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Safety Data Sheet EN

HiTEC® 4103W Cetane Improver

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
HiTEC® 4103W Cetane Improver
Product Form
Liquid.

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119539586-27

Identified Uses

Industrial. Formulation and blending of fuel additives and fuels. Consumer. Use of product within an Aftermarket product.

Manufacturers & Suppliers

A

Afton Chemical Limited

manufacturer

Euro-Tech Centre, London Road, Bracknell, RG12 2UW, England

+44 1344 304141

A

Afton Chemical S.R.L. (Woluwe)

manufacturer

Alma Court, Lenneke Marelaan, 8, B-1932, St-Stevens-Woluwe, Belgium

+32 2 715 2211

A

Afton Chemical SPRL (Feluy Plant)

manufacturer

Rue de Scoufflény, 50, B-7191 Ecaussinnes Lalaing, Belgium

+32 67 286211

Emergency Contacts

Emergency Contact

+43-13649237

24 hours a day, 7 days a week

Emergency Contact

+32-28083237

24 hours a day, 7 days a week

Emergency Contact

+359-32570104

24 hours a day, 7 days a week

Emergency Contact

+385-17776920

24 hours a day, 7 days a week

Emergency Contact

+420-228880039

24 hours a day, 7 days a week

Emergency Contact

+45-69918573

24 hours a day, 7 days a week

Emergency Contact

+358-942419014

24 hours a day, 7 days a week

Emergency Contact

+33-975181407

24 hours a day, 7 days a week

Emergency Contact

+36-18088425

24 hours a day, 7 days a week

Emergency Contact

+353-19014670

24 hours a day, 7 days a week

Emergency Contact

+39-0245557031

24 hours a day, 7 days a week

Emergency Contact

+352-20202416

24 hours a day, 7 days a week

Emergency Contact

+31-858880596

24 hours a day, 7 days a week

Emergency Contact

+47-21930678

24 hours a day, 7 days a week

Emergency Contact

+48-223988029

24 hours a day, 7 days a week

Emergency Contact

+351-308801773

24 hours a day, 7 days a week

Emergency Contact

+421-233057972

24 hours a day, 7 days a week

Emergency Contact

+38-618888016

24 hours a day, 7 days a week

Emergency Contact

+46-852503403

24 hours a day, 7 days a week

Emergency Contact

+41-435082011

24 hours a day, 7 days a week

Emergency Contact

+380-947101374

24 hours a day, 7 days a week

Emergency Contact

+44-8708200418

24 hours a day, 7 days a week

Emergency Contact

+1-703-527-3887

24 hours a day, 7 days a week

Emergency Contact

+65-3158-1349

24 hours a day, 7 days a week

Emergency Contact

+61-290372994

24 hours a day, 7 days a week

Emergency Contact

4001-204937

24 hours a day, 7 days a week

Emergency Contact

+(91)-22-3354 3594

24 hours a day, 7 days a week

Emergency Contact

+81-345209637

24 hours a day, 7 days a week

Emergency Contact

00-308-13-2549

24 hours a day, 7 days a week

Emergency Contact

+1-703-741-5979

24 hours a day, 7 days a week

Emergency Contact

1-800-424-9300

24 hours a day, 7 days a week

Emergency Contact

+32 (0)70 245 245

Emergency Contact

+45 8212 1212

Emergency Contact

+33 (0)1 45 42 59 59

Emergency Contact

+30 210 779 3777

Emergency Contact

+371 67042473

Emergency Contact

+43-13649237

Emergency Contact

+31 (0)30 2748888

Emergency Contact

+47 22 59 13 00

Emergency Contact

+351 800 250 250

Emergency Contact

+40 (0)21 318 36 06

8am – 3pm

Emergency Contact

+34 91 562 04 20

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P235 Keep cool.
P261 Avoid breathing vapor.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P281 Wear protective clothing.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P315 Get immediate medical attention.
P391 Collect spillage.
P403 Store in a well-ventilated place.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
2-ethylhexyl nitrate EC: 248-363-6 27247-96-7 100% Yes

The mineral oils in the product contain < 3% DMSO extract (IP 346).

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. If not breathing, give artificial respiration. If breathing is difficult, administer oxygen.

Symptoms: Harmful if inhaled. Adverse symptoms may include the following: Inhalation of vapors may cause a sharp decrease in blood pressure with resulting loss of consciousness.

Skin contact

Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Continue to rinse for at least 15 minutes.

Symptoms: Harmful in contact with skin. Defatting to the skin. May cause skin dryness and irritation. Adverse symptoms may include the following: irritation, dryness, cracking. Overexposure to organic nitrates by inhalation of vapor or skin contact may cause headache, dizziness, nausea, and decreased blood pressure.

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: No known significant effects or critical hazards. No specific data.

Ingestion

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Harmful if swallowed. No specific data.

Immediate Medical Attention

Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. If unconscious, get medical attention immediately.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

In case of fire, use water spray (fog), foam, dry chemical or CO₂.

