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Safety Data Sheet EN

Azinphos-methyl

CAS 86-50-0
EC 201-676-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Azinphos-methyl
Product Code
45333
Chemical Name
Methyltriazotin Guthion

Regulatory Identifiers

CAS Number
86-50-0 Check regulations →
EC Number
201-676-1 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street SAINT LOUIS MO 63103 USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 2 H300
Acute Tox. Cat. 1 H330
Acute Tox. Cat. 3 H311
Skin Sens. Cat. 1 H317
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS09 - Environmental hazard

GHS09

Hazard Statements

H300 Fatal if swallowed or if inhaled.
H311 Toxic in contact with skin.
H317 May cause an allergic skin reaction.
H330 Fatal if swallowed or if inhaled.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing.
P284 Wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P310 Immediately call a POISON CENTER/doctor.
P320 Specific treatment is urgent (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P361 Remove/Take off immediately all contaminated clothing.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
Methyltriazotin Guthion EC: 201-676-1 86-50-0 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Flush eyes with water as a precaution.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact: Material: Nitrile rubber, Minimum layer thickness: 0.11 mm, Break through time: 480 min, Material tested: Dermatril® (KCL 740 / Aldrich Z677272, Size M). Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0.11 mm, Break through time: 480 min, Material tested: Dermatril® (KCL 740 / Aldrich Z677272, Size M). Data source: KCL GmbH, test method: EN374. If used in solution or mixed with other substances and under conditions which differ from EN 374, contact the supplier of the CE approved gloves.

Eyes

Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Form: solid Colour: colourless
Colour
colourless
Colour Intensity
---
Form
solid
Odor
No data available
Odor Threshold
No data available
Ph
No data available
Melting Point
48 - 50 °C (118 - 122 °F)
Boiling Point
200 °C (392 ºF) at 1,013 hPa (760 mmHg)
Flash Point
No data available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
No data available
Vapor Density
No data available
Relative Density
1.440 g/cm3 at 20 °C (68 ºF)
Bulk Density
---
Density
---
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
insoluble
Partition Coefficient
No data available
Solubility In Water
insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2811
Shipping Name
Toxic solid, organic, n.o.s. (Azinphos-methyl)
Transport Class
6.1
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Azinphos-methyl?

The signal word is danger.

What is the physical form of Azinphos-methyl?

Azinphos-methyl is a solid appearing as form: solid colour: colourless with colourless color. It has no data available odor.

What is the solubility of Azinphos-methyl?

insoluble

What is Azinphos-methyl used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Azinphos-methyl?

This substance has 5 hazard statements:

  • H300: Fatal if swallowed or if inhaled.
  • H311: Toxic in contact with skin.
  • H317: May cause an allergic skin reaction.
  • H330: Fatal if swallowed or if inhaled.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Azinphos-methyl?

The melting point is 48 - 50 °C (118 - 122 °F) and the boiling point is 200 °C (392 ºF) at 1,013 hPa (760 mmHg).

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