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Safety Data Sheet EN

GASOIL DIESEL OFF ROAD

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
GASOIL DIESEL OFF ROAD

Regulatory Identifiers

CAS Number
N/A
UFI Code
YSM7-RP1H-J301-PPVX

Identified Uses

Formulation & (re)packing of substances and mixtures - Industrial, Use as a fuel - Industrial, Use as a fuel - Professional, Use as a fuel - Consumer

Manufacturers & Suppliers

T

TotalEnergies Marketing Belgium

national supplier

Anspachlaan 1, bus 2 / Boulevard anspach 1, boîte 2, 1000 Brussel/Bruxelles – België/Belgique

+32 (0)22 889 933

Emergency Contacts

National advisory body/Poison Center

+32 70 245 245

Supplier (info product)

+44 1235239670

SOS TotalEnergies Marketing Belgium (transport)

+32 78 15 51 51

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Carc. Cat. 2 H351
STOT RE Cat. 2 H373
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure. (bone marrow, liver, thymus)
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe gas, vapor or spray.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P331 Do NOT induce vomiting.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Contains: Dye and fiscal marker. Contains: Mixture of C16-C18 fatty acids methyl esters.

Chemical Name CAS Number Concentration Hazardous
Fuels, diesel EC: 269-822-7 68334-30-5 90% Yes
N-ethyl-N-[2-[1-(2-methylpropoxy)ethoxy] ethyl]-4-(phenylazo)aniline EC: 252-021-1 34432-92-3 0.006% Yes

Contains: Dye and fiscal marker Contains: Mixture of C16-C18 fatty acids methyl esters Component: % (v/v)

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Seek immediate medical attention/advice. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: In case of exposure to hot product, inhalation of vapors in high concentration may cause irritation of respiratory system. Can cause central nervous system (CNS) depression. nausea or vomiting, headache, dizziness/vertigo, convulsive seizures, cardiac arrhythmia, Loss of coordination.

Skin contact

Immediately remove any contaminated clothing, shoes or socks. Wash contaminated skin with soap and water. Continue to rinse for at least 10 minutes. Get medical attention if symptoms appear. Wash clothing before reuse. Clean shoes thoroughly before reuse. High pressure injection of the products under the skin may have very serious consequences even though no symptom or injury may be apparent. In this case, the casualty should be sent immediately to hospital.

Symptoms: Causes skin irritation.

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Continue to rinse for at least 10 minutes. If irritation persists, get medical attention.

Symptoms: May cause mild reversible eye irritation. watering, redness.

Ingestion

Take victim immediately to hospital. SYMPTOMS MAY NOT APPEAR IMMEDIATELY. Wash out mouth with water. Keep person warm and at rest. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: nausea or vomiting, stomach pains, diarrhea, Can cause central nervous system (CNS) depression.

Immediate Medical Attention

Seek immediate medical attention/advice. In case of high pressure injection, the casualty should be sent immediately to hospital. Take victim immediately to hospital if ingested.

Medical Treatment

The exposed person may need to be kept under medical surveillance for 48 hours.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

on small fires: Use dry chemical, CO₂, water spray (fog) or foam. Sand. large fires: Foam, Water fog (trained personnel only)

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water to cool tanks and parts exposed to the thermal flux not caught up in the flames.

Firefighter Protection

In case of a large fire or in confined or poorly ventilated spaces, wear full fire resistant protective clothing and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Only allow access to authorised persons. Do not touch or walk through spilled material. Hazard of slipping on spilled product.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with dry earth, sand or other non-combustible material. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Cover discharges with foam in order to reduce the risks of ignition. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Use spark-proof tools and explosion-proof equipment. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

Environmental

Toxic to aquatic life with long lasting effects. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dispose of via a licensed waste disposal contractor.

Materials: non-combustible, absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Avoid contact with eyes, skin and clothing. Avoid breathing vapor. Never siphon by mouth. Manipulate in a well-ventilated area. Ensure ventilation is adequate if there is a risk of aerosol formation or vapor build-up. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Avoid release to the environment.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Hygiene

After handling, always wash hands thoroughly with soap and water. Take off immediately all contaminated clothing and wash it before reuse. Provide regular cleaning of equipment, work area and clothing. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. OPERATE ONLY ON COLD AND DEGASSED TANKS IN VENTILATED PREMISES (TO AVOID RISK OF EXPLOSION). Never weld any container or empty pipe that has not been degassed. Ensure all equipment is electrically grounded before beginning transfer operations. Friction generated by product discharge can create static charges of sufficient magnitude to cause SPARKS WHICH MAY LEAD TO FIRE OR EXPLOSION.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation and check that a safe, breathable atmosphere is present before entry into confined spaces. Explosive atmosphere in confined spaces. Check that the vapor concentration is lower than the lower flammability limit (explosimeter, ...).

