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Safety Data Sheet EN

Metam-sodium (ISO)

CAS 137-42-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Metam-sodium (ISO)
Product Code
A0044728
Synonyms
sodium methyldithiocarbamate

Regulatory Identifiers

CAS Number
137-42-8 Check regulations →

Identified Uses

General use

Uses advised against

Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin.

Manufacturers & Suppliers

Chemos GmbH & Co. KG logo

Chemos GmbH & Co. KG

Sonnenring 7 84032 Altdorf Germany

+49 871-966346-0

http://www.chemos.de/

Emergency Contacts

Emergency information service

+49 89 1 92 40

National Poison Information Centre Medical Toxicology Unit

+44 171 635 91 91

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P501 Dispose of contents/container to industrial combustion plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
metam-sodium (ISO) EC: 205-293-0 137-42-8 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respiratory tract irritation, consult a physician. Provide fresh air.

Skin contact

Wash with plenty of soap and water.

Eye contact

Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.

Ingestion

Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, BC-powder, Carbon dioxide (CO2)

Unsuitable media

Water jet

Specific hazards

Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2), Sulphur oxides (SOx)

Instructions

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

In case of fire and/or explosion do not breathe fumes.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

For non-emergency personnel: Remove persons to safety. For emergency responders: Wear breathing apparatus if exposed to vapours/dust/spray/gases.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. If substance has entered a water course or sewer, inform the responsible authority.

Cleanup methods

Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage.

Materials: absorbent material (e.g. cloth, fleece), sawdust, kieselgur (diatomite), sand, universal binder

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Measures to prevent fire as well as aerosol and dust generation. Use local and general ventilation. Use only in well-ventilated areas.

Hygiene

Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

Fire prevention

Measures to prevent fire as well as aerosol and dust generation. Use local and general ventilation.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Appropriate engineering controls. General ventilation.

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

Eyes

Wear eye/face protection.

Respiratory

In case of inadequate ventilation wear respiratory protection.

Environmental

Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Density
information on this property is not available
Form
---
Kinematic Viscosity
---
Softening Point
---
Crystallisation Point
---
Solubility In Fat
---
Density
not determined
Physical State Data
liquid
Auto Ignition Temperature
not determined
Physical State
liquid
Partition Coefficient
this information is not available
Molecular Weight
---
Appearance
---
Lower Explosive Limit
not determined
Evaporation Rate
not determined
Flash Point
not determined
Upper Explosive Limit
not determined
Metal Corrosion
---
Properties Status
---
Ph
not determined
Decomposition Temperature
---
Explosive Limits
---
Odor Threshold
---
Bulk Density
---
Relative Evaporation Rate
---
Flammability
not relevant, (fluid)
Cloud Point
---
Odor
characteristic
Dynamic Viscosity
---
Solubility
not determined
Freezing Point
not determined
Colour Intensity
---
Solubility In Water
---
Voc Content
---
Melting Point
not determined
Vapor Density
this information is not available
Boiling Point
not determined
Solidification Point
---
Vapor Pressure
not determined
State Under Standard Conditions
---
Colour
brown
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

See below "Conditions to avoid".

Reactivity

Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".

Hazardous reactions

No known hazardous reactions.

Avoid

There are no specific conditions known which have to be avoided.

Incompatible

Oxidisers Acids

Decomposition

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3267
Shipping Name
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
Transport Class
8 (corrosive substances)
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Metam-sodium (ISO) known by?

Metam-sodium (ISO) is also known as: sodium methyldithiocarbamate

What is the hazard signal word for Metam-sodium (ISO)?

The signal word is danger.

What is the physical form of Metam-sodium (ISO)?

Metam-sodium (ISO) is a liquid with brown color. It has characteristic odor.

What is the solubility of Metam-sodium (ISO)?

not determined

What is Metam-sodium (ISO) used for?

General use

What are the hazard statements for Metam-sodium (ISO)?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Metam-sodium (ISO)?

The melting point is not determined and the boiling point is not determined.