergency Contacts

Emergency Contact

+44 (0) 1235 239 670

24h/7d

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Acute Tox. Cat. 3
Acute Tox. Cat. 3
Acute Tox. Cat. 3
STOT SE Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H370 Causes damage to organs.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P235 Keep cool.
P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P311 If exposed or concerned: Call a POISON CENTER or doctor/physician.
P311 Call a POISON CENTER or doctor.
P321 Specific treatment (see label).
P330 Rinse mouth.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use appropriate media to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
ALCOOL METHYLIQUE EC: 200-659-6 67-56-1 99.85% Yes

Component Related Regulatory Information Specific concentration limit (SCL): STOT SE 1; H370: C 10%, STOT SE 2; H371: 3% C < 10%

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air and keep comfortable for breathing. Administer oxygen if breathing is difficult. Immediately call a POISON CENTER or doctor.

Symptoms: Breathing is difficult. Coma and death due to respiratory failure may follow severe exposures. Toxic if inhaled.

Skin contact

Remove/take off immediately all contaminated clothing. Wash with plenty of water. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse.

Symptoms: Toxic if in contact with skin.

Eye contact

Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation develops and persists, get medical attention.

Symptoms: Irritation develops and persists.

Ingestion

Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Seek medical attention immediately.

Symptoms: Poison. May be fatal if swallowed. If swallowed there is a risk of blindness. Toxic if swallowed. Ingestion causes nausea, weakness and central nervous system effects, headache, vomiting, dizziness, symptoms of drunkenness. Coma and death due to respiratory failure may follow severe exposures.

Immediate Medical Attention

Immediately call a POISON CENTER or doctor. Seek medical attention immediately. Medical treatment necessary. If ingested, get immediate medical attention. There is a need for rapid treatment of any ingestion exposure.

Medical Treatment

Treat symptomatically and supportively. The severity of outcome following methanol ingestion may be more related to the time between ingestion and treatment, rather than the amount ingested. Therefore, there is a need for rapid treatment of any ingestion exposure.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Use explosion-proof electrical/ventilating/lighting equipment. Handle substance within a closed system. Ground/Bond container and receiving equipment. Maintain eye wash fountain and quick-drench shower in work area.

Hands

Wear suitable gloves tested to (EN 374), butyl rubber.

Eyes

Use eye protection according to EN 166, designed to protect against liquid splashes.

Respiratory

Any supplied-air respirator with a full face piece that is operated in a pressure-demand or other positive-pressure mode (EN 137). Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Skin/Body

Wear appropriate chemical resistant clothing (EN ISO 6529).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
clear
Colour
colorless
Colour Intensity
---
Form
---
Odor
alcohol odor
Odor Threshold
4.2 - 5960 ppm
Ph
Not applicable
Melting Point
-97.8 C
Boiling Point
64.7 C
Flash Point
11 C
Freezing Point
-97.6 C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
4.1 (butyl acetate = 1 )
Vapor Pressure
12.8 kPa (@ 20 C )
Vapor Density
---
Relative Density
792 kg/m
Bulk Density
---
Density
0.791 - 0.793 at 20 C
Flammability
Not applicable
Upper Explosive Limit
36.5 %
Lower Explosive Limit
5.5 %
Explosive Limits
---
Auto Ignition Temperature
464 C
Decomposition Temperature
Not available
Solubility
Not available
Partition Coefficient
0.82
Solubility In Water
Not available
Solubility In Fat
---
Molecular Weight
32.04 (g/mol )
Voc Content
100 %
Metal Corrosion
---
Dynamic Viscosity
0.8 cP (25 C, dynamic )
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1230
Shipping Name
METHANOL
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methanol known by?

Methanol is also known as: houtgeest

What is the hazard signal word for Methanol?

The signal word is danger.

What is the physical form of Methanol?

Methanol is a liquid appearing as clear with colorless color. It has alcohol odor odor.

What is the solubility of Methanol?

Not available

What is Methanol used for?

Industrial use: Distribution of substance. Formulation & (re)packing of substances and mixtures. Use as a fuel. Use in cleaning agents. Use as laboratory reagent. Water treatment chemicals, wastewater. Professional use: Use as a fuel. Use in cleaning agents. Use as laboratory reagent. Use in oil and gas field drilling and production operations. Consumer use: Use in cleaning agents.

What are the hazard statements for Methanol?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H301: Toxic if swallowed.
  • H311: Toxic in contact with skin.
  • H331: Toxic if inhaled.
  • H370: Causes damage to organs.

What is the melting point of Methanol?

The melting point is -97.8 C and the boiling point is 64.7 C.

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