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Safety Data Sheet EN

3,4-Dihydroxybenzoic acid

CAS 99-50-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
3,4-Dihydroxybenzoic acid
Product Code
B24016
Chemical Name
3,4-Dihydroxybenzoic acid
Synonyms
Protocatechuic acid

Regulatory Identifiers

CAS Number
99-50-3 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

A

Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific)

manufacturer

Shore Road, Heysham, Lancashire, LA3 2XY, United Kingdom

+44 (0) 1524 850506

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

EUH014 May form combustible dust concentrations in air
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
3,4-Dihydroxybenzoic acid EC: 202-760-0 99-50-3 97% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration.

Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Clean mouth with water.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray. Carbon dioxide (CO₂). Dry chemical. Chemical foam.

Unsuitable media

No information available.

Specific hazards

Fine dust dispersed in air may ignite.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

See Section 12 for additional Ecological Information.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. Do not breathe dust. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Natural rubber, Butyl rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

No protective equipment is needed under normal use conditions. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Small scale/Laboratory use: Maintain adequate ventilation

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
No data available
Relative Density
---
Solidification Point
---
Solubility
---
Colour Intensity
---
State Under Standard Conditions
---
Lower Explosive Limit
---
Density
No data available
Ph
No information available
Properties Status
---
Voc Content
---
Form
---
Evaporation Rate
Not applicable - Solid
Flammability
No information available
Molecular Weight
154.12
Solubility In Fat
---
Cloud Point
---
Melting Point
198 - 202 °C / 388.4 - 395.6 °F
Boiling Point
No information available
Physical State
Powder Solid
Vapor Pressure
No data available
Vapor Density
Not applicable
Freezing Point
---
Relative Evaporation Rate
---
Metal Corrosion
---
Softening Point
No data available
Dynamic Viscosity
---
Appearance
Brown
Odor Threshold
No data available
Upper Explosive Limit
---
Solubility In Water
No information available
Auto Ignition Temperature
Not applicable
Colour
---
Flash Point
No information available
Odor
Odorless
Crystallisation Point
---
Explosive Limits
---
Physical State Data
solid
Kinematic Viscosity
---
Partition Coefficient
---
Decomposition Temperature
No data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. No information available.

Avoid

Incompatible products.

Incompatible

Strong oxidizing agents. Strong bases.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 3,4-Dihydroxybenzoic acid known by?

3,4-Dihydroxybenzoic acid is also known as: Protocatechuic acid

What is the hazard signal word for 3,4-Dihydroxybenzoic acid?

The signal word is warning.

What is the physical form of 3,4-Dihydroxybenzoic acid?

3,4-Dihydroxybenzoic acid is a powder solid appearing as brown . It has odorless odor.

What is 3,4-Dihydroxybenzoic acid used for?

Laboratory chemicals.

What are the hazard statements for 3,4-Dihydroxybenzoic acid?

This substance has 4 hazard statements:

  • EUH014: May form combustible dust concentrations in air
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation

What is the melting point of 3,4-Dihydroxybenzoic acid?

The melting point is 198 - 202 °C / 388.4 - 395.6 °F and the boiling point is No information available.