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Safety Data Sheet EN

Appretan N9616 liq RT

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Appretan N9616 liq RT
Product Code
124644

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Textile processing industry Textile finish

Manufacturers & Suppliers

A

Archroma Distrib.&Mgt. GmbH, Sede sec.IT

distributor

Via Gabriele D'Annunzio 2 – 21010 Vizzola Ticino (VA).

+39 031 8123180

Emergency Contacts

Emergency Contact

+33 1 7211 0003

NCEC (EU)

+44 1235 239670

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-one (3:1) EC: 911-418-6 55965-84-9 0.0002 - 0.0015% Yes
Formaldehyde EC: 200-001-8 50-00-0 0.02 - 0.1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove to fresh air. Get medical advice/ attention.

Skin contact

If on skin, rinse well with water.

Eye contact

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Call in a physician immediately and show him the Safety Data Sheet.

Immediate Medical Attention

Get medical advice/ attention for inhalation, seek medical advice for eye contact, and call in a physician immediately for ingestion.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray jet, Alcohol-resistant foam, Dry powder, Carbon dioxide (CO2)

Unsuitable media

High volume water jet

Specific hazards

In case of fire hazardous decomposition products may be produced such as: Carbon monoxide and carbon dioxide

Firefighter Protection

Self-contained breathing apparatus, Full protective suit

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Collect contaminated fire extinguishing water separately. This must not be discharged into drains. The product should not be allowed to enter drains, water courses or the soil.

Cleanup methods

Soak up with inert absorbent material

Materials: inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust)

—

Related Products

Similar products with comparable safety profiles

A

Appretan N92111 liq

---

R

Relca-TOP-6201 liq

---

R

RADIA 9565

---

R

RADIA 6109

CAS: 91744-20-6

R

RADIA 7916

CAS: 85586-21-6

R

RADIA 6101

CAS: 8002-13-9

R

RADIA 7169

CAS: 68604-44-4

R

RADIA 6120

CAS: 8001-22-7

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only in well-ventilated areas. It cannot be ruled out, that traces of following substances are present. Formaldehyde

Storage

Protect against frost. The product after freezing is no longer usable. Protect from extreme heat and cold.

Hygiene

Wash hands before breaks and at the end of workday. Use protective skin cream before handling the product. Take off immediately all contaminated clothing and wash it before reuse. Do not eat, drink or smoke when using this product. Observe the usual precautions for handling chemicals.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Local ventilation recommended - mechanical ventilation may be used.

Hands

Nitrile rubber gloves. These types of protective gloves are offered by various manufacturers. Please note the manufacturers' detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.

Eyes

Safety glasses. see respiratory protection

Respiratory

Use respiratory protection in case of insufficient exhaust ventilation or prolonged exposure. Filter A (organic gases and vapours) to standard DIN EN 141

Skin/Body

Wear suitable protective clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
milky white
Colour Intensity
---
Form
Liquid
Odor
slight, of acrylate
Odor Threshold
not available
Ph
3 - 5 (20 °C) Method: ISO 1148 Determined in the undiluted form
Melting Point
---
Boiling Point
approx. 100 °C
Flash Point
Method: NFT 60103 (closed cup) No flash point upto 100 °C.
Freezing Point
---
Softening Point
---
Solidification Point
approx. 0 °C
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
not available
Vapor Pressure
approx. 23 hPa (20 °C) Corresp. to vapour pressure of water
Vapor Density
---
Relative Density
approx. 1
Bulk Density
---
Density
1,0 g/cm³
Flammability
The product is not flammable.
Upper Explosive Limit
not available
Lower Explosive Limit
not available
Explosive Limits
---
Auto Ignition Temperature
not available
Decomposition Temperature
not available
Solubility
---
Partition Coefficient
This property is not applicable for mixtures.
Solubility In Water
completely miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
Method: Expert judgement Not corrosive to metals
Dynamic Viscosity
50 - 120 mPa.s Method: ISO 2555
Kinematic Viscosity
not available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

See section 10.3. "Possibility of hazardous reactions"

Hazardous reactions

No dangerous reaction known under conditions of normal use.

Avoid

freezing

Incompatible

not known

Decomposition

No hazardous decomposition products if stored and handled as prescribed

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Information related to the product itself: Fish toxicity: not available Fish toxicity (chronic): not available Daphnia toxicity: not available Daphnia toxicity (chronic): not available Algae toxicity: not available Bacteria toxicity: not available Information related to the component: 5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-one (3:1)

