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Safety Data Sheet EN

RADIA 3901

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
RADIA 3901
Product Form
Mixture

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial use wide dispersive use

Uses advised against

No additional information available

Manufacturers & Suppliers

OLEON N.V. logo

OLEON N.V.

manufacturer

Assenedestraat 2, 9940 Ertvelde - Belgium

+32 9 341 10 11

http://www.oleon.com

Emergency Contacts

SGS ERS

+32 3 575 55 55

24/7

SGS ERS

+1 888 765 6554

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
STOT SE Cat. 1 H370

GHS Pictograms

GHS02 - Flammable

GHS02

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H301 + H311 Toxic if swallowed or in contact with skin.
H370 Causes damage to organs.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P260 Do not breathe mist, spray, vapours.
P264 Wash hands thoroughly after handling.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
methanol EC: 200-659-6 67-56-1 60 - 100% Yes

Notes

Composition of product is highly variable

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Immediately consult a doctor/medical service.

Symptoms: EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Symptoms similar to those listed under ingestion.

Skin contact

Wash immediately with lots of water. Soap may be used. Do not apply (chemical) neutralizing agents. Remove clothing before washing. Consult a doctor/medical service.

Symptoms: Symptoms similar to those listed under ingestion.

Eye contact

Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Take victim to an ophthalmologist if irritation persists.

Symptoms: Redness of the eye tissue. Lacrimation.

Ingestion

Rinse mouth with water. Immediately after ingestion, give alcohol to drink. Give nothing to drink. Do not induce vomiting. Immediately consult a doctor/medical service. Take the container/vomit to the doctor/hospital. Call Poison Information Centre (www.who.int/ipcs/poisons/centre/directory/en).

Symptoms: Nausea. Vomiting. AFTER INGESTION OF HIGH QUANTITIES: FOLLOWING SYMPTOMS MAY APPEAR LATER: Change in the haemogramme/blood composition. Headache. Feeling of weakness. Abdominal pain. Muscular pain. Central nervous system depression. Dizziness. Mental confusion. Drunkenness. Coordination disorders. Disturbed motor response. Disturbances of consciousness. Visual disturbances. Blindness. Respiratory difficulties. Cramps/uncontrolled muscular contractions.

Immediate Medical Attention

Immediately consult a doctor/medical service.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Specific hazards

DIRECT FIRE HAZARD: Highly flammable liquid and vapour. Gas/vapour flammable with air within explosion limits. INDIRECT FIRE HAZARD: May be ignited by sparks. DIRECT EXPLOSION HAZARD: Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD: may be ignited by sparks. Reactions with explosion hazards: see 'Reactivity Hazard'.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep upwind. Mark the danger area. Close doors and windows of adjacent premises.

Environmental

Prevent soil and water pollution.

—

Related Products

Similar products with comparable safety profiles

R

RADIA 3903

---

R

RADIA 3905

---

R

RADIA 3907

---

R

RADIA 3906

---

R

RADIA 3908

---

R

RADIA 3900

---

R

RADIA 3911

---

R

RADIA 3910

---

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handling temperature: ≥ 10 °C above melting point

Storage

Store in a cool area. Store in a dry area. Keep container in a well-ventilated place. Fireproof storeroom. Keep locked up. Aboveground.

Fire prevention

Fireproof storeroom.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Gloves.

Eyes

Protective goggles.

Respiratory

Wear gas mask with filter type A if conc. in air > exposure limit. High vapour/gas concentration: self-contained respirator.

Skin/Body

Head/neck protection. Protective clothing. Materials for protective clothing: GIVE GOOD RESISTANCE: polyethylene/ethylenevinylalcohol. styrene-butadiene rubber. viton. GIVE LESS RESISTANCE: chloroprene rubber. chlorinated polyethylene. natural rubber. nitrile rubber/PVC. GIVE POOR RESISTANCE: leather. neoprene. nitrile rubber. polyethylene. PVA. PVC. polyurethane

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Characteristic odour. Sweet odour.
Odor Threshold
---
Ph
---
Melting Point
0 °C
Boiling Point
ca. 65 °C (1013 hPa)
Flash Point
ca. 10 °C (1013 hPa)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
4,1 (butylacetate=1); 6,3 (ether=1)
Evaporation Rate
---
Vapor Pressure
128 hPa (20 °C)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
ca. 0,9 g/cm³ (20°C)
Flammability
---
Upper Explosive Limit
36,5 vol %
Lower Explosive Limit
5,5 vol %
Explosive Limits
---
Auto Ignition Temperature
ca. 455 °C (1013 hPa)
Decomposition Temperature
---
Solubility
Ethanol: complete; Ether: complete; Acetone: complete
Partition Coefficient
---
Solubility In Water
Insoluble
Solubility In Fat
Soluble in oils/fats
Molecular Weight
32,04 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
ca. 0,5 mm²/s (25°C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

Violent to explosive reaction with (some) metal powders and with (strong) oxidizers. Violent exothermic reaction with (some) acids and with (some) halogens compounds.

