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Safety Data Sheet EN

Acryloyl chloride

CAS 814-68-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Acryloyl chloride
Product Code
A24109
Chemical Name
Acryloyl chloride

Regulatory Identifiers

CAS Number
814-68-6 Check regulations →

Identified Uses

Laboratory chemicals Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV

manufacturer

Ildefonse Vandammestraat 5/7B, B-1560 HOEILAART

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Met. Corr. Cat. 1 H290
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 1 H330
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H225 Highly flammable liquid and vapour.
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
acrylic acid chloride EC: 212-399-0 814-68-6 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician or ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2) Dry powder

Unsuitable media

Foam Water/Water Foam

Specific hazards

Combustible. Pay attention to flashback. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at ambient temperatures.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Keep workplace dry. Do not allow product to come into contact with water.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: butyl-rubber, Minimum layer thickness: 0,7 mm, Break through time: 480 min, Material tested: Butoject® (KCL 898). Splash contact: Material: Chloroprene, Minimum layer thickness: 0,65 mm, Break through time: 30 min, Material tested: KCL 720 Camapren®

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter A-(P3). Required when vapours/aerosols are generated. Recommended Filter type: Filter type ABEK. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility
---
Freezing Point
---
Partition Coefficient
No data available
Form
---
Ph
acidic
Physical State Data
liquid
Properties Status
---
Cloud Point
---
Voc Content
---
Boiling Point
72 - 76 °C - lit.
Density
1,114 g/mL at 25 °C - lit.
Kinematic Viscosity
No data available
State Under Standard Conditions
---
Vapor Density
---
Physical State
liquid
Appearance
---
Flammability
---
Odor Threshold
---
Metal Corrosion
---
Lower Explosive Limit
---
Auto Ignition Temperature
No data available
Flash Point
-1 °C
Crystallisation Point
---
Odor
No data available
Dynamic Viscosity
No data available
Colour
light yellow
Solubility In Fat
---
Evaporation Rate
---
Bulk Density
---
Solubility In Water
No data available
Explosive Limits
---
Softening Point
---
Molecular Weight
---
Relative Density
No data available
Upper Explosive Limit
---
Vapor Pressure
No data available
Melting Point
No data available
Relative Evaporation Rate
---
Colour Intensity
---
Solidification Point
---
Decomposition Temperature
140 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

sensitive to moisture

Reactivity

Vapours may form explosive mixture with air. Reacts violently with water.

Hazardous reactions

Violent reactions possible with: alkali hydroxides, Amines, Water, Alcohols. Violent polymerisation may be caused by: heat.

Avoid

heat

Incompatible

alkali hydroxides, Amines, Water, Alcohols, polymerisation initiators

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3488
Shipping Name
TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. (acrylic acid chloride)
Transport Class
6.1 (3, 8)
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Acryloyl chloride?

The signal word is danger.

What is the physical form of Acryloyl chloride?

Acryloyl chloride is a liquid with light yellow color. It has no data available odor.

What is Acryloyl chloride used for?

Laboratory chemicals Manufacture of substances

What are the hazard statements for Acryloyl chloride?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H290: May be corrosive to metals.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H330: Fatal if inhaled.

What is the melting point of Acryloyl chloride?

The melting point is No data available and the boiling point is 72 - 76 °C - lit..