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Safety Data Sheet EN

Lithium primary cylindrical cell

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Lithium primary cylindrical cell
Product Form
cylindrical cell

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

V

VARTA Microbattery GmbH

manufacturer

Daimlerstr. 1, D-73479 Ellwangen/Jagst, Germany

Emergency Contacts

VAC

+49 7961 921 110

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

Hazard Statements

If in case of mistreatment the ingredients are released, a spontaneously flammable gas mixture may be released under certain circumstances (measures according to chapter 4 to 6).
Attention: If batteries are treated wrong the danger of burns or bursts occurs.
If the negative electrode gets in contact with water or humidity hydrogen gas is formed, which may inflame spontaneously.

Precautionary Statements

Batteries must not be heated above 100°C or incinerated.
The battery contents must not get in contact with water.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Lithium 7439-93-2 1 - 3% Yes
Manganese dioxide 1313-13-9 13 - 40% Yes
Propylene carbonate 108-32-7 10% Yes
1,2-Dimethoxy ethane 110-71-4 10% Yes
Lithium perchlorate 7791-03-9 5% Yes
Steel and nickel --- 33 - 74% No
Plastic --- 3 - 10% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Fresh air. Seek for medical assistance.

Skin contact

Remove solid particles immediately. Flush affected areas with plenty of water (at least 15 min.). Remove contaminated cloth immediately. Seek for medical assistance.

Eye contact

Flush the eye gently with plenty of water (at least 15 min.). Seek for medical assistance.

Ingestion

Drink plenty of water. Avoid vomiting. Seek for medical assistance. No trials for neutralization.

Immediate Medical Attention

Seek for medical assistance.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Metal fire extinction powder, rock salt or dry sand shall be used. In case only water is available, it can be used in large amounts.

Unsuitable media

Carbon dioxide (CO₂) is not suitable. Water in small quantities may have adverse effects.

Specific hazards

Cells may explode and release metal parts. At contact of anode material with water extremely flammable hydrogen gas and caustic liquid are released.

Firefighter Protection

Protective clothing including breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Bind released ingredients with powder (rock salt, sand). Dispose off according to the local law and rules. Avoid leached substances to penetrate into the earth, canalization or water.

Cleanup methods

Package the battery tightly including ingredients together with lime, sand or rock salt. Then clean with water.

Materials: lime, sand or rock salt

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Always follow the warning information on the batteries and in the manuals of devices. Only use the recommended battery types. Keep batteries away from children. For devices to be used by children, the battery casing should be protected against unauthorized access. Unpacked batteries shall not lie about in bulk. In case of battery change always replace all batteries by new ones of identical type and brand. Do not swallow batteries. Do not throw batteries into water. Do not throw batteries into fire. Do not short-circuit batteries. Do not recharge primary batteries. Do not open or disassemble batteries.

Storage

Storage preferably at room temperature (approx. 20°C). Avoid large temperature changes. Avoid direct sunlight. At higher temperature the electrical performance may be reduced. Storage of unpacked batteries can cause short circuit and heat generation. If possible, store the batteries in original packaging (because of short circuit protection and exemptions according to transport regulations).

Fire prevention

Do not throw batteries into fire. Do not short-circuit batteries. The storage area shall be monitored by an automatic fire detection system, connected to a permanently manned place. A fire-extinguishing system shall reflect the extinguishing agents mentioned in chapter 5.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

The data for this section has not been processed yet.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

The data for this section has not been processed yet.

10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Hazardous reactions

When heated above 100°C the risk of rupture occurs.

Avoid

heated above 100°C

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

USA: Lithium primary round cells are classified by the federal government as non-hazardous waste and are safe for disposal in the normal municipal waste stream. In the European Union, manufacturing, handling and disposal of batteries is regulated on the basis of the DIRECTIVE 2006/66/EC. Importers and users outside EU should consider the local law and rules.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3090
Shipping Name
Lithium Metal Batteries
ADR

During the transportation of large amounts of batteries by ship, trailer or railway, do not store them in places of high temperature and do not allow them to be exposed to condensation. During the transportation do not allow the packaging to be damaged, as a damage of the packaging may cause fire. In the event packaging is damaged, special procedures must be used including inspection and repackaging if necessary and handle with care.

IMDG

During the transportation of large amounts of batteries by ship, trailer or railway, do not store them in places of high temperature and do not allow them to be exposed to condensation. During the transportation do not allow the packaging to be damaged, as a damage of the packaging may cause fire. In the event packaging is damaged, special procedures must be used including inspection and repackaging if necessary and handle with care.

IATA

During the transportation of large amounts of batteries by ship, trailer or railway, do not store them in places of high temperature and do not allow them to be exposed to condensation. During the transportation do not allow the packaging to be damaged, as a damage of the packaging may cause fire. In the event packaging is damaged, special procedures must be used including inspection and repackaging if necessary and handle with care. The outside of each package that contains primary (non-rechargeable) lithium batteries or cells must be marked "PRIMARY LITHIUM BATTERIES-FORBIDDEN FOR TRANSPORT ABOARD PASSENGER AIRCRAFT" on a background of contrasting color.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Lithium primary cells are articles and not substances, thus there is no risk of water pollution, except the batteries are violated or dismantled.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Lithium primary cylindrical cell?

The signal word is no signal word.

What are the hazard statements for Lithium primary cylindrical cell?

This substance has 3 hazard statements:

  • If in case of mistreatment the ingredients are released, a spontaneously flammable gas mixture may be released under certain circumstances (measures according to chapter 4 to 6).
  • Attention: If batteries are treated wrong the danger of burns or bursts occurs.
  • If the negative electrode gets in contact with water or humidity hydrogen gas is formed, which may inflame spontaneously.