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Safety Data Sheet EN

Storage solution

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Storage solution

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals.

Manufacturers & Suppliers

Metrohm AG logo

Metrohm AG

manufacturer

Ionenstrasse, 9100 Herisau, Schweiz

+41 (0)71 353 85 85

http://www.metrohm.com

M

Metrohm Nordic Oy

national supplier

Vantaankoskentie 14, 01670 Vantaa, Finland

+358 (0) 10 778 6800

Emergency Contacts

Poison Center

0800 147 111

24 h / day

Poison Center

09 471 977

24 h / day

GBK GmbH

+49 (0)6132-84463

24 h

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H319 Causes serious eye irritation.

Precautionary Statements

P280 Wear eye or face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
ammonium chloride EC: 235-186-4 12125-02-9 10 - 25% Yes
reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) 55965-84-9 0.0015% Yes
copper dinitrate EC: 221-838-5 3251-23-8 0.1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No known significant effects or critical hazards.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: No known significant effects or critical hazards.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation, watering, redness

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No known significant effects or critical hazards.

Immediate Medical Attention

Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog). Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

Do not use water jet.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Absorb with liquid-binding material (sand, diatomite, universal binders etc.) or use a spill kit.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material.

Materials: inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth, liquid-binding material (sand, diatomite, universal binders etc.), spill kit

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: Wear suitable gloves tested to EN374. Material: Chloroprene, natural rubber (latex), thickness: ≥0.11mm.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: Wear tightly-sealed safety glasses. (EN 166, splash goggles)

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid. Colourless.
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Odourless.
Odor Threshold
Not available.
Ph
4.5 to 5
Melting Point
Not available.
Boiling Point
100°C
Flash Point
Not applicable.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not available.
Vapor Density
Not available.
Relative Density
Not available.
Bulk Density
---
Density
1.04249 g/cm³ [20°C]
Flammability
Not applicable.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not self-ignitable.
Decomposition Temperature
Not available.
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Miscible in water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Keep away from heat, sparks and flame.

Incompatible

Strong oxidising materials, strong acids, strong alkalis.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | --- | --- | --- | --- | --- | | ammonium chloride | Acute EC50 850 mg/l [OECD 209] | Activated sludge | 0.5 hours | - | | | Acute EC50 2700 mg/l Static | Algae - Chlorella vulgaris | 18 days | read-across | | | Acute EC50 1300 mg/l Static | Algae - Chlorella vulgaris | 5 days | read-across | | | Acute EC50 98.5 mg/l Static | Daphnia - Ceriodaphnia dubia | 48 hours | - | | | Acute EC50 136.6 mg/l Static | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 42.91 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Acute LC50 46.27 mg/l | Fish - Prosopium williamsoni | 96 hours | - | | | Chronic EC10 4.28 mg/l | Fish - Lepomis macrochirus | 30 days | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | --- | --- | --- | --- | --- | | reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) | Acute EC50 0.16 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 0.19 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Chronic NOEC 0.0004 mg/l [OECD 201] | Algae | 48 hours | - | Conclusion/Summary : Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

12.2 Persistence and degradability

Conclusion/Summary : There are no data available on the mixture itself. | Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) | - | - | Readily |

There are no data available on the mixture itself.

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.2 Persistence and degradability

Product/ingredient name: copper dinitrate, Aquatic half-life: -, Photolysis: -, Biodegradability: Readily

12.3 Bioaccumulative potential

Product/ingredient name: ammonium chloride, LogPow: -3.2, BCF: -, Potential: Low

12.3 Bioaccumulative potential

Product/ingredient name: reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1); LogPow: -0.486 to 0.401; BCF: -; Potential: Low

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

The mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties

Product does not contain substances above legal limits included in the list established in accordance with Article 59(1) of Regulation (EC) No 1907/2006 for having endocrine disrupting properties or is identified to have endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.

The product does not contain substances with endocrine disrupting properties above legal limits.

12.7 Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

NACE: 20.59, UC62: 34

Chemical Safety Assessment Not performed

There are no known additional national regulations relevant to the SDS.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Storage solution?

The signal word is warning.

What is the physical form of Storage solution?

Storage solution is a liquid. appearing as liquid. colourless. with colourless. color. It has odourless. odor.

What is Storage solution used for?

Laboratory chemicals.

What are the hazard statements for Storage solution?

This substance has 1 hazard statement:

  • H319: Causes serious eye irritation.

What is the melting point of Storage solution?

The melting point is Not available. and the boiling point is 100°C.