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Safety Data Sheet EN

LOCTITE 480

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE 480

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Adhesive

Manufacturers & Suppliers

Henkel Ltd logo

Henkel Ltd

manufacturer

Adhesives Wood Lane End HP2 4RQ Hemel Hempstead Great Britain

+44 (1442) 278000

https://mysds.henkel.com/index.html#/appSelection

Emergency Contacts

Emergency Contact

+44 (0)1442 278497

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing vapors.
P273 Avoid release to the environment.
P280 Wear protective gloves/eye protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with national regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethyl 2-cyanoacrylate EC: 230-391-5 7085-85-0 50 - 100% Yes
Hydroquinone EC: 204-617-8 123-31-9 0.1 - 1% Yes
phthalic anhydride EC: 201-607-5 85-44-9 0.1 - 1% Yes
maleic anhydride EC: 203-571-6 108-31-6 0.0001 - 0.001% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If symptoms persist, seek medical advice.

Symptoms: Irritation, coughing, shortness of breath, chest tightness.

Skin contact

If lips are accidentally stuck together apply warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action. Burns should be treated normally after the adhesive has been removed from the skin. Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water.

Symptoms: Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn.

Eye contact

If the eye is bonded closed, release eyelashes with warm water by covering with wet pad. Keep eye covered until debonding is complete, usually within 1-3 days. Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage.

Symptoms: Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help to debond the adhesive.

Ingestion

Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly separate the solidified product from the mouth (several hours).

Immediate Medical Attention

Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage. If symptoms persist, seek medical advice.

Medical Treatment

Burns should be treated normally after the adhesive has been removed from the skin.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, extinguishing powder, carbon dioxide. Fine water spray

Unsuitable media

None known

Specific hazards

In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released.

Instructions

In case of fire, keep containers cool with water spray.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Wear protective equipment. Avoid contact with skin and eyes.

Environmental

Do not empty into drains / surface water / ground water.

Cleanup methods

Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor.

Materials: water

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid skin and eye contact.

Storage

Refer to Technical Data Sheet

Hygiene

Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure good ventilation/extraction.

Hands

Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Polyethylene or polypropylene gloves are recommended when using large volumes. Do not use PVC, rubber or nylon gloves. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced.

Eyes

Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Protective eye equipment should conform to EN166.

Respiratory

Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387)

Skin/Body

Wear suitable protective clothing. Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
black
Colour Intensity
---
Form
liquid
Odor
irritating
Odor Threshold
---
Ph
Not applicable, Product reacts with water.
Melting Point
Not applicable, Product is a liquid
Boiling Point
> 149 °C (> 300.2 °F) no method
Flash Point
80 - 93 °C (176 - 199.4 °F); Tagliabue closed cup
Freezing Point
---
Softening Point
---
Solidification Point
< -25 °C (< -13 °F)
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 0,5 mm hg (25 °C (77 °F)); < 700 hPa; no method (50 °C (122 °F))
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,05 g/cm³ None (20 °C (68 °F))
Flammability
The product is not flammable.
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
485 °C (905 °F)
Decomposition Temperature
Not applicable, Substance/mixture is not self-reactive, no organic peroxide and does not decompose under foreseen conditions of use
Solubility
Polymerises in presence of water. (20 °C (68 °F); Solvent: Water); Miscible (20 °C (68 °F); Solvent: Acetone)
Partition Coefficient
Not applicable Mixture
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
> 20,5 mm2/s (40 °C (104 °F); )
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.

Hazardous reactions

See section reactivity

Incompatible

See section reactivity.

Decomposition

None if used for intended purpose.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture.

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroquinone 123-31-9 | LC50 | 0,638 mg/l | 96 h | Oncorhynchus mykiss | OECD Guideline 203 (Fish, Acute Toxicity Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | phthalic anhydride 85-44-9 | LC50 | 313 mg/l | 48 h | Leuciscus idus | DIN 38412-15 | | phthalic anhydride 85-44-9 | NOEC | 10 mg/l | 60 d | no data | OECD Guideline 210 (fish early lite stage toxicity test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | maleic anhydride 108-31-6 | LC50 | 115 mg/l | | | OECD Guideline 203 (Fish, Acute Toxicity Test) |

Toxicity

Toxicity (Daphnia): | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroquinone 123-31-9 | EC50 | 0,134 mg/l | 48 h | Daphnia magna | OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) |

Toxicity

Toxicity (Daphnia): | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | phthalic anhydride 85-44-9 | EC50 | >640 mg/l | 48 h | Daphnia magna | other guideline: |

Toxicity

Toxicity (Daphnia): | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | maleic anhydride 108-31-6 | EC50 | 42,81 mg/l | 48 h | Daphnia magna | OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) |

