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Safety Data Sheet EN

i-Nonanoic acid

CAS 3302-10-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
i-Nonanoic acid
Chemical Name
3,5,5-Trimethylhexanoic acid

Regulatory Identifiers

CAS Number
3302-10-1 Check regulations →
REACH No.
01-2119517580-45-0001

Identified Uses

Chemical used in synthesis and/or formulation of industrial products

Manufacturers & Suppliers

B

BASF SE

manufacturer

67056 Ludwigshafen, GERMANY

B

BASF plc

national supplier

PO Box 4, Earl Road, Cheadle Hulme, Cheadle, Cheshire, SK8 6QG, UNITED KINGDOM

+44 161 485-6222

Emergency Contacts

Emergency Contact

+49 180 2273-112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.

Precautionary Statements

P264 Wash with plenty of water and soap thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves and eye/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P330 Rinse mouth.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/container to hazardous or special waste collection point.
IF ON SKIN (or hair): Wash with plenty of soap and water.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
3,5,5-Trimethylhexanoic acid EC: 221-975-0 3302-10-1 95 - 99% Yes
Isononanoic acid EC: 248-092-3 26896-18-4 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Keep patient calm, remove to fresh air, seek medical attention.

Skin contact

Remove contaminated clothing. Wash thoroughly with soap and water.

Eye contact

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Ingestion

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Immediate Medical Attention

Seek medical attention if inhaled, ingested, or in case of eye contact.

Medical Treatment

Treat according to symptoms (decontamination, vital functions)

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

dry powder, foam, carbon dioxide, water jet

Specific hazards

nitrogen oxides, carbon oxides. The substances/groups of substances mentioned can be released in case of fire.

Firefighter Protection

Wear self-contained breathing apparatus and chemical-protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation. Avoid contact with the skin, eyes and clothing.

Small spill

Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Large spill

Pump off product.

Environmental

Do not empty into drains.

Cleanup methods

Pump off product (large amounts); Pick up with suitable absorbent material (residues).

Materials: sand, sawdust, general-purpose binder, kieselguhr

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Storage

Keep container tightly closed in a cool, well-ventilated place.

Fire prevention

Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): fluoroelastomer (FKM) - 0.7 mm coating thickness butyl rubber (butyl) - 0.7 mm coating thickness polyvinylchloride (PVC) - 0.7 mm coating thickness nitrile rubber (NBR) - 0.4 mm coating thickness chloroprene rubber (CR) - 0.5 mm coating thickness Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) natural rubber/natural latex (NR) - 0.5 mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types.

Eyes

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Respiratory

Respiratory protection in case of vapour/aerosol release. Suitable respiratory protection for higher concentrations or long-term effect: Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2)

Skin/Body

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

Environmental

For information regarding environmental exposure controls, see Section 6.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
colourless
Colour
colourless
Colour Intensity
---
Form
liquid
Odor
faint odour
Odor Threshold
not determined
Ph
approx. 3.5 (0.2 %(m), 20 °C)
Melting Point
< -60 °C Literature data.
Boiling Point
230 - 240 °C (1,013 hPa) Literature data.
Flash Point
137 °C (DIN 51758)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Value can be approximated from Henry's Law Constant or vapor pressure.
Vapor Pressure
0.0058 hPa (measured) (20 °C), 0.111 hPa (measured) (50 °C)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0.9 g/cm3 (20 °C) Literature data.
Flammability
not flammable
Upper Explosive Limit
For liquids not relevant for classification and labelling.
Lower Explosive Limit
For liquids not relevant for classification and labelling., The lower explosion point may be 5 - 15 °C below the flash point.
Explosive Limits
---
Auto Ignition Temperature
320 °C Literature data.
Decomposition Temperature
---
Solubility
---
Partition Coefficient
3.34 (calculated) (25 °C)
Solubility In Water
not soluble
Solubility In Fat
---
Molecular Weight
158.24 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
11.47 mPa.s (20 °C) (ASTM D 445-97)
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable if stored and handled as prescribed/indicated.

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: No corrosive effect on metal.

Hazardous reactions

Reacts with strong alkalies. Exothermic reaction.

Avoid

See MSDS section 7 - Handling and storage.

Incompatible

strong alkalies

Decomposition

No hazardous decomposition products if stored and handled as prescribed/indicated.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Assessment of aquatic toxicity: Acutely harmful for aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations.

Acutely harmful for aquatic organisms. No inhibition of activated sludge degradation activity expected at low concentrations.

12.2. Persistence and degradability

Not provided.

12.3. Bioaccumulative potential

Not provided.

12.4. Mobility in soil

Not provided.

12.5. Results of PBT and vPvB assessment

Not provided.

12.6. Endocrine disrupting properties

Not provided.

12.7. Other adverse effects

Not provided.

12.1. Toxicity

Toxicity to fish: LC50 (96 h) 122 mg/l, Oncorhynchus mykiss (OECD 203; ISO 7346; 84/449/EEC, C.1, semistatic) The statement of the toxic effect relates to the analytically determined concentration. Aquatic invertebrates: EC50 (48 h) 68 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) The details of the toxic effect relate to the nominal concentration. Aquatic plants: EC50 (72 h) 81 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. Microorganisms/Effect on activated sludge: EC50 (180 min) 470 mg/l, activated sludge, domestic (OECD Guideline 209) Nominal concentration. Literature data. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Chronic toxicity to fish: Study scientifically not justified. Chronic toxicity to aquatic invertebrates: Study scientifically not justified. Assessment of terrestrial toxicity: Study scientifically not justified.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O): Readily biodegradable (according to OECD criteria). Elimination information: 96 % DOC reduction (14 d) (OECD 301 A (new version)) (activated sludge, domestic)

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3. Bioaccumulative potential

Assessment bioaccumulation potential: Accumulation in organisms is not to be expected. Bioaccumulation potential: Bioconcentration factor: 3.1 - 7 (42 d), Cyprinus carpio (OECD Guideline 305 C)

12.4. Mobility in soil

Assessment transport between environmental compartments: Volatility: The substance will not evaporate into the atmosphere from the water surface. Adsorption in soil: Study scientifically not justified.

12.5. Results of PBT and vPvB assessment

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self classification

The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative).

12.6. Other adverse effects

The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer.

The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Incinerate in suitable incineration plant, observing local authority regulations.

Disposal

This product and any uncleaned containers must be disposed of as hazardous waste in accordance with the 2005 Hazardous Waste Regulations and amendments (United Kingdom)

Waste Codes

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data should be considered when making any assessment under the Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials' (United Kingdom).

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for i-Nonanoic acid?

The signal word is danger.

What is the physical form of i-Nonanoic acid?

i-Nonanoic acid is a liquid appearing as colourless with colourless color. It has faint odour odor.

What is i-Nonanoic acid used for?

Chemical used in synthesis and/or formulation of industrial products

What are the hazard statements for i-Nonanoic acid?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.

What is the melting point of i-Nonanoic acid?

The melting point is < -60 °C Literature data. and the boiling point is 230 - 240 °C (1,013 hPa) Literature data..