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Safety Data Sheet EN

Citral

CAS 5392-40-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Citral
Product Code
C83007

Regulatory Identifiers

CAS Number
5392-40-5 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

manufacturer

Brusselsesteenweg 288 B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary Statements

P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
citral; 3,7-dimethyl-2,6-octadienal (cis-/trans-mixture of isomers) EC: 226-394-6 5392-40-5 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: caution if victim vomits. Keep airways free. Call a physician immediately.

Symptoms: Risk of aspiration! Pulmonary failure possible after aspiration of vomit.

Immediate Medical Attention

Consult a physician (skin contact). Call in ophthalmologist (eye contact). Call a physician immediately (swallowing).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb® )

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Tightly closed.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject® (KCL 898). Splash contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 240 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Water
0,42 g/l at 25 °C - OECD Test Guideline 105
Relative Density
0,89 at 20 °C
Explosive Limits
---
Solidification Point
---
Freezing Point
---
Crystallisation Point
---
Upper Explosive Limit
9,9 %(V)
Solubility In Fat
---
Colour
light yellow
Boiling Point
229 °C - lit.
Lower Explosive Limit
4,3 %(V)
Relative Evaporation Rate
---
Flammability
---
Softening Point
---
Odor
No data available
Properties Status
---
Auto Ignition Temperature
225 °C at 1.013 hPa - DIN 51794
Kinematic Viscosity
1,67 mm2/s at 40 °C - OECD Test Guideline 114
Partition Coefficient
log Pow: 2,76 at 25 °C
Ph
No data available
Metal Corrosion
---
Dynamic Viscosity
2,15 mPa.s at 20 °C1,46 mPa.s at 40 °C
Form
---
Colour Intensity
---
Physical State Data
liquid
Molecular Weight
---
Decomposition Temperature
---
Flash Point
98 °C - DIN 51758
Density
0,888 g/cm3 at 25 °C - lit.
State Under Standard Conditions
---
Solubility
---
Odor Threshold
---
Evaporation Rate
---
Cloud Point
---
Melting Point
Melting point/range: < -10 °C
Physical State
clear, liquid
Bulk Density
---
Vapor Pressure
< 0,1 hPa at 25 °C
Vapor Density
---
Voc Content
---
Appearance
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Hazardous reactions

Violent reactions possible with: Aluminum alkalines Strong oxidizing agents acids

Avoid

Strong heating.

Incompatible

Aluminum, Mild steel

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

Shipping Name
Not dangerous goods
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Citral?

The signal word is warning.

What is the physical form of Citral?

Citral is a clear, liquid with light yellow color. It has no data available odor.

What is Citral used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Citral?

This substance has 3 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.

What is the melting point of Citral?

The melting point is Melting point/range: < -10 °C and the boiling point is 229 °C - lit..