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Safety Data Sheet EN

LUBRIZOL® CV1100

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LUBRIZOL® CV1100

Regulatory Identifiers

CAS Number
N/A
UFI Code
HY44-G57C-U00C-462C

Identified Uses

Heavy duty diesel engine oil additive.

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H315 Causes skin irritation.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P264 Wash face, hands and any exposed skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
Distillates (petroleum), hydrotreated heavy paraffinic EC: 265-157-1 --- 1 - 10% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC: 283-392-8 --- 6.25 - 10% Yes
Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts EC: 947-519-7 --- 1 - 5% Yes
Calcium branched alkyl phenate sulphide (overbased) --- 1 - 5% Yes
Calcium branched alkyl phenate sulphide --- 1 - 5% Yes
Benzene, polypropene derivatives, sulfonated, calcium salts --- 0.1 - 1% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 0.01 - 0.25% Yes
2,6-Di-tert-butylphenol EC: 204-884-0 --- 0.1 - 0.25% Yes
Diphenylamine EC: 204-539-4 --- 0.1 - 0.25% Yes
O,O,O-triphenyl phosphorothioate EC: 209-909-9 --- 0.01 - 0.25% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Wash with soap and water. If skin irritation occurs, get medical attention. Get medical attention if symptoms occur. Launder contaminated clothing before reuse.

Eye contact

Flush thoroughly with water. If irritation occurs, get medical assistance. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Not determined.

Specific hazards

See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Avoid contact with skin. Observe good industrial hygiene practices. Provide adequate ventilation. Use personal protective equipment as required. Wash hands thoroughly after handling. Launder contaminated clothing before reuse. Avoid environmental contamination.

Storage

Store away from incompatible materials. Do not store product at temperature in excess of 45°C (113°F) for extended periods of time, 1 week or more; or, using a heat source, such as steam, at a temperature in excess of 100°C (212°F).

Hygiene

Wash hands thoroughly after handling. Launder contaminated clothing before reuse.

Fire prevention

Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use material in well ventilated area only. Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered.

Eyes

Wear tight-fitting goggles or face shield. Eye protection should meet the standards set out in EN 166.

Respiratory

A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use respirator with an organic vapor and dust/mist cartridge if the recommended exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Use respirator with an organic vapor cartridge if exposure limit is exceeded. Use disposable dust/mist mask if the recommended exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material. Chemical resistant boots.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark brown
Colour
Dark brown
Colour Intensity
---
Form
liquid
Odor
Mild
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
---
Flash Point
154 °C (Pensky-Martens Closed Cup)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
0.932 - 0.972 (15.6 °C)
Bulk Density
7.93 lb/gal (15.6 °C)
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
1305 mm2/s (40 °C); 80 mm2/s (100 °C) 3714 mm2/s (25 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Do not expose to excessive heat, ignition sources, or oxidizing materials.

Incompatible

oxidizing materials

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, nitrogen oxides, and other products of incomplete combustion. Diphenylamine and alkenes may also be released.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.3 Bioaccumulative potential

Diphenylamine Log Kow: 3.4 (calculated)

12.4 Mobility in soil

No data available

12.3 Bioaccumulative potential

2,6-Di-tert-butylphenol Log Kow: 4.5 (Measured)

12.1 Toxicity

### Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Toxicity

### Fish Distillates (petroleum), hydrotreated heavy paraffinic LC 50 (Fathead Minnow, 96 h): > 100 mg/l

12.1 Toxicity

Fish Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts LC 50 (Rainbow Trout, 4 d): 4.5 mg/l LC 50 (Sheepshead Minnow, 4 d): 46 mg/l

12.1 Toxicity

### Fish Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts LC 50 (Rainbow Trout, 96 h): > 100.1 mg/l LC 50 (Fathead Minnow, 96 h): > 1,000 mg/l LC 50 (Sheepshead Minnow, 96 h): > 10,000 mg/l

12.1 Toxicity

### Fish Calcium branched alkyl phenate sulphide (overbased) LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Toxicity

### Fish Calcium branched alkyl phenate sulphide LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Toxicity

### Fish Phenol, dodecyl-, branched LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Toxicity

Fish 2,6-Di-tert-butylphenol LC 50 (Fathead Minnow, 4 d): 1.4 mg/l LC 50 (Rainbow Trout, 4 d): 13 mg/l

12.1 Toxicity

### Fish Diphenylamine LC 50 (Not reported, 2 d): 2.2 mg/l

12.1 Toxicity

Fish ++ O,O,O-triphenyl phosphorothioate LC 50 (Zebra Fish, 4 d): > 100 mg/l No toxicity at solubility limit. NOEC (Rainbow Trout, 97 d): 0.0017 mg/l

Aquatic Invertebrates

Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Toxicity

Distillates (petroleum), hydrotreated heavy paraffinic EC 50 (Water flea (Daphnia magna), 48 h): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l

12.1 Toxicity

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Water flea (Daphnia magna), 2 d): 23 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Toxicity

Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

12.1 Toxicity

Calcium branched alkyl phenate sulphide (overbased) EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

12.1 Toxicity

Aquatic Invertebrates Calcium branched alkyl phenate sulphide EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

Aquatic Invertebrates

Phenol, dodecyl-, branched EC 50 (Water flea (Daphnia magna), 2 d): 0.037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0.58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.0037 mg/l

12.1 Toxicity

2,6-Di-tert-butylphenol EC 50 (Water flea (Daphnia magna), 2 d): 0.45 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 0.8 mg/l

12.1 Toxicity

Diphenylamine EC 50 (Water flea (Daphnia magna), 2 d): 0.31 mg/l

12.1 Toxicity

++ O,O,O-triphenyl phosphorothioate EC 50 (Water Flea (Daphnia Magna), 2 d): > 100 mg/l No toxicity at solubility limit. NOEC (Water Flea (Daphnia Magna), 21 d): > 5.5 mg/l No toxicity at solubility limit.

