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Safety Data Sheet EN

Barium hydroxide octahydrate

CAS 12230-71-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Barium hydroxide octahydrate
Product Code
P009
Chemical Name
Barium hydroxide octahydrate

Regulatory Identifiers

CAS Number
12230-71-6 Check regulations →

Identified Uses

Laboratory chemical, Laboratory and analytical use

Uses advised against

Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin. Do not use for private purposes (household). Food, drink and animal feedingstuffs.

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe, Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

NSW Poisons Information Centre Childrens Hospital

131126

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled
H314 Causes severe skin burns and eye damage

Precautionary Statements

P260 Do not breathe dusts or mists
P280 Wear eye protection/face protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P321 Specific treatment (see on this label)
P501 Dispose of contents/container to industrial combustion plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Barium hydroxide octahydrate 98 %, p.a., ACS, ISO

Chemical Name CAS Number Concentration Hazardous
Barium hydroxide octahydrate 12230-71-6 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Skin contact

After contact with skin, wash immediately with plenty of water. Immediate medical treatment required because corrosive injuries that are not treated are hard to cure.

Symptoms: Corrosion

Eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye.

Symptoms: Risk of blindness, Risk of serious damage to eyes

Ingestion

Rinse mouth immediately and drink plenty of water. Rinse mouth with water (only if the person is conscious). Call a physician immediately. If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects).

Symptoms: Vomiting, Gastric perforation

Immediate Medical Attention

Immediate medical treatment required because corrosive injuries that are not treated are hard to cure. Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder

Unsuitable media

water jet

Specific hazards

Non-combustible.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

In case of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus. Wear full chemical protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe dust.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Take up mechanically.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle and open container with care. Avoid dust formation. Clear contaminated areas thoroughly.

Storage

Store in a dry place.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. Type of material: NBR (Nitrile rubber). Material thickness: ≥0,3 mm. Breakthrough times of the glove material: >480 minutes (permeation: level 6).

Eyes

Use safety goggle with side protection. Wear face protection.

Respiratory

Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P2 (filters at least 94 % of airborne particles, colour code: White).

Skin/Body

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Evaporation Rate
---
Vapor Density
---
Auto Ignition Temperature
not determined
Physical State
solid
Properties Status
---
Explosive Limits
---
Dynamic Viscosity
---
Kinematic Viscosity
not relevant
Form
---
Density
2.18 g/cm³ at 20 °C
Ph
12.5 (in aqueous solution: 50 g/l, 20 °C)
Vapor Pressure
not determined
Molecular Weight
---
Physical State Data
solid
Appearance
---
Flammability
non-combustible
Lower Explosive Limit
not relevant (solid)
Softening Point
---
Solubility In Water
72 g/l at 20 °C
Colour
white
Voc Content
---
Solidification Point
---
State Under Standard Conditions
---
Flash Point
not applicable
Upper Explosive Limit
not relevant (solid)
Colour Intensity
---
Freezing Point
78 °C
Partition Coefficient
not relevant (inorganic)
Boiling Point
not determined
Crystallisation Point
---
Solubility In Fat
---
Solubility
---
Relative Evaporation Rate
---
Melting Point
78 °C
Cloud Point
---
Odor
odourless
Odor Threshold
---
Decomposition Temperature
78 °C
Relative Density
---
Metal Corrosion
---
Bulk Density
900 – 1,100 kg/m³
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

This material is not reactive under normal ambient conditions.

Hazardous reactions

Dangerous/dangerous reactions with: Acids, Hydrogen sulphide (H₂S)

Avoid

Keep away from heat. Decomposition takes place from temperatures above: 78 °C at 1,013 hPa.

Incompatible

Light metals, aluminium, zinc, tin

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

Waste Codes

H8 Corrosives Basel Convention
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3262
Shipping Name
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S.
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Directive 94/33/EC on the protection of young people at work. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Barium hydroxide octahydrate?

The signal word is danger.

What is the physical form of Barium hydroxide octahydrate?

Barium hydroxide octahydrate is a solid with white color. It has odourless odor.

What is Barium hydroxide octahydrate used for?

Laboratory chemical, Laboratory and analytical use

What are the hazard statements for Barium hydroxide octahydrate?

This substance has 2 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled
  • H314: Causes severe skin burns and eye damage

What is the melting point of Barium hydroxide octahydrate?

The melting point is 78 °C and the boiling point is not determined.