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Safety Data Sheet EN

1,1-Dichloropropane

CAS 78-99-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1,1-Dichloropropane
Product Code
272973

Regulatory Identifiers

CAS Number
78-99-9 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

global supplier

3050 Spruce Street SAINT LOUIS MO 63103 USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2A H319
Carc. Cat. 2 H351
STOT SE Cat. 3 H335
Aquatic Acute Cat. 3 H402
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
P281 Use personal protective equipment as required.
P303+P361+P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P370+P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
N/A --- 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) Splash contact Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 60 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Density
---
Physical State
liquid
Solubility In Water
No data available
Solubility
No data available
Odor Threshold
No data available
Vapor Pressure
No data available
Flash Point
7 °℃ (45 °F) - closed cup
Softening Point
---
Dynamic Viscosity
No data available
Explosive Limits
---
Lower Explosive Limit
Lower explosion limit: 3.1 %(V)
Form
clear, liquid
Molecular Weight
---
Flammability
No data available
Boiling Point
88 ℃ (190 °F)
Crystallisation Point
---
Cloud Point
---
Voc Content
---
Solidification Point
---
Physical State Data
liquid
Odor
No data available
Evaporation Rate
No data available
Melting Point
No data available
Auto Ignition Temperature
No data available
Solubility In Fat
---
Colour
colourless
Metal Corrosion
---
State Under Standard Conditions
---
Relative Density
1.13 g/mL at 25 ℃ (77 ºF)
Colour Intensity
---
Ph
No data available
Bulk Density
---
Partition Coefficient
No data available
Decomposition Temperature
No data available
Upper Explosive Limit
---
Vapor Density
No data available
Appearance
clear, liquid
Kinematic Viscosity
---
Relative Evaporation Rate
---
Properties Status
---
Freezing Point
No data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1993
Shipping Name
Flammable liquids, n.o.s. (1,1-Dichloropropane)
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 1,1-Dichloropropane?

The signal word is danger.

What is the physical form of 1,1-Dichloropropane?

1,1-Dichloropropane is a liquid appearing as clear, liquid with colourless color. It has no data available odor.

What is the solubility of 1,1-Dichloropropane?

No data available

What is 1,1-Dichloropropane used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for 1,1-Dichloropropane?

This substance has 7 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of 1,1-Dichloropropane?

The melting point is No data available and the boiling point is 88 ℃ (190 °F).

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