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Safety Data Sheet EN

HiTEC® 4046B Heating Oil Additive

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
HiTEC® 4046B Heating Oil Additive
Product Form
Liquid.

Regulatory Identifiers

CAS Number
N/A
UFI Code
ST9G-JMEM-YW30-YP4G

Identified Uses

Industrial. Formulation and blending of fuel additives and fuels.

Manufacturers & Suppliers

A

Afton Chemical Limited

manufacturer

Euro-Tech Centre, London Road, Bracknell, RG12 2UW, England

+44 1344 304141

A

Afton Chemical S.R.L. (Woluwe)

manufacturer

Alma Court, Lenneke Marelaan, 8, B-1932, St-Stevens-Woluwe, Belgium

+32 2 715 2211

A

Afton Chemical S.R.L. (Feluy Plant)

manufacturer

Rue de Scoufflény, 50, B-7191 Ecaussinnes Lalaing, Belgium

+32 67 286211

Emergency Contacts

Emergency Contact

+43-13649237

24 hours a day, 7 days a week

Emergency Contact

+351-308801773

24 hours a day, 7 days a week

Emergency Contact

+32-28083237

24 hours a day, 7 days a week

Emergency Contact

+421-233057972

24 hours a day, 7 days a week

Emergency Contact

+359-32570104

24 hours a day, 7 days a week

Emergency Contact

+38-618888016

24 hours a day, 7 days a week

Emergency Contact

+385-17776920

24 hours a day, 7 days a week

Emergency Contact

+46-852503403

24 hours a day, 7 days a week

Emergency Contact

+420-228880039

24 hours a day, 7 days a week

Emergency Contact

+41-435082011

24 hours a day, 7 days a week

Emergency Contact

+45-69918573

24 hours a day, 7 days a week

Emergency Contact

+380-947101374

24 hours a day, 7 days a week

Emergency Contact

+358-942419014

24 hours a day, 7 days a week

Emergency Contact

+44-8708200418

24 hours a day, 7 days a week

Emergency Contact

+33-975181407

24 hours a day, 7 days a week

Emergency Contact

+1-703-527-3887

24 hours a day, 7 days a week

Emergency Contact

+49-69-6435-08409

24 hours a day, 7 days a week

Emergency Contact

+65 3163 8374

24 hours a day, 7 days a week

Emergency Contact

+36-18088425

24 hours a day, 7 days a week

Emergency Contact

+61-290372994

24 hours a day, 7 days a week

Emergency Contact

+353-19014670

24 hours a day, 7 days a week

Emergency Contact

4001-204937

24 hours a day, 7 days a week

Emergency Contact

+39-0245557031

24 hours a day, 7 days a week

Emergency Contact

+(91)-22-3354 3594

24 hours a day, 7 days a week

Emergency Contact

+352-20202416

24 hours a day, 7 days a week

Emergency Contact

+81-345209637

24 hours a day, 7 days a week

Emergency Contact

+31-858880596

24 hours a day, 7 days a week

Emergency Contact

+65-3158-1349

24 hours a day, 7 days a week

Emergency Contact

+47-21930678

24 hours a day, 7 days a week

Emergency Contact

00-308-13-2549

24 hours a day, 7 days a week

Emergency Contact

+48-223988029

24 hours a day, 7 days a week

Emergency Contact

+1-703-741-5979

24 hours a day, 7 days a week

Emergency Contact

1-800-424-9300

24 hours a day, 7 days a week

Emergency Contact

+43 1 406 43 43

Emergency Contact

+32 (0)70 245 245

Emergency Contact

+359 2 9154 233

Emergency Contact

+3851 2348 342

Emergency Contact

+357 1401

Emergency Contact

+420 224 91 92 93

Emergency Contact

+45 8212 1212

Emergency Contact

+372 16662

Emergency Contact

+33 (0)1 45 42 59 59

Emergency Contact

+30 210 779 3777

Emergency Contact

+36 80 201 199

Emergency Contact

+354 112

Emergency Contact

+371 67042473

Emergency Contact

+370 (85) 236 2052

Emergency Contact

+352 8002 5500