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Toxicity

Distillates (petroleum), hydrotreated heavy paraffinic EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): > 100 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 72 h): >= 100 mg/l

Toxicity to Aquatic Plants

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 21 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 d): 10 mg/l

Toxicity to Aquatic Plants

Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

Toxicity to Aquatic Plants

Calcium branched alkyl phenate sulphide (overbased) EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

Toxicity to Aquatic Plants

Calcium branched alkyl phenate sulphide EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

Toxicity to Aquatic Plants

Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.36 mg/l

Toxicity to Aquatic Plants

2,6-Di-tert-butylphenol EC 50 (Green algae (Selenastrum capricornutum), 3 d): 3.6 mg/l

Toxicity to Aquatic Plants

Diphenylamine EC 50 (Green algae (Selenastrum capricornutum), 3 d): 1.51 mg/l

12.1 Toxicity

EC 50 (Green algae (Scenedesmus quadricauda), 3 d): > 100 mg/l

Toxicity to microorganisms

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Sludge, 0.1 d): > 10,000 mg/l

Toxicity

Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts: EC 50 (Sludge, 0.1 d): > 10,000 mg/l

Persistence and degradability

Bioaccumulative potential

Mobility in soil

Results of PBT and vPvB assessment

Endocrine disrupting properties

Other adverse effects

Toxicity to microorganisms

Calcium branched alkyl phenate sulphide (overbased) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Toxicity

Calcium branched alkyl phenate sulphide EC 50 (Sludge, 0.1 d): > 1,000 mg/l

Toxicity to microorganisms

Phenol, dodecyl-, branched EC 50 (Sludge, 0.1 d): > 1,000 mg/l

Toxicity

2,6-Di-tert-butylphenol EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Toxicity

++ O,O,O-triphenyl phosphorothioate EC 50 (Sludge, 3 h): > 100 mg/l

12.2 Persistence and Degradability

### Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Distillates (petroleum), hydrotreated heavy paraffinic OECD TG 301 F, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts OECD TG 301 B, 1.5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts OECD TG 301 D, 8 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Calcium branched alkyl phenate sulphide (overbased) OECD TG 301 B, 4.7 - 10.8 %, 28 d, Not readily degradable. Inherent Sludge, 38.8 %, 28 d

12.2 Persistence and Degradability

### Biodegradation Calcium branched alkyl phenate sulphide OECD TG 301 B, 4.7 - 10.8 %, 28 d, Not readily degradable. Inherent Sludge, 38.8 %, 28 d

12.2 Persistence and Degradability

Biodegradation Phenol, dodecyl-, branched Miscellaneous, 10 %, 56 d, Not readily degradable. OECD TG 301 B, 25 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation 2,6-Di-tert-butylphenol OECD TG 302 B, 24 %, 28 d, Not readily degradable. OECD TG 301 B, 5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Diphenylamine OECD TG 301 D, 26 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

++ O,O,O-triphenyl phosphorothioate OECD TG 301 B, 17.8 - 19.3 %, 28 d, Not readily degradable. OECD TG 302 C, 59.9 - 66.8 %, 28 d

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF)

12.3 Bioaccumulative potential

Calcium branched alkyl phenate sulphide (overbased) Bioconcentration Factor (BCF): 2.2

12.3 Bioaccumulative potential

Calcium branched alkyl phenate sulphide Bioconcentration Factor (BCF): 2.2 Bioconcentration Factor (BCF): 2.2

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) Phenol, dodecyl-, branched Bioconcentration Factor (BCF): 794.33 (Measured)

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) ++ O,O,O-triphenyl phosphorothioate Fish, Bioconcentration Factor (BCF): 2,551 (Flow Through)

12.3 Bioaccumulative potential

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts Log Kow: 0.56 (Measured)

12.3 Bioaccumulative potential

Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts Log Kow: 10.88 (Read across)

12.3 Bioaccumulative potential

Calcium branched alkyl phenate sulphide (overbased) Log Kow: 11.08 (Measured)

12.3 Bioaccumulative potential

Calcium branched alkyl phenate sulphide Log Kow: 11.08 (Measured)

12.3 Bioaccumulative potential

Phenol, dodecyl-, branched Log Kow: 7.14 (Measured)

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties:

Product: This substance/mixture contains components considered to have endocrine disrupting properties for environment, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. Phenol, dodecyl-, branched The substance is considered to have endocrine disrupting properties according to REACH Article 57(f) for the environment.

The product contains components considered to have endocrine disrupting properties for the environment, specifically Phenol, dodecyl-, branched, according to REACH Article 57(f).

12.7 Other adverse effects

This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity. Harmful to aquatic life with long lasting effects. Calcium branched alkyl phenate sulphide (overbased) This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity. Calcium branched alkyl phenate sulphide This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity.

The material contains an alkylated phenol impurity (highly toxic). Testing of the calcium phenate component indicates long-lasting harmful effects to aquatic life (Aquatic Chronic 4). The product is classified as harmful to aquatic life with long-lasting effects.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LUBRIZOL® CV1100?

The signal word is warning.

What is the physical form of LUBRIZOL® CV1100?

LUBRIZOL® CV1100 is a liquid appearing as dark brown with dark brown color. It has mild odor.

What is LUBRIZOL® CV1100 used for?

Heavy duty diesel engine oil additive.

What are the hazard statements for LUBRIZOL® CV1100?

This substance has 2 hazard statements:

  • H315: Causes skin irritation.
  • H411: Toxic to aquatic life with long lasting effects.