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Safety Data Sheet EN

Hexamethylenediamine 100%

CAS 124-09-4
EC 204-679-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hexamethylenediamine 100%
Chemical Name
hexamethylenediamine

Regulatory Identifiers

CAS Number
124-09-4 Check regulations →
EC Number
204-679-6 Check regulations →

Identified Uses

for the production of homopolymerisates and copolymerisates, initial product for chemical syntheses

Manufacturers & Suppliers

B

BASF SE

manufacturer

67056 Ludwigshafen, GERMANY

+49 621 60 42737

Emergency Contacts

Emergency Contact

+49 180 2273-112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS05 - Corrosive

GHS05

Hazard Statements

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P260 Do not breathe dust/gas/mist/vapours.
P264 Wash contaminated body parts thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, protective clothing and eye protection or face protection.
P301+P330 IF SWALLOWED: rinse mouth.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or physician.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents and container to hazardous or special waste collection point.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

hexamethylenediamine

Chemical Name CAS Number Concentration Hazardous
hexamethylenediamine EC: 204-679-6 124-09-4 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Keep patient calm, remove to fresh air, seek medical attention.

Skin contact

Remove contaminated clothing and dispose of safely to prevent any exposure. Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist. Burns caused by molten material require hospital treatment. Areas affected by molten material should be quickly placed under cold running water.

Eye contact

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Ingestion

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention. Do not induce vomiting.

Medical Treatment

Treat according to symptoms (decontamination, vital functions), no known specific antidote.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Chemical resistant protective gloves (EN ISO 374-1) chloroprene rubber (CR) - 0.5 mm coating thickness nitrile rubber (NBR) - 0.4 mm coating thickness polyvinylchloride (PVC) - 0.7 mm coating thickness Manufacturer's directions for use should be observed because of great diversity of types.

Eyes

Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Respiratory

Breathing protection if gases/vapours are formed. Gas filter for gases/vapours of alkaline compounds such as ammonia, amines (e.g. EN 14387 Type K).

Skin/Body

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
melt
Odor
amine-like
Odor Threshold
---
Ph
12,4
Melting Point
41 ℃
Boiling Point
201 ℃
Flash Point
85 ℃
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
0,26 hPa (20 ℃)
Vapor Density
---
Relative Density
0,978
Bulk Density
---
Density
0,84 g/cm3
Flammability
not highly flammable
Upper Explosive Limit
7,6 %(V)
Lower Explosive Limit
0,9 %(V)
Explosive Limits
---
Auto Ignition Temperature
305 ℃
Decomposition Temperature
not determined
Solubility
637 g/l
Partition Coefficient
n-octanol/water (log Kow): 0,44 (25 ℃; pH value: approx. 13)
Solubility In Water
637 g/l
Solubility In Fat
---
Molecular Weight
116,21 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1 mPa.s
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2280
Shipping Name
HEXAMETHYLENEDIAMINE, SOLID MOLTEN
Transport Class
8
Packing Group
III
ADR

Tunnel code: E

IMDG

EmS: F-A; S-B

IATA

None known

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hexamethylenediamine 100%?

The signal word is danger.

What is the physical form of Hexamethylenediamine 100%?

Hexamethylenediamine 100% is a liquid with colourless color. It has amine-like odor.

What is the solubility of Hexamethylenediamine 100%?

637 g/l

What is Hexamethylenediamine 100% used for?

for the production of homopolymerisates and copolymerisates, initial product for chemical syntheses

What are the hazard statements for Hexamethylenediamine 100%?

This substance has 5 hazard statements:

  • H302: Harmful if swallowed.
  • H312: Harmful in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H318: Causes serious eye damage.
  • H335: May cause respiratory irritation.

What is the melting point of Hexamethylenediamine 100%?

The melting point is 41 ℃ and the boiling point is 201 ℃.

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