Emergency Contact

+31 (0)88 755 8000

Emergency Contact

+47 22 59 13 00

Emergency Contact

+351 800 250 250

Emergency Contact

+40 (0)21 318 36 06

8am – 3pm

Emergency Contact

+421 2 5477 4166

Emergency Contact

+386 112

Emergency Contact

+34 91 562 04 20

Emergency Contact

+46 112

Emergency Contact

+39 800 883 300

Emergency Contact

+39 055 794 7819

Emergency Contact

+39 800 183 459

Emergency Contact

+39 02 6610 1029

Emergency Contact

+39 081 545 3333

Emergency Contact

+39 0382 24444

Emergency Contact

+39 06 305 4343

Emergency Contact

+39 06 4997 8000

Emergency Contact

+39 06 6859 3726

Emergency Contact

+39 800 011 858

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Skin Sens. Cat. 1 H317
Repr. Cat. 1B H360FD
STOT SE Cat. 3 H336
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
H360FD May damage fertility. May damage the unborn child.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P261 Avoid breathing vapor.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P301 + P330 + P331 IF SWALLOWED: Do NOT induce vomiting.
P308 + P313 IF exposed or concerned: Get medical advice or attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P352 IF ON SKIN: Wash with plenty of water.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P403 Store in a well-ventilated place.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Long-chain alkenyl amide EC: 947-263-6 68478-81-9 1 - 3% Yes
Hydrocarbons, C10, aromatics, < 1% naphthalene EC: 918-811-1 64742-94-5 35 - 45% Yes
Hydrocarbons, C10-C13, aromatics, <1% naphthalene EC: 922-153-0 64742-94-5 5 - 10% Yes
2,6-di-tert-butyl-p-cresol EC: 204-881-4 128-37-0 5 - 10% Yes
cyclohexyldimethylamine EC: 202-715-5 98-94-2 3 - 5% Yes
Reaction mass of 3a, 4,5,6,7,7a-hexahydro-4,7-methanoinden-5-yl acetate and 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl EC: 911-369-0 5413-60-5 1 - 2.5% Yes
3-methylbutyl butyrate EC: 203-380-8 106-27-4 1 - 3% Yes
2-ethylhexan-1-ol EC: 203-234-3 104-76-7 1 - 2.3% Yes
Hydrocarbons, C10, aromatics, > 1% naphthalene EC: 919-284-0 64742-94-5 1 - 3% Yes
α,α'-propylenedinitrilodi-o-cresol EC: 202-374-2 94-91-7 1 - 3% Yes
Hydrocarbons, C10-C13, aromatics, >1% naphthalene EC: 926-273-4 64742-94-5 0.5 - 1% Yes
naphthalene EC: 202-049-5 91-20-3 0.5 - 1% Yes
Amines, polyethylenepoly-, tetraethylenepentamine fraction EC: 292-587-7 112-57-2 0.3 - 0.5% Yes
rosin EC: 232-475-7 8050-09-7 0.1 - 0.3% Yes
ethyl enantate EC: 203-382-9 106-30-9 0.1 - 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. If not breathing, give artificial respiration. If breathing is difficult, administer oxygen.

Symptoms: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Adverse symptoms may include the following: nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Continue to rinse for at least 15 minutes.

Symptoms: Causes skin irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include the following: pain or irritation, watering, redness.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Aspiration hazard if swallowed. Can enter lungs and cause damage.

Immediate Medical Attention

Get medical attention immediately. Call a poison center or physician.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

In case of fire, use water spray (fog), foam, dry chemical or CO₂.

Unsuitable media

Do not use water jet.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material. Contain and collect spillage with non-combustible, absorbent material.