12.1 Toxicity

Chronic toxicity to aquatic invertebrates | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroquinone 123-31-9 | NOEC | 0,0057 mg/l | 21 d | Daphnia magna | OECD 211 (Daphnia magna, Reproduction Test) |

12.1 Toxicity

Chronic toxicity to aquatic invertebrates | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | phthalic anhydride 85-44-9 | NOEC | 16 mg/l | 21 d | Daphnia magna | OECD 211 (Daphnia magna, Reproduction Test) |

Toxicity

Toxicity (Algae): | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroquinone 123-31-9 | EC50 | 0,335 mg/l | 72 h | Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) | OECD Guideline 201 (Alga, Growth Inhibition Test) |

Toxicity

Toxicity (Algae): | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | phthalic anhydride 85-44-9 | EC50 | > 100 mg/l | 72 h | not specified | OECD Guideline 201 (Alga, Growth Inhibition Test) | | phthalic anhydride 85-44-9 | NOEC | 100 mg/l | 72 h | not specified | OECD Guideline 201 (Alga, Growth Inhibition Test) |

Toxicity

Toxicity (Algae): Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method maleic anhydride 108-31-6 | EC50 | 29 mg/l | 72 h | Scenedesmus subspicatus (new name: Desmodesmus subspicatus) | OECD Guideline 201 (Alga, Growth Inhibition Test) maleic anhydride 108-31-6 | EC10 | 23 mg/l | 72 h | Scenedesmus subspicatus (new name: Desmodesmus subspicatus) | OECD Guideline 201 (Alga, Growth Inhibition Test)

12.1 Toxicity

Toxicity to microorganisms Hydroquinone 123-31-9 | EC 50 | 0,038 mg/l | 30 min | | not specified

12.1 Toxicity

Toxicity to microorganisms | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | phthalic anhydride 85-44-9 | EC50 | > 1.000 mg/l | 3 h | activated sludge | ISO 8192 (Test for Inhibition of Oxygen Consumption by Activated Sludge) |

12.1 Toxicity

Toxicity to microorganisms | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | maleic anhydride 108-31-6 | EC0 | > 10.000 mg/l | 30 min | | not specified |

12.2. Persistence and degradability

| Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Ethyl 2-cyanoacrylate 7085-85-0 | not readily biodegradable. | aerobic | 57 % | 28 d | OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) |

12.2. Persistence and degradability

| Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Hydroquinone 123-31-9 | readily biodegradable | aerobic | 75 - 81 % | 30 d | EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Test) |

12.2. Persistence and degradability

| Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | phthalic anhydride 85-44-9 | readily biodegradable | aerobic | 85,2 % | 14 d | OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) |

12.2. Persistence and degradability

| Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | maleic anhydride 108-31-6 | readily biodegradable | aerobic | 98 % | 7 d | OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test) |

12.4. Mobility in soil

Hazardous substances CAS-No. | LogPow | Temperature | Method Ethyl 2-cyanoacrylate 7085-85-0 | 0,776 | 22 °C | EU Method A.8 (Partition Coefficient) Hydroquinone 123-31-9 | 0,59 | | EU Method A.8 (Partition Coefficient) phthalic anhydride 85-44-9 | 1,6 | | EU Method A.8 (Partition Coefficient) maleic anhydride 108-31-6 | 1,62 | | not specified

12.5. Results of PBT and vPvB assessment

| Hazardous substances CAS-No. | PBT / vPvB | | --- | --- | | Ethyl 2-cyanoacrylate 7085-85-0 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. | | Hydroquinone 123-31-9 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. | | phthalic anhydride 85-44-9 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. | | maleic anhydride 108-31-6 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. |

12.6. Endocrine disrupting properties

not applicable

12.7. Other adverse effects

No data available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with local and national regulations.

Disposal

Cured adhesive: Dispose of as water insoluble non-toxic solid chemical in authorised landfill or incinerate under controlled conditions.

Waste Codes

08 04 09* waste adhesives and sealants containing organic solvents and other dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3334
Shipping Name
Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Transport Class
9
Packing Group
III
IATA

Primary packs containing less than 500ml are unregulated by this mode of transport and may be shipped unrestricted.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE 480?

The signal word is warning.

What is the physical form of LOCTITE 480?

LOCTITE 480 is a liquid with black color. It has irritating odor.

What is the solubility of LOCTITE 480?

Polymerises in presence of water. (20 °C (68 °F); Solvent: Water); Miscible (20 °C (68 °F); Solvent: Acetone)

What is LOCTITE 480 used for?

Adhesive

What are the hazard statements for LOCTITE 480?

This substance has 4 hazard statements:

  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of LOCTITE 480?

The melting point is Not applicable, Product is a liquid and the boiling point is > 149 °C (> 300.2 °F) no method.