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Chloropicrin

DANGER liquid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Chloropicrin
Product Code
442521

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Identified Uses
Laboratory chemicals, Synthesis of substances

Overview

Chloropicrin is a clear, liquid substance commonly used laboratory chemicals, synthesis of substances.

Manage Your Safety Data Sheets

Organize and access your chemical safety data with ease.

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Acute Tox. Category 3 H301
Acute Tox. Category 1 H330
Skin Irr. Category 2 H315
Eye Irrit. Category 2A H319
Skin Sens. Category 1 H317
STOT SE Category 3 H335
Aquatic Acute Category 1 H400
Aquatic Chronic Category 1 H410

GHS Hazard Pictograms & Safety Symbols

GHS06 GHS Hazard Pictogram: Acute toxicity hazard - Poisonous materials that can cause death or serious harm

GHS06

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS09 GHS Hazard Pictogram: Environmental hazard - Materials toxic to aquatic life and environment

GHS09

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H301: Toxic if swallowed.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H330: Fatal if inhaled.
  • H335: May cause respiratory irritation.
  • H410: Very toxic to aquatic life with long lasting effects.

Precautionary Statements

  • P260: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
  • P264: Wash skin thoroughly after handling.
  • P270: Do not eat, drink or smoke when using this product.
  • P271: Use only outdoors or in a well-ventilated area.
  • P272: Contaminated work clothing should not be allowed out of the workplace.
  • P273: Avoid release to the environment.
  • P280: Wear eye protection/ face protection.
  • P280: Wear protective gloves.
  • P284: Wear respiratory protection.
  • IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
  • P302+P352: IF ON SKIN: Wash with plenty of soap and water.
  • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
  • P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P333+P313: If skin irritation or rash occurs: Get medical advice/ attention.
  • P337+P313: If eye irritation persists: Get medical advice/ attention.
  • P362: Take off contaminated clothing and wash before reuse.
  • P391: Collect spillage.
  • P403+P233: Store in a well-ventilated place. Keep container tightly closed.
  • P405: Store locked up.
  • P501: Dispose of contents/ container to an approved waste disposal plant.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Sigma-Aldrich

manufacturer

πŸ“

3050 Spruce Street, SAINT LOUIS MO 63103, USA

🌍

US

πŸ“ž

+1 800-325-5832

πŸ“ 

+1 800-325-5052

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

CHEMTREC

πŸ“ž

+1-703-527-3887

🌍

US

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
Chloropicrin
EC: 200-930-9
76-06-2 100% ⚠️ Hazardous

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

🫁 Inhalation Exposure

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

πŸ–οΈ Skin Contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

πŸ‘οΈ Eye Contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

🍽️ Ingestion/Swallowing

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Fire Fighting Measures & Emergency Response

Fire suppression methods, extinguishing media, and firefighting safety procedures

βœ… Suitable Extinguishing Media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

πŸ”₯ Fire Fighting Instructions

Wear self-contained breathing apparatus for firefighting if necessary.

Accidental Release Measures & Spill Response

Emergency spill cleanup procedures, containment methods, and environmental protection

🚨 Emergency Procedures

Evacuate personnel to safe areas.

🌍 Environmental Precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

🧹 Cleanup Methods

Dispose of as hazardous waste.

Cleanup Materials:

Keep in suitable, closed containers for disposal.