Materials: inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not swallow. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Hands

Hand Protection: Wear chemical resistant gloves. Nitrile gloves of minimum thickness 0.4 mm have an expected breakthrough time of 120 minutes or less when in frequent contact with the product. Due to variable exposure conditions the user must consider that the practical use of a chemical-protective glove in practice may be much shorter than the permeation time above. Manufacturer's directions for use, especially about the minimum thickness and the minimum breakthrough time, must be observed. This information does not replace suitability tests by the end user since glove protection varies depending on the conditions under which the product is used.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Use appropriate respiratory protection if there is the potential to exceed the exposure limit(s). Seek professional advice prior to respirator selection and use. Select respirator based on suitability to provide adequate worker protection for given working conditions and level of airborne contaminant. Approved/certified respirator with organic vapor cartridge.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear. Oily liquid.
Colour
Brown.
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
Closed cup: 61°C [Pensky-Martens (Minimum)]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
0.053 kPa (0.4 mm Hg)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0.927 g/cm³ [15°C]
Flammability
Not applicable (liquid).
Upper Explosive Limit
6%
Lower Explosive Limit
1%
Explosive Limits
---
Auto Ignition Temperature
405°C
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C): 7.6 mm²/s (7.6 cSt) Minimum 2.98 cSt @ 100°C
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

High temperatures, sparks and open flames.

Incompatible

Strong oxidizing and reducing agents.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | Hydrocarbons, C10, aromatics, < 1% naphthalene | Acute EL50 >1 mg/l | Algae - Raphidocelis subcapitata | 72 hours | - | | | Acute EL50 1.4 mg/l | Crustaceans - Daphnia magna | 48 hours | Based on data for a similar substance. | | | Acute LL50 2 to 5 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Chronic NOEL 1 mg/l | Algae - Raphidocelis subcapitata | 72 hours | - | | | Chronic NOEL 0.48 mg/l | Crustaceans - Daphnia magna | 21 days | Based on data for a similar substance. |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | Hydrocarbons, C10-C13, aromatics, <1% naphthalene | Acute EL50 >1 mg/l | Algae - Raphidocelis subcapitata | 72 hours | - | | | Acute EL50 1.4 mg/l | Crustaceans - Daphnia magna | 48 hours | Based on data for a similar substance. | | | Acute LL50 2 to 5 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Chronic NOEL 1 mg/l | Algae - Raphidocelis subcapitata | 72 hours | - | | | Chronic NOEL 0.48 mg/l | Crustaceans - Daphnia magna | 21 days | Based on data for a similar substance. |

