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Safety Data Sheet EN

N,N-Dimethylformamide ROTISOLV® HPLC

CAS 68-12-2
EC 200-679-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
N,N-Dimethylformamide ROTISOLV® HPLC
Product Code
0702
Chemical Name
N,N-Dimethylformamide

Regulatory Identifiers

CAS Number
68-12-2 Check regulations →
EC Number
200-679-5 Check regulations →
REACH No.
01-2119475605-32-xxxx

Identified Uses

Laboratory chemical, Laboratory and analytical use

Uses advised against

Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household). Food, drink and animal feeding-stuffs.

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe, Germany

+49 (0) 721 - 56 06 0

www.carlroth.de

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332
Eye Irrit. Cat. 2 H319
Repr. Cat. 1B H360D

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour
H312 + H332 Harmful in contact with skin or if inhaled
H319 Causes serious eye irritation
H360D May damage the unborn child

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308 + P313 IF exposed or concerned: Get medical advice/attention

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
N,N-Dimethylformamide EC: 200-679-5 68-12-2 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Skin contact

Rinse skin with water/shower.

Eye contact

Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of eye irritation consult an ophthalmologist.

Immediate Medical Attention

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)

Unsuitable media

water jet

Specific hazards

Combustible. In case of insufficient ventilation and/or in use, may form flammable/explosive vapour-air mixture. Solvent vapours are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures. Vapours are heavier than air, spread along floors and form explosive mixtures with air. Vapours may form explosive mixtures with air.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

In case of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray. Avoidance of ignition sources.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). Place in appropriate containers for disposal.

Materials: sand, diatomaceous earth, acid- or universal binding agents

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provision of sufficient ventilation. Avoid exposure.

Storage

Keep container tightly closed.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. When using do not smoke.

Fire prevention

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Ground/bond container and receiving equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Type of material: Butyl caoutchouc (butyl rubber). Material thickness: ≥0,5 mm. Breakthrough times of the glove material: >480 minutes (permeation: level 6).

Eyes

Use safety goggle with side protection.

Respiratory

Respiratory protection necessary at: Aerosol or mist formation. Type: A (against organic gases and vapours with a boiling point of > 65 °C, colour code: Brown).

Skin/Body

Preventive skin protection (barrier creams/ointments) is recommended.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solidification Point
---
Vapor Density
---
Evaporation Rate
---
Odor
like: - amine
Decomposition Temperature
>350 °C
Solubility In Fat
---
Upper Explosive Limit
500 g/m³ (UEL) / 16 vol% (UEL)
Lower Explosive Limit
70 g/m³ (LEL) / 2,2 vol% (LEL)
Auto Ignition Temperature
435 °C at 1.013 hPa
Voc Content
---
Solubility In Water
miscible in any proportion
Colour Intensity
---
Physical State Data
liquid
Softening Point
---
Flash Point
57,5 °C at 1.013 hPa (ECHA)
Metal Corrosion
---
Physical State
liquid
Relative Density
---
Density
0,95 g/cm³ at 20 °C
Solubility
---
Bulk Density
---
Explosive Limits
---
Cloud Point
---
Flammability
flammable liquid in accordance with GHS criteria
Boiling Point
153 °C at 1.013 hPa
Crystallisation Point
---
Molecular Weight
---
Partition Coefficient
-1,01 (TOXNET)
Vapor Pressure
3,77 hPa at 20 °C
Dynamic Viscosity
0,85 mPa s at 20 °C
Colour
colourless
State Under Standard Conditions
---
Odor Threshold
0,329 ppm
Kinematic Viscosity
0,8947 mm²/s at 20 °C
Appearance
---
Ph
7 (in aqueous solution: 200 g/l, 20 °C)
Melting Point
-61 °C
Properties Status
---
Form
---
Relative Evaporation Rate
---
Freezing Point
-61 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

It's a reactive substance. Risk of ignition. If heated Risk of ignition. Vapours may form explosive mixtures with air.

Hazardous reactions

Violent reaction with: strong oxidiser, Permanganates, for example potassium permanganate, Phosphorus oxides (e.g. P2O5)

Avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep away from heat. Decomposition takes place from temperatures above: >350 °C.

Incompatible

different plastics, copper, tin

Decomposition

Hazardous combustion products: see section 5. Release of: Formaldehyde. Ammonia (NH3).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2265
Shipping Name
N,N-DIMETHYLFORMAMIDE
Transport Class
3
Packing Group
III
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

According to REACH, Article 14 (1) a chemical safety assessment has been carried out for this substance or components of this mixture when the substance has been registered in quantities of 10 tonnes or more per year per registrant.

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for N,N-Dimethylformamide ROTISOLV® HPLC?

The signal word is danger.

What is the physical form of N,N-Dimethylformamide ROTISOLV® HPLC?

N,N-Dimethylformamide ROTISOLV® HPLC is a liquid with colourless color. It has like: - amine odor.

What is N,N-Dimethylformamide ROTISOLV® HPLC used for?

Laboratory chemical, Laboratory and analytical use

What are the hazard statements for N,N-Dimethylformamide ROTISOLV® HPLC?

This substance has 4 hazard statements:

  • H226: Flammable liquid and vapour
  • H312 + H332: Harmful in contact with skin or if inhaled
  • H319: Causes serious eye irritation
  • H360D: May damage the unborn child

What is the melting point of N,N-Dimethylformamide ROTISOLV® HPLC?

The melting point is -61 °C and the boiling point is 153 °C at 1.013 hPa.