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Safety Data Sheet EN

Potassium sulfide

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Potassium sulfide
Product Code
42104

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

Alfa Aesar, A Johnson Matthey Company logo

Alfa Aesar, A Johnson Matthey Company

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Johnson Matthey Catalog Company, Inc. logo

Johnson Matthey Catalog Company, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Emergency Contacts

Alfa Aesar

(978) 521-6300

CHEMTREC

(800) 424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Self-heat. Cat. 1
Skin Corr. Cat. 1
Aquatic Acute Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS09 - Environmental hazard

GHS09

Hazard Statements

H251 Self-heating: may catch fire.
H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.

Precautionary Statements

P235 Keep cool.
P235 Store away from other materials.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P341 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see label).
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 Maintain air gap between stacks/pallets.
P405 Store locked up.
P410 Protect from sunlight.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Potassium sulfide 1312-73-8 44% No
Mixed potassium sulfides --- --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Seek immediate medical advice.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, sand, extinguishing powder.

Unsuitable media

Water

Specific hazards

In case of fire, the following can be released: Sulfur oxides (SOx), Hydrogen sulfide

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not allow material to be released to the environment without proper governmental permits.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the workplace.

Storage

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers.

Fire prevention

Reacts with acids forming hydrogen sulfide

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. Material of gloves: The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.

Eyes

Safety glasses, Tightly sealed goggles, Full face protection

Respiratory

Use suitable respirator when high concentrations are present.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Lump
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
Red-brown
Colour Intensity
---
Form
Lump
Odor
Not determined
Odor Threshold
---
Ph
---
Melting Point
Not determined
Boiling Point
Not determined
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not determined
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1.805 g/cm³
Flammability
---
Upper Explosive Limit
Not determined
Lower Explosive Limit
Not determined
Explosive Limits
---
Auto Ignition Temperature
Not determined
Decomposition Temperature
Not determined
Solubility
Soluble
Partition Coefficient
---
Solubility In Water
Soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Decomposition will not occur if used and stored according to specifications.

Reactivity

No dangerous reactions known

Hazardous reactions

No dangerous reactions known

Avoid

Decomposition will not occur if used and stored according to specifications.

Incompatible

Acids, Oxidizing agents

Decomposition

Sulfur oxides (SOx), Hydrogen sulfide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1382
Shipping Name
POTASSIUM SULPHIDE
Transport Class
4.2
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Hazard symbols: C (Corrosive), N (Dangerous for the environment). Risk phrases: 31, 34, 50. Safety phrases: 20, 26, 36/37/39, 45, 57. Information about limitation of use: For use only by technically qualified individuals.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Potassium sulfide?

The signal word is danger.

What is the physical form of Potassium sulfide?

Potassium sulfide is a lump with red-brown color. It has not determined odor.

What is the solubility of Potassium sulfide?

Soluble

What are the hazard statements for Potassium sulfide?

This substance has 3 hazard statements:

  • H251: Self-heating: may catch fire.
  • H314: Causes severe skin burns and eye damage.
  • H400: Very toxic to aquatic life.

What is the melting point of Potassium sulfide?

The melting point is Not determined and the boiling point is Not determined.