Hazardous reactions

No additional information available

Avoid

No supplementary information available.

Incompatible

No supplementary information available.

Decomposition

No supplementary information available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecology - general : No supplementary information available. Ecology - air : No supplementary information available. Ecology - water : Mild water pollutant (surface water) Not harmful to fishes (LC50(96h) >1000 mg/l) Not harmful to invertebrates (Daphnia) (EC50, 48 h, > 1000 mg/l) Not harmful to algae (EC50(72h) >1000 mg/l) Slightly harmful to bacteria (EC50 100/1000 mg/l) Sludge digestion is inhibited at 800 mg/l Nitrification of activated sludge is inhibited at 160 mg/l 50% Acute aquatic toxicity : Not classified Chronic aquatic toxicity : Not classified

12.2 Persistence and degradability

Readily biodegradable in water test: 99% OECD 301D. BOD 80% ThOD

12.3 Bioaccumulative potential

Slightly bioaccumulative

12.1. Toxicity

| methanol (67-56-1) | | | --- | --- | | LC50 fish 1 | 15400 mg/l (EPA 660/3 - 75/009, 96 h, Lepomis macrochirus, Flow-through system, Fresh water, Experimental value, Lethal) | | EC50 Daphnia 1 | 18260 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 96 h, Daphnia magna, Semi-static system, Fresh water, Locomotor effect) | | ErC50 (algae) | 22000 mg/l (OECD 201: Alga, Growth Inhibition Test, 96 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value) |

12.2. Persistence and degradability

Readily biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) | 0,6 - 1,12 g O2/g substance Chemical oxygen demand (COD) | 1,42 g O2/g substance ThOD | 1,5 g O2/g substance

Methanol is readily biodegradable in both soil and water.

12.3. Bioaccumulative potential

methanol (67-56-1) | BCF fish 1 | 1 - 4,5 (72 h, Cyprinus carpio, Static system, Fresh water, Experimental value) | | --- | --- | | Log Pow | -0,77 (Experimental value) | | Bioaccumulative potential | Low potential for bioaccumulation (BCF < 500). |

Low potential for bioaccumulation (BCF < 500).

12.4. Mobility in soil

methanol (67-56-1) | Surface tension | 0,023 N/m (20 °C) | | --- | --- | | Log Koc | 0,088 (log Koc, SRC PCKOCWIN v2.0, Calculated value) | | Ecology - soil | Highly mobile in soil. |

12.5. Results of PBT and vPvB assessment

Component | methanol (67-56-1) | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |

The substance does not meet the PBT or vPvB criteria of REACH regulation, annex XIII.

12.6. Other adverse effects

No additional information available

No additional information available

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Take up liquid spill into a non combustible material e.g.: sand, earth, vermiculite, slaked lime, or soda ash. Scoop absorbed substance into closing containers. See "Material-handling" for suitable container materials. Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling

Disposal

Recycle by distillation. Incinerate under surveillance. Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.

Waste Codes

KGA category 06 LWCA (the Netherlands) national code
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1230
Shipping Name
METHANOL
Transport Class
3 (6.1)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for RADIA 3901?

The signal word is danger.

What is the physical form of RADIA 3901?

RADIA 3901 is a liquid appearing as liquid. with colourless. color. It has characteristic odour. sweet odour. odor.

What is the solubility of RADIA 3901?

Ethanol: complete; Ether: complete; Acetone: complete

What is RADIA 3901 used for?

Industrial use wide dispersive use

What are the hazard statements for RADIA 3901?

This substance has 3 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H301 + H311: Toxic if swallowed or in contact with skin.
  • H370: Causes damage to organs.

What is the melting point of RADIA 3901?

The melting point is 0 °C and the boiling point is ca. 65 °C (1013 hPa).