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

πŸ§ͺ Physical State
liquid
Critical Property
πŸ“Š Physical State Data
liquid
πŸ“Š State Under Standard Conditions
Not available
πŸ‘οΈ Appearance
clear, liquid
🎨 Colour
light brown
πŸ“Š Colour Intensity
Not available
πŸ“Š Form
clear, liquid
πŸ‘ƒ Odor
Not available
πŸ“Š Odor Threshold
Not available
πŸ§ͺ Ph
Not available
🧊 Melting Point
Not available
πŸ’¨ Boiling Point
112 °℃ (234 ΒΊF)
Critical Property
πŸ”₯ Flash Point
Not available
πŸ“Š Freezing Point
Not available
πŸ“Š Softening Point
Not available
πŸ“Š Solidification Point
Not available
πŸ“Š Cloud Point
Not available
πŸ“Š Crystallisation Point
Not available
πŸ“Š Relative Evaporation Rate
Not available
πŸ’¨ Evaporation Rate
Not available
πŸ’¨ Vapor Pressure
Not available
πŸ“Š Vapor Density
Not available
πŸ“Š Relative Density
1.657 g/cm3 at 25 ℃ (77 ΒΊF)
πŸ“Š Bulk Density
Not available
βš–οΈ Density
Not available
πŸ”₯ Flammability
Not available
πŸ“Š Upper Explosive Limit
Not available
πŸ“Š Lower Explosive Limit
Not available
πŸ“Š Explosive Limits
Not available
πŸ“Š Auto Ignition Temperature
Not available
πŸ“Š Decomposition Temperature
Not available
πŸ’§ Solubility
Not available
πŸ“Š Partition Coefficient
Not available
πŸ“Š Solubility In Water
Not available
πŸ“Š Solubility In Fat
Not available
πŸ“Š Molecular Weight
Not available
πŸ“Š Voc Content
Not available
πŸ“Š Metal Corrosion
Not available
πŸ“Š Dynamic Viscosity
Not available
πŸ“Š Kinematic Viscosity
Not available
πŸ“Š Properties Status
Not available

Safe Handling & Storage Procedures

Industrial handling precautions, storage conditions, and workplace safety requirements

⚠️ Handling Precautions

β€’ Avoid contact with skin and eyes.

β€’ Avoid inhalation of vapour or mist.

πŸͺ Storage Conditions

β€’ Keep container tightly closed in a dry and well-ventilated place.

β€’ Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

🏭 Engineering Controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

🧀 Hand Protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

πŸ‘οΈ Eye Protection

Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

😷 Respiratory Protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

🦺 Skin/Body Protection

Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

🌍 Environmental Exposure Controls

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Chemical Stability & Reactivity Data

Chemical stability, hazardous reactions, and incompatible materials information

βœ… Chemical Stability

Stable under recommended storage conditions.

πŸ§ͺ Incompatible Materials

Metals, Amines, Strong bases

πŸ’¨ Hazardous Decomposition Products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Ecological Information & Environmental Impact

Environmental toxicity, biodegradation, bioaccumulation, and ecological effects data

🌱 Toxicity

Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 0.016 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia pulex (Water flea) - 0.063 mg/l - 48 h

🌱 Persistence and degradability

No data available

🌱 Bioaccumulative potential

No data available

🌱 Mobility in soil

No data available

🌱 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

🌱 Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life. No data available

Waste Disposal & Treatment Methods

Waste disposal procedures, treatment methods, and regulatory compliance requirements

♻️ Waste Treatment Methods

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

πŸ—‚οΈ Product Disposal Recommendations

Dispose of as unused product.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

🏷️ UN Number

1580

πŸ“¦ Proper Shipping Name

Chloropicrin

⚠️ Transport Hazard Class

6.1

πŸ“‹ Packing Group

I

Regulatory Information & Compliance

Chemical regulations, safety assessments, and regulatory compliance status

πŸ“‹ Regulatory Summary

No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. The following components are subject to reporting levels established by SARA Title III, Section 313: Chloropicrin (CAS-No. 76-06-2). This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

❌ Chemical Safety Assessment

No chemical safety assessment has been performed for this substance.

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Chloropicrin?

The signal word for this substance is "danger".

What is the physical form of Chloropicrin?

Chloropicrin is a liquid appearing as clear, liquid with light brown color.

What is Chloropicrin used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Chloropicrin?

This substance has 7 hazard statements: H301: Toxic if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H330: Fatal if inhaled. H335: May cause respiratory irritation. H410: Very toxic to aquatic life with long lasting effects.