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Safety Data Sheet EN

LOCTITE 454 PRISM TUB 20 GR

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE 454 PRISM TUB 20 GR
Product Form
Cyanoacrylate
Product Code
490119, L45403

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 4
Eye Irrit. Cat. 2B
Repr. Cat. 1B
STOT SE Cat. 3

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H227 COMBUSTIBLE LIQUID
H320 CAUSES EYE IRRITATION
H335 MAY CAUSE RESPIRATORY IRRITATION
H360 MAY DAMAGE FERTILITY OR THE UNBORN CHILD

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, sparks, open flames, hot surfaces - no smoking.
P261 Avoid breathing mist/vapours.
P264 Wash affected area thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, clothing, eye and face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P370 + P378 In case of fire: Use foam, dry chemical or carbon dioxide to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Hazardous Component(s) | CAS Number | Weight %*

Chemical Name CAS Number Concentration Hazardous
Ethyl 2-cyanoacrylate 7085-85-0 80 - 100% Yes
Siloxanes and Silicones, di-Me, reaction products with silica 67762-90-7 5 - 10% Yes
Bis(2-hydroxy-3-tert-butyl-5-methylphenyl)methane 119-47-1 0.1 - 1% Yes

Concentration range is provided to assist users in providing appropriate protections.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention.

Skin contact

Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart using a blunt instrument. If skin is burned due to the rapid generation of heat by a large drop, seek medical attention. If lips are bonded, apply warm water to the lips and encourage wetting and pressure from saliva in mouth. Peel or roll lips apart. Do not pull lips apart with direct opposing force.

Symptoms: Skin may be burned due to the rapid generation of heat by a large drop.

Eye contact

Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. Do not force eye open. Keep eye covered until debonding is complete, usually within 1-3 days.

Symptoms: Lachrymatory effect. Solid particles of polymerized cyanoacrylate trapped behind the eyelid may cause abrasive damage.

Ingestion

Ensure breathing passages are not obstructed. The product will polymerize rapidly and bond to the mouth making it almost impossible to swallow. Saliva will separate any solidified product in several hours. Prevent the patient from swallowing any separated mass.

Symptoms: Bonding to the mouth.

Immediate Medical Attention

Medical attention should be sought in case solid particles of polymerized cyanoacrylate trapped behind the eyelid caused abrasive damage. If skin is burned due to the rapid generation of heat by a large drop, seek medical attention.

Medical Treatment

Surgery is not necessary to separate accidentally bonded tissues. Experience has shown that bonded tissues are best treated by passive, non-surgical first aid. If rapid curing has caused thermal burns they should be treated symptomatically after adhesive is removed.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray (fog), foam, dry chemical or carbon dioxide.

Unsuitable media

Not available.

Instructions

Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode.

Firefighter Protection

Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

Flood with water to complete polymerization and scrape off the floor.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Avoid contact with fabric or paper goods. Contact with these materials may cause rapid polymerization which can generate smoke and strong irritating vapors, and cause thermal burns.

Storage

Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

Hygiene

Wash thoroughly after handling.

Fire prevention

Keep in a cool, well ventilated area away from heat, sparks and open flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid, Gel
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear
Colour
Clear
Colour Intensity
---
Form
---
Odor
Irritating
Odor Threshold
Not available.
Ph
Not applicable, Product reacts with water.
Melting Point
Not applicable, Product is a liquid
Boiling Point
> 149 °C (> 300.2 °F) None
Flash Point
80 - 93.4 °C (176°F - 200.12 °F) Tagliabue closed cup 86.7 °C (188.06 °F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 0.2 mm hg
Vapor Density
---
Relative Density
1.05
Bulk Density
---
Density
---
Flammability
The product is not flammable.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
485 °C (905°F)
Decomposition Temperature
Not available.
Solubility
Miscible Acetone; Polymerises in presence of water. Water
Partition Coefficient
Not available.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
< 2 %; < 20 g/l (California SCAQMD Method 316B) (Estimated)
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
> 20.5 mm2/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

Not available.

Hazardous reactions

Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.

Avoid

Spontaneous polymerization.

Incompatible

Water, amines, alkalis and alcohols.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3334
Shipping Name
Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Transport Class
9
Packing Group
III
IATA

Primary packs containing less than 500ml are unregulated by this mode of transport and may be shipped unrestricted.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE 454 PRISM TUB 20 GR?

The signal word is danger.

What is the physical form of LOCTITE 454 PRISM TUB 20 GR?

LOCTITE 454 PRISM TUB 20 GR is a liquid, gel appearing as clear with clear color. It has irritating odor.

What is the solubility of LOCTITE 454 PRISM TUB 20 GR?

Miscible Acetone; Polymerises in presence of water. Water

What are the hazard statements for LOCTITE 454 PRISM TUB 20 GR?

This substance has 4 hazard statements:

  • H227: COMBUSTIBLE LIQUID
  • H320: CAUSES EYE IRRITATION
  • H335: MAY CAUSE RESPIRATORY IRRITATION
  • H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD

What is the melting point of LOCTITE 454 PRISM TUB 20 GR?

The melting point is Not applicable, Product is a liquid and the boiling point is > 149 °C (> 300.2 °F) None.