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Safety Data Sheet EN

Cerium(III) chloride heptahydrate

CAS 18618-55-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Cerium(III) chloride heptahydrate
Product Code
228931

Regulatory Identifiers

CAS Number
18618-55-8 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1C H314
Eye Dam. Cat. 1 H318
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS09 - Environmental hazard

GHS09

Hazard Statements

H314 Causes severe skin burns and eye damage.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe dust.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
cerium(III)-chloride heptahydrate EC: 232-227-8 18618-55-8 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Hydrogen chloride gas, Cerium oxides. Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Tightly closed. Dry. hygroscopic Store under inert gas. Moisture sensitive.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Vapor Pressure
---
Upper Explosive Limit
---
Softening Point
---
Freezing Point
---
Explosive Limits
---
Solubility In Water
---
Form
---
Odor Threshold
---
Decomposition Temperature
---
Solubility In Fat
---
Flash Point
---
Cloud Point
---
Bulk Density
---
Auto Ignition Temperature
---
Physical State
Crystals with lumps
Physical State Data
solid
Solidification Point
---
Partition Coefficient
---
Kinematic Viscosity
---
Odor
---
Solubility
---
Ph
---
Relative Evaporation Rate
---
Appearance
---
Properties Status
---
Colour Intensity
---
State Under Standard Conditions
---
Dynamic Viscosity
---
Melting Point
---
Colour
---
Boiling Point
---
Relative Density
---
Vapor Density
---
Metal Corrosion
---
Density
3,94 g/mL at 25 °C - lit.
Molecular Weight
---
Flammability
---
Voc Content
---
Evaporation Rate
---
Crystallisation Point
---
Lower Explosive Limit
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

No data available

Avoid

Avoid moisture.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3260
Shipping Name
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (cerium(III)-chloride heptahydrate)
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Cerium(III) chloride heptahydrate?

The signal word is danger.

What is the physical form of Cerium(III) chloride heptahydrate?

Cerium(III) chloride heptahydrate is a crystals with lumps .

What is Cerium(III) chloride heptahydrate used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Cerium(III) chloride heptahydrate?

This substance has 2 hazard statements:

  • H314: Causes severe skin burns and eye damage.
  • H410: Very toxic to aquatic life with long lasting effects.