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Safety Data Sheet EN

1,4-Difluorobenzene

CAS 540-36-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1,4-Difluorobenzene
Product Code
114610000; 114610250; 114611000
Synonyms
Para-Difluorobenzene.

Regulatory Identifiers

CAS Number
540-36-3 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher Scientific

importer

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

F

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

Emergency Contacts

US call

001-800-227-6701

Europe call

+32 14 57 52 11

Emergency Number US

001-201-796-7100

Europe

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225

GHS Pictograms

GHS02 - Flammable

GHS02

Hazard Statements

H225 Highly flammable liquid and vapor

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P240 Ground and bond container and receiving equipment

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,4-Difluorobenzene EC: 208-742-9 540-36-3 99% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove from exposure, lie down. Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention.

Symptoms: Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water. Get medical attention.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray. Carbon dioxide (CO₂). Dry chemical. Chemical foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available.

Specific hazards

Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Instructions

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

See Section 12 for additional Ecological Information.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: sand, silica gel, acid binder, universal binder, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. Avoid contact with skin and clothing. Avoid breathing vapors or mists. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat, sparks and flame. Flammables area.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Keep away from heat, sparks and flame. Use spark-proof tools and explosion-proof equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use explosion-proof electrical/ventilating/lighting/equipment. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Nitrile rubber, Neoprene, Natural rubber, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Eyes

Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Respiratory

No protective equipment is needed under normal use conditions. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Small scale/Laboratory use: Maintain adequate ventilation

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Environmental

No information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Light yellow
Colour
---
Colour Intensity
---
Form
---
Odor
No information available
Odor Threshold
No data available
Ph
No information available
Melting Point
-13 °C / 8.6 °F
Boiling Point
88 - 89 °C / 190.4 - 192.2 °F
Flash Point
2 °C / 35.6 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
---
Bulk Density
Not applicable
Density
1.170
Flammability
Highly flammable
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
114.09
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous Polymerization No information available. Hazardous Reactions No information available.

Avoid

Keep away from open flames, hot surfaces and sources of ignition. Incompatible products.

Incompatible

Strong oxidizing agents. Oxidizing agent.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂). Gaseous hydrogen fluoride (HF).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1993
Shipping Name
Flammable liquid, n.o.s.
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 1,4-Difluorobenzene known by?

1,4-Difluorobenzene is also known as: Para-Difluorobenzene.

What is the hazard signal word for 1,4-Difluorobenzene?

The signal word is danger.

What is the physical form of 1,4-Difluorobenzene?

1,4-Difluorobenzene is a liquid appearing as light yellow . It has no information available odor.

What is 1,4-Difluorobenzene used for?

Laboratory chemicals.

What are the hazard statements for 1,4-Difluorobenzene?

This substance has 1 hazard statement:

  • H225: Highly flammable liquid and vapor

What is the melting point of 1,4-Difluorobenzene?

The melting point is -13 °C / 8.6 °F and the boiling point is 88 - 89 °C / 190.4 - 192.2 °F.