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Safety Data Sheet EN

Syntilo 81 BF

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Syntilo 81 BF
Product Form
Liquid
Product Code
464351-FR01

Regulatory Identifiers

CAS Number
N/A
UFI Code
CFP2-40NW-0004-T5EY

Identified Uses

Handling and dilution of metal working fluid concentrates-Industrial Use of lubricants in high energy open processes-Industrial Use of lubricants in high energy open processes-Professional Use of the substance/mixture Metalworking fluid - soluble. For specific application advice see appropriate Technical Data Sheet or consult our company representative.

Manufacturers & Suppliers

C

Castrol Holdings Europe B.V.

manufacturer

d'Arcyweg 76, 3198NA Europoort Rotterdam

C

Castrol France SAS

manufacturer

Campus Saint Christophe, Bâtiment Galilée 3, 10 Avenue de l'Entreprise, Cergy-Pontoise, Cedex, 95863

+33 (0) 805 638 302

Emergency Contacts

ORFILA

01 45 42 59 59

Centre Anti-Poisons de Paris, Hôpital Fernand Widal

01 40 05 48 48

Centre Antipoison et de Toxicovigilance de LYON

04 72 11 69 11

Centre Anti-Poisons de Marseille, Hôpital Salvator

04 91 75 25 25

Permanence BP France

01 30 30 49 99

24/24

Carechem

+44 (0) 1235 239 670

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves. Wear eye or face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Corrosion inhibitors and additives in aqueous solution.

Chemical Name CAS Number Concentration Hazardous
carbonic acid, compound with 2-aminoethanol (1:2) EC: 244-600-2 21829-52-7 10 - 16% Yes
2-aminoethanol EC: 205-483-3 141-43-5 8.6% Yes
1,2-ethanediamine, N,N,N',N'-tetramethyl-, polymer with 1,1'-oxybis(2-chloroethane) 31075-24-8 0.3% Yes
3-iodo-2-propynyl butylcarbamate EC: 259-627-5 55406-53-6 0.3% Yes
sodium 4(or 5)-methyl-1H-benzotriazolide EC: 265-004-9 64665-57-2 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove to fresh air. Get medical attention if symptoms occur.

Symptoms: Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Overexposure to the inhalation of airborne droplets or aerosols may cause irritation of the respiratory tract.

Skin contact

Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention.

Symptoms: Causes skin irritation. Defatting to the skin. Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis.

Eye contact

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention.

Symptoms: Causes serious eye irritation. Potential risk of transient stinging or redness if accidental eye contact occurs.

Ingestion

Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Wash out mouth with water if person is conscious. Get medical attention if symptoms occur.

Symptoms: Irritating to mouth, throat and stomach. Ingestion of large quantities may cause nausea and diarrhoea.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treatment should in general be symptomatic and directed to relieving any effects.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use foam or all-purpose dry chemical to extinguish.

Unsuitable media

Do not use water jet. The use of a water jet may cause the fire to spread by splashing the burning product.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

No action shall be taken involving any personal risk or without suitable training. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Floors may be slippery; use care to avoid falling.

Small spill

Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Contaminated absorbent material may pose the same hazard as the spilt product. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Absorb with an inert material and place in an appropriate waste disposal container. Contain and collect spillage with non-combustible, absorbent material.

Materials: sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Avoid contact of spilt material and runoff with soil and surface waterways. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Empty containers retain product residue and can be hazardous. Avoid prolonged or repeated contact with skin. During metal working, solid particles from workpieces or tools will contaminate the fluid and may cause abrasions of the skin. Where such abrasions result in a penetration of the skin, first aid treatment should be applied as soon as reasonably possible. The presence of certain metals in the workpiece or tool, such as chromium, cobalt and nickel, can contaminate the metalworking fluid and as a result may induce allergic skin reactions. Evaporation of water from soluble cutting fluids during use may lead to an increase in concentration which may result in the development of skin conditions due to irritation and defatting. It is important to monitor fluid strength on a regular basis with a refractometer and maintain it at the recommended concentration. Lubricants from other sources and other contaminants should be minimised. Swarf and other debris should be removed.

Storage

Store in a dry, cool and well-ventilated area. Protect from freezing. Keep away from heat and direct sunlight.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Keep away from heat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.