Hands

Hydrocarbon-proof gloves for aromatic hydrocarbons. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Note: Gloves made of PVA are not water-resistant, and are not suitable for emergency use. Repeated or prolonged exposure: Glove material: polyvinyl alcohol (PVA); any thickness; Break through time > 480 min; standard : EN 374. Glove material: Fluorinated rubber; any thickness; Break through time > 480 min; standard : EN 374. Glove material: Nitrile rubber; Glove thickness > 0.5 mm; Break through time > 480 min; standard : EN 374. In case of contact through splashing: Glove material: Neoprene; Glove thickness > 0.75 mm; Break through time > 60 min; standard : EN 374. Glove material: polyvinyl chloride (PVC); Glove thickness > 1.3 mm; Break through time > 30 min; standard : EN 374.

Eyes

Goggles, face shield or other full-face protection should be worn if there is a risk of direct exposure to aerosols or splashes. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. In case of insufficient ventilation, wear suitable respiratory equipment. When using a mask or half mask : Full face piece respirator with organic vapor/acid gas cartridge or canister, Type A. Respirator with combination filter for vapor/particulate, Type A/P2. In an emergency or for exceptional short-lasting jobs in an atmosphere polluted by the product, it is necessary to wear protective respiratory equipment. To enter tankers, tanks, reservoirs where the oxygen content is too low, wear insulating respiratory apparatus. The use of breathing apparatus must comply strictly with the manufacturer's instructions and the regulations governing their choices and uses.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. Antistatic non-skid safety shoes or boots

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Softening Point
---
Freezing Point
Not available.
Vapor Pressure
<1 kPa
Melting Point
Not available.
Appearance
Liquid. [limpid]
Relative Evaporation Rate
---
Density
0.82 to 0.845 g/cm³
Physical State Data
liquid
Flammability
Flammable in the presence of the following materials or conditions: open flames, sparks and static discharge.
Colour
Red.
Upper Explosive Limit
5%
Auto Ignition Temperature
>250°C
Crystallisation Point
---
Dynamic Viscosity
---
Physical State
Liquid.
Vapor Density
>5 [Air = 1]
Colour Intensity
---
Flash Point
>55°C
Evaporation Rate
Not available.
Kinematic Viscosity
<7 mm²/s
Decomposition Temperature
Not available.
Lower Explosive Limit
0.5%
Explosive Limits
---
Ph
Not applicable. Product is non-soluble (in water).
Cloud Point
---
Molecular Weight
---
Voc Content
---
Odor Threshold
Not available.
Properties Status
---
Bulk Density
---
Form
---
Odor
Characteristic.
Boiling Point
150 to 380°C
State Under Standard Conditions
---
Relative Density
0.82 to 0.845
Solubility In Water
Not soluble
Solubility In Fat
---
Solubility
Not soluble
Solidification Point
---
Partition Coefficient
Not applicable.
Metal Corrosion
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (see Section 7).

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Take precautionary measures against static discharges.

Incompatible

Reactive or incompatible with the following materials: strong acids, Strong oxidizing agents, Strong bases, Halogens

Decomposition

Use as a fuel.: Carbon dioxide (CO₂), carbon monoxide, nitrogen oxides (NO, NO₂ etc.), various hydrocarbons, Aldehyde. Soot.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of waste product or used containers according to local regulations.

Disposal

Dispose of waste product or used containers according to local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1202
Shipping Name
GAS OIL
Transport Class
3
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

See exposure scenarios

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for GASOIL DIESEL OFF ROAD?

The signal word is danger.

What is the physical form of GASOIL DIESEL OFF ROAD?

GASOIL DIESEL OFF ROAD is a liquid. appearing as liquid. [limpid] with red. color. It has characteristic. odor.

What is the solubility of GASOIL DIESEL OFF ROAD?

Not soluble

What is GASOIL DIESEL OFF ROAD used for?

Formulation & (re)packing of substances and mixtures - Industrial, Use as a fuel - Industrial, Use as a fuel - Professional, Use as a fuel - Consumer

What are the hazard statements for GASOIL DIESEL OFF ROAD?

This substance has 7 hazard statements:

  • H226: Flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H332: Harmful if inhaled.
  • H351: Suspected of causing cancer.
  • H373: May cause damage to organs through prolonged or repeated exposure. (bone marrow, liver, thymus)
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of GASOIL DIESEL OFF ROAD?

The melting point is Not available. and the boiling point is 150 to 380°C.

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