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Safety Data Sheet EN

L-(-)-Malic acid

CAS 97-67-6
EC 202-601-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
L-(-)-Malic acid
Product Code
J63221
Synonyms
L-Hydroxysuccinic acid; Apple acid

Regulatory Identifiers

CAS Number
97-67-6 Check regulations →
EC Number
202-601-5 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

A

Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific)

manufacturer

Shore Road, Heysham, Lancashire, LA3 2XY, United Kingdom

+44 (0) 1524 850506

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation
H319 Causes serious eye irritation

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Butanedioic acid, hydroxy-, (S)- EC: 202-601-5 97-67-6 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Get medical attention. If not breathing, give artificial respiration.

Skin contact

Get medical attention. Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust formation.

Environmental

Should not be released into the environment.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Materials: suitable, closed containers

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Natural rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement). Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Particle filtering: EN149:2001 When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

Environmental

No information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Freezing Point
---
Solubility In Water
360 g/L (20°C)
Form
---
Vapor Pressure
negligible
State Under Standard Conditions
---
Colour Intensity
---
Softening Point
No data available
Solidification Point
---
Odor Threshold
No data available
Auto Ignition Temperature
No data available
Dynamic Viscosity
---
Decomposition Temperature
140 °C
Flash Point
220 °C / 428 °F (Method - No information available)
Molecular Weight
134.09
Evaporation Rate
Not applicable - Solid
Crystallisation Point
---
Solubility
---
Explosive Limits
---
Physical State Data
solid
Lower Explosive Limit
---
Upper Explosive Limit
---
Properties Status
---
Cloud Point
---
Density
---
Melting Point
99 - 107 °C / 210.2 - 224.6 °F
Relative Density
---
Ph
approx 2 (1% aq. solution)
Appearance
White
Bulk Density
---
Voc Content
---
Vapor Density
Not applicable
Relative Evaporation Rate
---
Physical State
Powder Solid
Colour
---
Odor
Odorless
Flammability
No information available
Kinematic Viscosity
---
Partition Coefficient
---
Metal Corrosion
---
Boiling Point
No information available
Solubility In Fat
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Excess heat. Incompatible products. Avoid dust formation.

Incompatible

Bases. Metals. Reducing Agent.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is L-(-)-Malic acid known by?

L-(-)-Malic acid is also known as: L-Hydroxysuccinic acid; Apple acid

What is the hazard signal word for L-(-)-Malic acid?

The signal word is warning.

What is the physical form of L-(-)-Malic acid?

L-(-)-Malic acid is a powder solid appearing as white . It has odorless odor.

What is L-(-)-Malic acid used for?

Laboratory chemicals.

What are the hazard statements for L-(-)-Malic acid?

This substance has 2 hazard statements:

  • H315: Causes skin irritation
  • H319: Causes serious eye irritation

What is the melting point of L-(-)-Malic acid?

The melting point is 99 - 107 °C / 210.2 - 224.6 °F and the boiling point is No information available.