Hands

Wear suitable gloves. Recommended: Nitrile gloves. Gloves should be chosen in consultation with the supplier / manufacturer and taking account of a full assessment of the working conditions. Continuous contact: Gloves with a minimum breakthrough time of 240 minutes, or >480 minutes if suitable gloves can be obtained. Short-term / splash protection: Recommended breakthrough times as above. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm. Standards: EN 420, EN 374.

Eyes

Safety glasses with side shields. Standards: EN 166.

Respiratory

In case of insufficient ventilation, wear suitable respiratory equipment. For protection against metal working fluids, respiratory protection that is classified as "resistant to oil" (class R) or oil proof (class P) should be selected where appropriate. Standards: EN 529, EN 149, EN 405, EN 140 plus filter, EN 136 plus filter, EN 143, EN 14387.

Skin/Body

Use of protective clothing is good industrial practice. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Yellow. [Light]
Colour Intensity
---
Form
---
Odor
Not available.
Odor Threshold
Not available.
Ph
9.2 [Conc. (% w/w): 3%]
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
Closed cup: >100°C (>212°F) [Estimated. Water content interferes with flash point determination.]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Water: 23.8 mm Hg (3.2 kPa) at 20°C; 2,2',2"-nitrilotriethanol: <0.0075 mm Hg (<0.001 kPa) at 20°C; sebacic acid: 0 mm Hg (0 kPa) at 20°C; 2-aminoethanol: 0.4 mm Hg (0.053 kPa) at 20°C; 6,6',6"-(1,3,5-triazine-2,4,6-triflurimino) trihexanoic acid: 0 mm Hg (0 kPa) at 20°C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
>1000 kg/m³ (>1 g/cm³) at 20°C
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
2,2',2"-nitrilotriethanol: 324°C (615.2°F); 2-aminoethanol: 410°C (770°F)
Decomposition Temperature
---
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic: 9.4 mm²/s (9.4 cSt) at 40°C
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerisation will not occur.

Avoid

High temperatures

Incompatible

Reactive or incompatible with the following materials: oxidising materials. Slightly reactive or incompatible with the following materials: acids.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Environmental hazards Toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability

Expected to be biodegradable.

12.3 Bioaccumulative potential

Not available.

12.4 Mobility in soil

Soil/water partition coefficient (Koc) Not available. Mobility Liquid. Soluble in water.

12.5 Results of PBT and vPvB assessment

Product does not meet the criteria for PBT or vPvB according to Regulation (EC) No. 1907/2006, Annex XIII.

Product does not meet the criteria for PBT or vPvB according to Regulation (EC) No. 1907/2006, Annex XIII.

12.6 Endocrine disrupting properties

Not available. Remarks - Endocrine disruptor - Environment Not available.

12.7 Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of via an authorised person/ licensed waste disposal contractor. For diluted fluid: emulsion splitting, coagulation and filtration.

Disposal

Where possible, arrange for product to be recycled. Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.

Waste Codes

12 01 10* synthetic machining oils EWC
12 01 09* machining emulsions and solutions free of halogens EWC
15 01 10* packaging containing residues of or contaminated by hazardous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
Environmentally hazardous substance, liquid, n.o.s. (1,2-ethanediamine, N,N,N',N'-tetramethyl-, polymer with 1,1'-oxybis(2-chloroethane), 3-lodo-2-propynyl butylcarbamate)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The company, as identified in Section 1, sells this product in the EU in compliance with the current requirements of REACH.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Syntilo 81 BF?

The signal word is warning.

What is the physical form of Syntilo 81 BF?

Syntilo 81 BF is a liquid. with yellow. [light] color. It has not available. odor.

What is Syntilo 81 BF used for?

Handling and dilution of metal working fluid concentrates-Industrial Use of lubricants in high energy open processes-Industrial Use of lubricants in high energy open processes-Professional Use of the substance/mixture Metalworking fluid - soluble. For specific application advice see appropriate Technical Data Sheet or consult our company representative.

What are the hazard statements for Syntilo 81 BF?

This substance has 3 hazard statements:

  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Syntilo 81 BF?

The melting point is Not available. and the boiling point is Not available..