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Safety Data Sheet EN

1,2-Dibromoethane

CAS 106-93-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1,2-Dibromoethane
Product Code
112790000; 112790010; 112790025; 112790100; 112790250; 112795000
Chemical Name
1,2-Dibromoethane
Synonyms
EDB; Ethylene dibromide

Regulatory Identifiers

CAS Number
106-93-4 Check regulations →
REACH No.
01-2119539453-38

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

national supplier

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

T

Thermo Fisher Scientific

national supplier

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Carc. Cat. 1B H350
STOT SE Cat. 3 H335
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H350 May cause cancer
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308 + P313 IF exposed or concerned: Get medical advice/attention

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Ethylene dibromide (1,2-Dibromoethane) EC: 203-444-5 106-93-4 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration.

Symptoms: Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting.

Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Clean mouth with water.

Immediate Medical Attention

Immediate medical attention is required for eye contact, skin contact, and inhalation. Call a physician immediately for ingestion.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray. Carbon dioxide (CO₂). Dry chemical. Chemical foam.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

Soak up with inert absorbent material

Materials: sand, silica gel, acid binder, universal binder, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not breathe mist/vapors/spray. Do not get in eyes, on skin, or on clothing.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Protect from direct sunlight. Do not store in metal containers.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Viton (R). Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Kinematic Viscosity
---
Upper Explosive Limit
---
Melting Point
9 - 10 °C / 48.2 - 50 °F
Odor Threshold
No data available
Relative Density
2.173
Colour
---
Relative Evaporation Rate
---
Colour Intensity
---
Solubility In Fat
---
Boiling Point
131 - 132 °C / 267.8 - 269.6 °F
Solubility
---
Explosive Limits
---
Form
---
Dynamic Viscosity
---
Physical State
Liquid
Molecular Weight
187.86
Vapor Density
6.5 (Air = 1.0)
Auto Ignition Temperature
No data available
Bulk Density
Not applicable
Physical State Data
liquid
Cloud Point
---
Solidification Point
---
Evaporation Rate
---
Crystallisation Point
---
Flammability
No data available
Freezing Point
---
Properties Status
---
Voc Content
---
Density
---
Odor
sweet
Appearance
Colorless
Metal Corrosion
---
Lower Explosive Limit
---
Vapor Pressure
11 mmHg @ 25 °C
Flash Point
> 104 °C / > 219.2 °F | Method - No information available
Partition Coefficient
1.93 (Ethylene dibromide (1,2-Dibromoethane))
Solubility In Water
4 g/L (20°C)
State Under Standard Conditions
---
Ph
No information available
Softening Point
---
Decomposition Temperature
> 340°C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Decomposes in contact with water, heat sensitive. Light sensitive. Decomposes on exposure to light.

Reactivity

None known, based on information available

Hazardous reactions

No information available.

Avoid

contact with water, heat, light

Incompatible

water

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂). Hydrogen halides.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1605
Shipping Name
ETHYLENE DIBROMIDE
Transport Class
6.1
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 1,2-Dibromoethane known by?

1,2-Dibromoethane is also known as: EDB; Ethylene dibromide

What is the hazard signal word for 1,2-Dibromoethane?

The signal word is danger.

What is the physical form of 1,2-Dibromoethane?

1,2-Dibromoethane is a liquid appearing as colorless . It has sweet odor.

What is 1,2-Dibromoethane used for?

Laboratory chemicals.

What are the hazard statements for 1,2-Dibromoethane?

This substance has 6 hazard statements:

  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation
  • H350: May cause cancer
  • H411: Toxic to aquatic life with long lasting effects

What is the melting point of 1,2-Dibromoethane?

The melting point is 9 - 10 °C / 48.2 - 50 °F and the boiling point is 131 - 132 °C / 267.8 - 269.6 °F.