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Safety Data Sheet EN

1-Hexanol for synthesis

CAS 111-27-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1-Hexanol for synthesis
Product Code
8.04393
Chemical Name
1-Hexanol

Regulatory Identifiers

CAS Number
111-27-3 Check regulations →
REACH No.
01-2119487967-12-XXXX

Identified Uses

Chemical for synthesis

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapor.
H302 + H312 Harmful if swallowed or in contact with skin.
H319 Causes serious eye irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
hexan-1-ol EC: 203-852-3 111-27-3 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: caution if victim vomits. Keep airways free. Call a physician immediately.

Symptoms: Risk of aspiration. Pulmonary failure possible after aspiration of vomit.

Immediate Medical Attention

Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: butyl-rubber, Minimum layer thickness: 0,7 mm, Break through time: 480 min, Material tested: Butoject® (KCL 898). Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,4 mm, Break through time: 30 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M)

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Form
---
Dynamic Viscosity
5,3 mPa.s at 20 °C
Density
0,82 g/cm³ at 20 °C
Decomposition Temperature
No data available
Properties Status
---
Evaporation Rate
---
Odor Threshold
---
Vapor Density
---
Solubility
---
Flammability
No data available
Solubility In Fat
---
Voc Content
---
Melting Point
Pour point: -45 °C at ca.1.013 hPa - ASTM D 97-66
Softening Point
---
Relative Evaporation Rate
---
Solubility In Water
1,3 g/l at 23 °C - OECD Test Guideline 105- soluble
State Under Standard Conditions
---
Ph
No data available
Crystallisation Point
---
Physical State Data
liquid
Relative Density
---
Colour
colorless
Colour Intensity
---
Solidification Point
---
Freezing Point
---
Explosive Limits
---
Vapor Pressure
3,64 hPa at ca.38 °C - ASTM D 2879-86
Cloud Point
---
Odor
characteristic
Molecular Weight
---
Upper Explosive Limit
7,7 % (V)
Boiling Point
155 °C at 1.015 hPa - ASTM D 1120-72
Metal Corrosion
---
Partition Coefficient
log Pow: 1,8 - OECD Test Guideline 117 - Bioaccumulation is not expected.
Flash Point
60 °C - closed cup - ASTM D 93
Auto Ignition Temperature
ca. 313 °C at 1.013 hPa - ASTM E-659
Appearance
---
Lower Explosive Limit
1,3 % (V)
Bulk Density
---
Kinematic Viscosity
3,64 mm²/s at 40 °C - ASTM D 445
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapor/air-mixtures are explosive at intense warming.

Hazardous reactions

Violent reactions possible with: Strong oxidizing agents, halogens. Risk of ignition or formation of inflammable gases or vapours with: Alkali metals, Alkaline earth metals, Aluminum.

Avoid

Heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2282
Shipping Name
HEXANOLS
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 1-Hexanol for synthesis?

The signal word is warning.

What is the physical form of 1-Hexanol for synthesis?

1-Hexanol for synthesis is a liquid with colorless color. It has characteristic odor.

What is 1-Hexanol for synthesis used for?

Chemical for synthesis

What are the hazard statements for 1-Hexanol for synthesis?

This substance has 3 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302 + H312: Harmful if swallowed or in contact with skin.
  • H319: Causes serious eye irritation.

What is the melting point of 1-Hexanol for synthesis?

The melting point is Pour point: -45 °C at ca.1.013 hPa - ASTM D 97-66 and the boiling point is 155 °C at 1.015 hPa - ASTM D 1120-72.