12.1. Toxicity

Fish toxicity: LC50 0,19 mg/l (96 h, Oncorhynchus mykiss (rainbow trout)) Method: EPA OPP 72-1 Fish toxicity (chronic): NOEC >= 46,4 μg/l (35 d, Danio rerio (zebra fish)) Analytical monitoring: yes Method: OECD Test Guideline 210 Daphnia toxicity: EC50 0,16 mg/l (48 h, Daphnia magna (Water flea)) Method: EPA OPP 72-2 Daphnia toxicity (chronic): NOEC 0,1 mg/l (21 d, Daphnia magna (Water flea)) Analytical monitoring: yes Method: OPP 72-4 (EPA-Guideline): Fish early life stage and aquatic invertebrates life cycle studies Algae toxicity: EC50 (Growth rate) 19,9 μg/l (72 h, Skeletonema costatum (marine diatom)) Method: OECD Test Guideline 201 Bacteria toxicity: EC50 4,5 mg/l (3 h, activated sludge of a predominantly domestic sewage) Method: OECD Test Guideline 209 Toxicity to soil-dwelling organisms: NOEC 8,8 mg/kg (14 d, Eisenia fetida (earthworms)) Method: OECD Test Guideline 207 NOEC 1 mg/kg (28 d, soil dwelling microorganisms) Method: OECD 217 Toxicity to terrestrial plants: NOEC 1.000 mg/l (21 d) Method: OECD Test Guideline 208 Sediment toxicity: Hyalella azteca (Scud) Test type: flow-through test Type of sediment: Artificial sediment Duration: 28 d NOEC 3,7 mg/l

12.1. Toxicity

Fish toxicity : LC50 24,1 mg/l (96 h, Pimephales promelas (fathead minnow)) Method : OECD Test Guideline 203 Fish toxicity (chronic) : NOEC >= 48 mg/l (28 d, Oryzias latipes (Japanese medaka)) Method : OECD Test Guideline 215 Daphnia toxicity : EC50 5,8 mg/l (48 h, Daphnia pulex (Water flea)) Method : OECD Test Guideline 202 Daphnia toxicity (chronic) : NOEC >= 6,4 mg/l (21 d, Daphnia magna (Water flea)) Method : OECD Test Guideline 211 Algae toxicity : EC50 (Growth rate) 6,61 mg/l (72 h, Desmodesmus subspicatus (Scenedesmus subspicatus)) Method : OECD Test Guideline 201 Bacteria toxicity : EC50 19 mg/l (3 h, activated sludge) Method : OECD Test Guideline 209

12.2. Persistence and degradability

Information related to the product itself: Physico-chemical eliminability : not available Biodegradability : not available Chemical oxygen demand (COD) : 1.250 g/l Biochemical oxygen demand (BOD5) : 56 g/l 5 d Information related to the component: 5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-one (3:1)

12.2. Persistence and degradability

Photodegradation : air The value is given based on a SAR/AAR approach using OECD Toolbox, DEREK, VEGA QSAR models (Cesar models), etc. Biodegradability : 47,6 % (28 d, Carbon dioxide (CO2)) Not readily biodegradable. Method : OECD Test Guideline 301B

12.2. Persistence and degradability

Photodegradation : air Biodegradability : 99 % (28 d) Readily biodegradable. Method : OECD Test Guideline 301A

12.3. Bioaccumulative potential

Information related to the product itself: Bioaccumulation: No information is available on the mixture "as is". If relevant information is available on the substances listed in Chapter 3, it is reported here. Information related to the component: 5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-one (3:1)

No information is available on the mixture as is.

12.3. Bioaccumulative potential

Bioaccumulation: Bioconcentration factor (BCF): 54
Method : OECD Guide-line 305 E

12.3. Bioaccumulative potential

Bioaccumulation: Bioconcentration factor (BCF): < 1

12.4. Mobility in soil

Information related to the product itself: Transport and distribution between environmental compartments: No information is available on the mixture "as is". If relevant information is available on the substances listed in Chapter 3, it is reported here. Information related to the component: 5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-one (3:1) Transport and distribution between environmental compartments: adsorption (Soil)
Koc : 7,7
Method : OECD Test Guideline 106 Information related to the component: Formaldehyde Transport and distribution between environmental compartments: adsorption (Soil)
Koc : 15,9
log Koc : 1,202

12.5. Results of PBT and vPvB assessment

Information related to the product itself: No information is available on the mixture "as is". If relevant information is available on the substances listed in Chapter 3, it is reported here. Information related to the component: 5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-one (3:1) The substance is not identified as a PBT or as a vPvB substance. Information related to the component: Formaldehyde The substance is not identified as a PBT or as a vPvB substance.

The mixture is not assessed as a whole. The components 5-Chloro-2-methyl-2,3-dihydroisothiazol-3-one and 2-Methyl-2,3-dihydroisothiazol-3-one (3:1) and Formaldehyde are not identified as PBT or vPvB substances.

12.6. Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7. Other adverse effects

Information related to the product itself: Additional ecotoxicological remarks Avoid release to the environment.

Avoid release to the environment.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Appretan N9616 liq RT?

The signal word is no signal word.

What is the physical form of Appretan N9616 liq RT?

Appretan N9616 liq RT is a liquid with milky white color. It has slight, of acrylate odor.

What is Appretan N9616 liq RT used for?

Textile processing industry Textile finish