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Safety Data Sheet EN

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE

CAS 76-13-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
Product Code
J.T. Baker: 491D, 9347, W591; Mallinckrodt: 2793
Chemical Name
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
Synonyms
Freon® TF Solvent; Freon® 113; Fluorocarbon 113; 1,1,2-Trichlorotrifluoroethane

Regulatory Identifiers

CAS Number
76-13-1 Check regulations →
02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H316 MAY CAUSE IRRITATION TO SKIN.
H332 HARMFUL IF INHALED.
H335 CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT.
H373 AFFECTS CARDIOVASCULAR AND CENTRAL NERVOUS SYSTEM.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,1,2-Trichloro-1,2,2-trifluoroethane 76-13-1 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.

Skin contact

Immediately flush skin with plenty of water for at least 15 minutes. Call a physician if irritation develops.

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Ingestion

Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician.

Immediate Medical Attention

Call a physician.

Medical Treatment

Do not give epinephrine or adrenergic activator as they will further sensitize the heart to development of arrhythmias.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use any means suitable for extinguishing surrounding fire.

Specific hazards

Not considered to be a fire hazard. When involved in fire, however, emits suffocating and toxic decomposition products.

Instructions

Water spray may be used to keep fire exposed containers cool.

Firefighter Protection

In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Remove all sources of ignition. Ventilate area of leak or spill. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust.

Environmental

Do not flush to sewer!

Cleanup methods

Collect liquid in an appropriate container or absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container.

Materials: vermiculite, dry sand, earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep in a tightly closed container. Protect against physical damage. Isolate from any source of heat or ignition. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.

Storage

Stored in a cool, dry, ventilated area. Store below boiling point.

Fire prevention

Isolate from any source of heat or ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.

Hands

Wear protective gloves

Eyes

Use chemical safety goggles.

Respiratory

If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. The cartridges recommended for this material have a predicted service of less than 30 minutes at concentrations of ten times (10x) the exposure limits. Actual service life will vary considerably, depending on concentration levels, temperature, humidity, and work rate.

Skin/Body

clean body-covering clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear, colorless liquid.
Colour
colorless
Colour Intensity
---
Form
---
Odor
Slight ethereal odor.
Odor Threshold
---
Ph
No information found.
Melting Point
-35C (-31F)
Boiling Point
47 - 48C (117 - 118F)
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
1.3 (Ether = 1)
Vapor Pressure
284 @ 20C (68F)
Vapor Density
6.5
Relative Density
1.56 @ 25C/4C
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble in water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under ordinary conditions of use and storage.

Hazardous reactions

Will not occur.

Avoid

Heat, flames, ignition sources and incompatibles.

Incompatible

Alkali or alkaline earth metals, powdered aluminum, zinc, beryllium, magnesium, other chemically active metals, acids, heat and open flame.

Decomposition

Hydrogen fluoride, hydrogen chloride, phosgene, carbonyl fluoride, chloride and fluoride gases may be released when this material is heated to decomposition.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE known by?

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE is also known as: Freon® TF Solvent; Freon® 113; Fluorocarbon 113; 1,1,2-Trichlorotrifluoroethane

What is the hazard signal word for 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE?

The signal word is warning.

What is the physical form of 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE?

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE is a liquid appearing as clear, colorless liquid. with colorless color. It has slight ethereal odor. odor.

What are the hazard statements for 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE?

This substance has 4 hazard statements:

  • H316: MAY CAUSE IRRITATION TO SKIN.
  • H332: HARMFUL IF INHALED.
  • H335: CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT.
  • H373: AFFECTS CARDIOVASCULAR AND CENTRAL NERVOUS SYSTEM.

What is the melting point of 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE?

The melting point is -35C (-31F) and the boiling point is 47 - 48C (117 - 118F).