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Safety Data Sheet EN

Heptafluorobutanoic acid

CAS 375-22-4*

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Heptafluorobutanoic acid
Chemical Name
heptafluorobutyric acid

Regulatory Identifiers

CAS Number
375-22-4* Check regulations →

Manufacturers & Suppliers

Apollo Scientific logo

Apollo Scientific

manufacturer

Whitefield Road, Bredbury SK62QR United Kingdom

01614060505

http://www.apolloscientific.co.uk/

Apollo Scientific Ltd logo

Apollo Scientific Ltd

manufacturer

Whitefield Road, Bredbury Cheshire SK6 2QR United Kingdom (NI)

+44(0) 161 406 0505

apolloscientific.co.uk

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Eye Dam. Cat. 1 H318
Skin Corr. Cat. 1A H314

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H314 Causes severe skin burns and eye damage.

Precautionary Statements

P260 Do not breathe mist/vapours/spray.
P264 Wash all exposed external body areas thoroughly after handling.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Heptafluorobutanoic acid 375-22-4 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.

Symptoms: Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).

Skin contact

Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor.

Eye contact

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

Immediate Medical Attention

Transport to hospital or doctor without delay.

Medical Treatment

For acute or short term repeated exposures to strong acids: Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling. Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in specific tissues. Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. Deep second-degree burns may benefit from topical silver sulfadiazine. Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjunctival cul-de-sacs. Irrigation should last at least 20-30 minutes. Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears may be indicated dependent on the severity of the injury. Steroid eye drops should only be administered with the approval of a consulting ophthalmologist. Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, Dry chemical powder, BCF (where regulations permit), Carbon dioxide, Water spray or fog - Large fires only.

Specific hazards

Combustible. Slight fire hazard when exposed to heat or flame. Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Heating may cause expansion or decomposition leading to violent rupture of containers. May emit acrid smoke and corrosive fumes.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

Small spill

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.

Environmental

See section 12

Cleanup methods

Wipe up.

Materials: sand, earth, inert material or vermiculite

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. WARNING: To avoid violent reaction. ALWAYS add material to water and NEVER water to material. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.

Storage

Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks.

Hygiene

Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use. When handling, DO NOT eat, drink or smoke.

Fire prevention

Avoid smoking, naked lights or ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Not Available
Colour
---
Colour Intensity
---
Form
---
Odor
Not Available
Odor Threshold
Not Available
Ph
Not Available
Melting Point
-18 °C
Boiling Point
119-121 °C
Flash Point
Not Available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not Available
Vapor Pressure
Not Available
Vapor Density
Not Available
Relative Density
Not Available
Bulk Density
---
Density
---
Flammability
Not Available
Upper Explosive Limit
Not Available
Lower Explosive Limit
Not Available
Explosive Limits
---
Auto Ignition Temperature
Not Available
Decomposition Temperature
Not Available
Solubility
---
Partition Coefficient
Not Available
Solubility In Water
Not Available
Solubility In Fat
---
Molecular Weight
Not Available
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not Available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Contact with alkaline material liberates heat

Reactivity

See section 7

Hazardous reactions

See section 7

Avoid

See section 7

Incompatible

See section 7

Decomposition

See section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3265
Shipping Name
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Transport Class
8
Packing Group
II
IMDG

274

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Heptafluorobutanoic acid?

The signal word is danger.

What is the physical form of Heptafluorobutanoic acid?

Heptafluorobutanoic acid is a liquid appearing as not available . It has not available odor.

What are the hazard statements for Heptafluorobutanoic acid?

This substance has 1 hazard statement:

  • H314: Causes severe skin burns and eye damage.

What is the melting point of Heptafluorobutanoic acid?

The melting point is -18 °C and the boiling point is 119-121 °C.