Unsuitable media

Do not use water jet.

Specific hazards

Risk of explosion if heated under confinement. In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move people out of line-of-sight of the scene and away from windows. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. Do not fight fire when it reaches the material. Withdraw from fire and let it burn. Spray storage vessels with water to maintain temperature below 100°C/212°F.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Fire-fighters' protective clothing will only provide limited protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Collect spillage.

Materials: inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from heat. Empty containers retain product residue and can be hazardous. Do not reuse container. Do not heat the product.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep away from heat. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Keep away from heat. Use explosion-proof electrical (ventilating, lighting and material handling) equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Hands

Hand Protection: Wear chemical resistant gloves. Nitrile gloves of minimum thickness 0.4 mm have an expected breakthrough time of 480 minutes or less when in frequent contact with the product. Due to variable exposure conditions the user must consider that the practical use of a chemical-protective glove in practice may be much shorter than the permeation time above. Manufacturer's directions for use, especially about the minimum thickness and the minimum breakthrough time, must be observed. This information does not replace suitability tests by the end user since glove protection varies depending on the conditions under which the product is used.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Use appropriate respiratory protection if there is the potential to exceed the exposure limit(s). Seek professional advice prior to respirator selection and use. Select respirator based on suitability to provide adequate worker protection for given working conditions and level of airborne contaminant. Approved/certified respirator with organic vapor cartridge.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid. [Clear viscous liquid.]
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear viscous liquid.
Colour
White to yellowish. Pale color.
Colour Intensity
---
Form
---
Odor
Fruity. Pungent. Ester. Characteristic.
Odor Threshold
Not available.
Ph
Not available.
Melting Point
<-45°C
Boiling Point
Decomposition temperature: >100°C
Flash Point
Closed cup: 65°C [Pensky-Martens. Minimum]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
0.027 kPa [room temperature]
Vapor Density
Not available.
Relative Density
0.95
Bulk Density
---
Density
0.968 g/cm³ [20°C]
Flammability
Not applicable (liquid).
Upper Explosive Limit
---
Lower Explosive Limit
0.85%
Explosive Limits
---
Auto Ignition Temperature
130°C
Decomposition Temperature
>100°C
Solubility
Insoluble in the following materials: cold water.
Partition Coefficient
5.24
Solubility In Water
12.6 g/l
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Dynamic (room temperature): 1.7 mPa·s (1.7 cP)
Kinematic Viscosity
Kinematic (room temperature): 0.018 cm²/s (1.8 cSt)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Unstable at temperatures greater than 100°C/212°F.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Hazardous reactions or instability may occur under certain conditions of storage or use. Reactions may include the following: risk of explosion

Avoid

heating under confinement

Incompatible

Strong oxidizing and reducing agents.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | Remarks | | 2-ethylhexyl nitrate | Acute EL50 3.22 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Acute EL50 >12.6 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute EL50 >1000 mg/l | Micro-organism | 3 hours | - | | | Acute LC50 2 mg/l | Fish - Danio rerio | 96 hours | - | | | Chronic EL10 1.54 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | --- | --- | --- | --- |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | 2-ethylhexyl nitrate | OECD 310 Ready Biodegradability - CO₂ in Sealed Vessels (Headspace Test) | 0 % - Not readily - 28 days | - |

12.3 Bioaccumulative potential

## 12.3 Bioaccumulative potential | Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | 2-ethylhexyl nitrate | 5.24 | - | high |

12.4 Mobility in soil

Soil/water partition : 5623.4 coefficient (Koc) Mobility : Not available.

12.5 Results of PBT and vPvB assessment

| Product/ingredient name | PBT | P | B | T | vPvB | vP | vB | | --- | --- | --- | --- | --- | --- | --- | --- | | 2-ethylhexyl nitrate | No | N/A | N/A | No | N/A | N/A | N/A |
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

13 07 03* other fuels (including mixtures) EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
Environmentally hazardous substance, liquid, n.o.s. (2-ethylhexyl nitrate)
Transport Class
9
Packing Group
III
ADR

Do not heat the product.

IMDG

Do not heat the product.

IATA

Do not heat the product.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for HiTEC® 4103W Cetane Improver?

The signal word is warning.

What is the physical form of HiTEC® 4103W Cetane Improver?

HiTEC® 4103W Cetane Improver is a liquid. [clear viscous liquid.] appearing as clear viscous liquid. with white to yellowish. pale color. color. It has fruity. pungent. ester. characteristic. odor.

What is the solubility of HiTEC® 4103W Cetane Improver?

Insoluble in the following materials: cold water.

What is HiTEC® 4103W Cetane Improver used for?

Industrial. Formulation and blending of fuel additives and fuels. Consumer. Use of product within an Aftermarket product.

What are the hazard statements for HiTEC® 4103W Cetane Improver?

This substance has 2 hazard statements:

  • H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of HiTEC® 4103W Cetane Improver?

The melting point is <-45°C and the boiling point is Decomposition temperature: >100°C.