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | 2,6-di-tert-butyl-p-cresol | EC50 >10000 mg/l | Micro-organism | 3 hours | - | | | Acute EC50 >0.4 mg/l | Algae - Desmodesmus subspicatus | 72 hours | - | | | Acute EC50 0.48 mg/l | Crustaceans - Daphnia magna | 48 hours | - | | | Acute LC50 1.1 mg/l | Fish - Oryzias latipes | 96 hours | - | | | Chronic EC10 0.4 mg/l | Algae - Desmodesmus subspicatus | 72 hours | - | | | Chronic NOEC 0.069 mg/l | Crustaceans - Daphnia magna | 21 days | - | | | Chronic NOEC 0.053 mg/l | Fish - Oryzias latipes | 30 days | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | cyclohexyldimethylamine | Acute EC50 3.5 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Acute EL50 206 mg/l | Micro-organism - Pseudomonas putida | 17 hours | - | | | Acute LC50 75 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LL50 31.58 mg/l | Fish - Leuciscus idus | 96 hours | - | | | Chronic EC10 0.6 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Chronic EC10 0.754 mg/l | Crustaceans - Daphnia magna | 21 days | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | 3-methylbutyl butyrate | Acute EC50 4.68 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Acute EC50 8.12 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 3.19 mg/l | Fish - Danio rerio | 96 hours | - | | | Chronic EC10 3.13 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | 2-ethylhexan-1-ol | NOEC >300 mg/l | Micro-organism | 24 hours | - | | | Acute EC50 39 mg/l | Crustaceans - Daphnia magna | 48 hours | - | | | Acute EL50 16.6 mg/l | Algae - Desmodesmus subspicatus | 72 hours | - | | | Acute LC50 17.1 mg/l | Fish - Leuciscus idus melanotus | 96 hours | - | | | Chronic EL10 5.3 mg/l | Algae - Desmodesmus subspicatus | 72 hours | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | Long-chain alkenyl amide | Acute EL50 496 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Acute EL50 >1000 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute EL50 >1000 mg/l | Micro-organism | 3 hours | - | | | Acute LL50 >1000 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Chronic EL10 318 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | --- | --- | --- | --- | --- | | Hydrocarbons, C10, aromatics, >1% naphthalene | Acute EL50 >1 mg/l | subcapitata Algae - Raphidocelis subcapitata | 72 hours | - | | | Acute EL50 1.4 mg/l | Crustaceans - Daphnia magna | 48 hours | Based on data for a similar substance. | | | Acute LL50 2 to 5 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Chronic NOEL 1 mg/l | Algae - Raphidocelis subcapitata | 72 hours | - | | | Chronic NOEL 0.48 mg/l | Crustaceans - Daphnia magna | 21 days | Based on data for a similar substance. |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | α,α'-propylenedinitrilodi-o-cresol | Acute EC50 1.117 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Acute EC50 3.162 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute EL50 50 mg/l | Micro-organism | 3 hours | - | | | Acute LL50 46 mg/l | Fish - Leuciscus idus | 96 hours | - | | | Chronic EC10 0.116 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | Hydrocarbons, C10-C13, aromatics, >1% naphthalene | Acute EL50 >1 mg/l | Algae - Raphidocelis subcapitata | 72 hours | - | | | Acute EL50 1.4 mg/l | Crustaceans - Daphnia magna | 48 hours | Based on data for a similar substance. | | | Acute LL50 2 to 5 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Chronic NOEL 1 mg/l | Algae - Raphidocelis subcapitata | 72 hours | - | | | Chronic NOEL 0.48 mg/l | Crustaceans - Daphnia magna | 21 days | Based on data for a similar substance. |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | naphthalene | Acute EC50 2.96 mg/l | Algae - Pseudokirchneriella subcapitata | 96 hours | - | | | Acute EC50 2.16 mg/l | Crustaceans - Daphnia magna | 48 hours | - | | | Acute LC50 1.6 mg/l | Fish - Oncorhynchus mykiss | 96 hours | - | | | Chronic NOEC 0.59 mg/l | Crustaceans - Daphnia pulex | 125 days | - | | | Chronic NOEC 0.12 mg/l | Fish - Oncorhynchus gorbuscha | 40 days | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | Amines, polyethylenepoly-, tetraethylenepentamine fraction | Acute EC50 6.8 mg/l | Algae - Selenastrum capricornutum | 72 hours | - | | | Acute EC50 1600 mg/l | Micro-organism | 60 minutes | - | | | Acute LC50 14.6 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 310 mg/l | Fish - Pimephales promelas | 96 hours | - | | | Chronic NOEC 0.5 mg/l | Algae - Selenastrum capricornutum | 72 hours | - |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | rosin | Acute EL50 39.6 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | Based upon data for a similar product. | | | Acute EL50 >10000 mg/l | Micro-organism | 3 hours | - | | | Acute LL50 1.6 mg/l | Daphnia - Daphnia magna | 48 hours | Based upon data for a similar product. | | | Acute LL50 1.7 mg/l | Fish - Pimephales promelas | 96 hours | Based upon data for a similar product. | | | Chronic NOEL 6.25 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | Based upon data for a similar product. |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | ethyl enantate | Acute EC50 0.44 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Acute EC50 >26.3 mg/l | Crustaceans - Daphnia magna | 48 hours | - | | | Acute LC50 >1.01 mg/l | Fish - Danio rerio | 96 hours | - | | | Chronic EC10 0.138 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - |

