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Safety Data Sheet EN

Methanol

CAS 67-56-1
EC 200-659-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methanol
Product Code
19393

Regulatory Identifiers

CAS Number
67-56-1 Check regulations →
EC Number
200-659-6 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc. logo

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

Monday-Friday, 8am-7pm EST

Carechem 24

(866) 928-0789

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
STOT SE Cat. 1 H370

GHS Pictograms

GHS02 - Flammable

GHS02

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H370 Causes damage to the eyes and the brain. Route of exposure: Oral and Inhalation, Dermal.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P303 + P361 + P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterization: Substances

Chemical Name CAS Number Concentration Hazardous
Methanol EC: 200-659-6 67-56-1 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Do not induce vomiting; immediately call for medical help.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Specific hazards

If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep unprotected persons away.

Environmental

Do not allow product to reach sewage system or any water course.

Cleanup methods

Absorb with liquid-binding material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly sealed. Open and handle container with care.

Storage

Store in a cool location. Store in cool, dry conditions in well sealed containers. Keep container tightly sealed.

Fire prevention

Keep ignition sources away.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Material of gloves Butyl rubber, BR. Penetration time of glove material (in minutes) 480. Glove thickness: 0.3 mm

Eyes

Safety glasses with side shields / NIOSH (US) or EN 166(EU)

Respiratory

Use self-contained respiratory protective device in emergency situations. Recommended filter device for short term use: Use a respirator with multi-purpose combination (US) or type AXBEK (EN 14387) as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards such as NIOSH (USA) or CEN (EU).

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Mild
Colour
---
Colour Intensity
---
Form
Liquid
Odor
Mild
Odor Threshold
Not determined.
Ph
Not determined.
Melting Point
-98 °C (-144 °F)
Boiling Point
64.7 °C (148 °F)
Flash Point
11 °C (52 °F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined.
Vapor Pressure
128 hPa (96 mm Hg)
Vapor Density
Not determined.
Relative Density
Not determined.
Bulk Density
---
Density
0.791 g/cm³ (6.601 lbs/gal)
Flammability
Not determined.
Upper Explosive Limit
44 Vol %
Lower Explosive Limit
5.5 Vol %
Explosive Limits
---
Auto Ignition Temperature
455 °C (851 °F)
Decomposition Temperature
Not determined
Solubility
---
Partition Coefficient
Not determined.
Solubility In Water
Fully miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not determined.
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No information known.

Hazardous reactions

Reacts with strong oxidizing agents

Avoid

No further relevant information available.

Incompatible

Oxidizing agents

Decomposition

Carbon monoxide and carbon dioxide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1230
Shipping Name
Methanol
Transport Class
3
Packing Group
II
IMDG

Warning: Flammable liquids

IATA

Warning: Flammable liquids

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Methanol?

The signal word is danger.

What is the physical form of Methanol?

Methanol is a liquid appearing as mild . It has mild odor.

What is Methanol used for?

SU24 Scientific research and development

What are the hazard statements for Methanol?

This substance has 3 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
  • H370: Causes damage to the eyes and the brain. Route of exposure: Oral and Inhalation, Dermal.

What is the melting point of Methanol?

The melting point is -98 °C (-144 °F) and the boiling point is 64.7 °C (148 °F).