12.2 Persistence and degradability

Afton HITEC® 4046B Heating Oil Additive Date: 6 March 2024 version: 1.12 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878 and United Kingdom SECTION 12: Ecological information | Product/ingredient name | Test | Result | Remarks | | --- | --- | --- | --- |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | Hydrocarbons, C10, aromatics, < 1% naphthalene | OECD 301F Ready Biodegradability - Manometric Respirometry Test | 58.6 % - Inherent - 28 days | Based on data for a similar substance. |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | Hydrocarbons, C10-C13, aromatics, <1% naphthalene | OECD 301F Ready Biodegradability - Manometric Respirometry Test | 58.6 % - Inherent - 28 days | Based on data for a similar substance. |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | 2,6-di-tert-butyl-p-cresol | OECD 301C Ready Biodegradability - Modified MITI Test (I) | 4.5 % - Not readily - 28 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | cyclohexyldimethylamine | OECD 301A Ready Biodegradability - DOC Die-Away Test | 90 to 100 % - Readily - 18 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | 3-methylbutyl butyrate | OECD 310 Ready Biodegradability - CO₂ in Sealed Vessels (Headspace Test) | 63 % - Not readily - 28 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | 2-ethylhexan-1-ol | OECD 301C Ready Biodegradability - Modified MITI Test (I) | 100 % - Readily - 14 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | Long-chain alkenyl amide | OECD 301D Ready Biodegradability - Closed Bottle Test | 6.2 % - Not readily - 35 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | Hydrocarbons, C10, aromatics, > 1% naphthalene | OECD 301F Ready Biodegradability - Manometric Respirometry Test | 58.6 % - Inherent - 28 days | Based on data for a similar substance. |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | α,α'-propylenedinitrilodi-o-cresol | OECD 301F Ready Biodegradability - Manometric Respirometry Test | 70 to 80 % - Readily - 28 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | Hydrocarbons, C10-C13, aromatics, >1% naphthalene | OECD 301F Ready Biodegradability - Manometric Respirometry Test | 58.6 % - Inherent - 28 days | Based on data for a similar substance. |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | naphthalene | OECD 302C Inherent Biodegradability: Modified MITI Test (II) | 0 to 2 % - Not readily - 28 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | Amines, polyethylenepoly-, tetraethylenepentamine fraction | OECD 301D Ready Biodegradability - Closed Bottle Test | 0 % - Not readily - 28 days | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | rosin | OECD 301D Ready Biodegradability - Closed Bottle Test | 71 % - Readily - 28 days | Based upon data for a similar product. |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | ethyl enantate | OECD 301F Ready Biodegradability - Manometric | 73 % - Readily - 28 days | - |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | Hydrocarbons, C10, aromatics, < 1% naphthalene | 2.8 to 6.5 | 99 to 5780 | high |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | Hydrocarbons, C10-C13, aromatics, <1% naphthalene | 2.8 to 6.5 | 99 to 5780 | high |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | 2,6-di-tert-butyl-p-cresol | 5.1 | 330 to 1800 | high |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | cyclohexyldimethylamine | 2.01 | 35.66 | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | Reaction mass of 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-5-yl acetate and 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl | 0.924 | 35 | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | 3-methylbutyl butyrate | 3.99 | - | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | 2-ethylhexan-1-ol | 2.9 | 25.33 | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | Hydrocarbons, C10, aromatics, >1% naphthalene | 2.8 to 6.5 | 99 to 5780 | high |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | α,α'-propylenedinitrilodi-o-cresol | 3.6 | - | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | Hydrocarbons, C10-C13, aromatics, >1% naphthalene | 2.8 to 6.5 | 99 to 5780 | high |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | naphthalene | 3.4 | 36.5 to 168 | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | rosin | 1.9 to 7.7 | - | high |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | ethyl enantate | 3.98 | - | low |

12.4 Mobility in soil

Soil/water partition : Not available. coefficient (Koc) Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

The mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties

Based on available data, the classification criteria are not met.

12.7 Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

13 07 03* other fuels (including mixtures) EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
Environmentally hazardous substance, liquid, n.o.s. (Solvent naphtha; Alkyl phenol)
Transport Class
9
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878 and United Kingdom

Chemical Safety Assessment Not performed
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for HiTEC® 4046B Heating Oil Additive?

The signal word is danger.

What is the physical form of HiTEC® 4046B Heating Oil Additive?

HiTEC® 4046B Heating Oil Additive is a liquid. appearing as clear. oily liquid. with brown. color. It has characteristic. odor.

What is HiTEC® 4046B Heating Oil Additive used for?

Industrial. Formulation and blending of fuel additives and fuels.

What are the hazard statements for HiTEC® 4046B Heating Oil Additive?

This substance has 6 hazard statements:

  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H336: May cause drowsiness or dizziness.
  • H360FD: May damage fertility. May damage the unborn child.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of HiTEC® 4046B Heating Oil Additive?

The melting point is Not available. and the boiling point is Not available..