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Safety Data Sheet EN

Loctite 270

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Loctite 270
Product Form
Mixture
Product Code
0134 0167

Regulatory Identifiers

CAS Number
N/A
UFI Code
0S41-JWHN-H206-4VNP

Identified Uses

Adhesives

Uses advised against

No additional information available

Manufacturers & Suppliers

DEUTZ AG logo

DEUTZ AG

distributor

Ottostr. 1, 51149 Köln-Porz (Eil) - Germany

+49 (0)221 822 0

http://www.deutz.com

H

Henkel AG & Co. KGaA

manufacturer

Henkelstraße 67, 40589 Düsseldorf - Germany

+49 (0)211 7970

D

DLAC Dienstleistungsagentur Chemie GmbH

Emergency Contacts

Giftinformationszentrum-Nord Zentrum Pharmakologie und Toxikologie der Universität Göttingen

+49 551 19240

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand
P102 Keep out of reach of children
P261 Avoid breathing vapours
P273 Avoid release to the environment
P280 Wear protective gloves
P302 + P352 IF ON SKIN: Wash with plenty of water
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention
P501 Dispose of contents/container to Disposal

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
3,3,5-trimethylcyclohexyl methacrylate EC: 231-927-0 7779-31-9 25 - 50% Yes
2,2'-ethylenedioxydiethyl dimethacrylate EC: 203-652-6 109-16-0 1 - 5% Yes
α,α-dimethylbenzyl hydroperoxide, cumene hydroperoxide EC: 201-254-7 80-15-9 1 - 3% Yes
maleic acid EC: 203-742-5 110-16-7 0.1 - 1% Yes
2'-phenylacetohydrazide EC: 204-055-3 114-83-0 0.1 - 1% Yes
1,4-naphthoquinone EC: 204-977-6 130-15-4 0.0025 - 0.025% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Assure fresh air breathing. If you feel unwell, seek medical advice.

Symptoms: May cause respiratory irritation. May cause shortness of breath, tightness of the chest, a sore throat and cough.

Skin contact

Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.

Symptoms: May cause an allergic skin reaction. Causes skin irritation. Redness.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Symptoms: Causes serious eye irritation. Conjunctivitis.

Ingestion

Rinse mouth. Drink plenty of water as a precaution. Do NOT induce vomiting. Get medical advice/attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide. Foam. dry extinguishing powder. Water spray.

Unsuitable media

Do not use a heavy water stream.

Instructions

Use water spray or fog for cooling exposed containers.

Firefighter Protection

Use a self-contained breathing apparatus and also a protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate unnecessary personnel.

Environmental

Prevent entry to sewers and public waters.

Cleanup methods

Take up mechanically (sweeping, shovelling) and collect in suitable container for disposal. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.

Materials: inert solids, such as clay or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Avoid breathing vapours. Avoid repeated or prolonged skin contact. Wear personal protective equipment.

Storage

Keep container tightly closed. Store in a cool, well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety procedures. When using do not eat, drink or smoke. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Green
Colour Intensity
---
Form
---
Odor
Characteristic
Odor Threshold
---
Ph
Not applicable
Melting Point
< -30 °C
Boiling Point
> 150 °C
Flash Point
> 100 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 0.13 mbar (20 °C) < 2.8 mbar (50 °C)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1.1 g/cm³ (20 °C)
Flammability
Non combustible.
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
Not applicable
Solubility
Water: easy Acetone: Soluble
Partition Coefficient
Not applicable
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
< 3 %
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
> 20.5 mm²/s (40 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under use and storage conditions as recommended in section 7.

Reactivity

Acids, strong bases, strong oxidants and reducing agents.

Hazardous reactions

Refer to section 10.1 on Reactivity.

Avoid

Stable under normal conditions of use.

Incompatible

Refer to section 10.1 on Reactivity.

Decomposition

Carbon oxides (CO, CO₂). Nitrogen oxides. Hydrocarbons.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.3. Bioaccumulative potential

| 2,2'-ethylenedioxydiethyl dimethacrylate (109-16-0) | | | Log Kow | 2.3 |

12.3. Bioaccumulative potential

| α,α-dimethylbenzyl hydroperoxide, cumene hydroperoxide (80-15-9) | | | Log Kow | 1.6, 25 °C |

12.4. Mobility in soil

No additional information available

12.1. Toxicity

Acute aquatic toxicity : Not classified Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects. 3,3,5-trimethylcyclohexyl methacrylate (7779-31-9)

Acute aquatic toxicity is not classified. Chronic aquatic toxicity is classified as toxic to aquatic life with long lasting effects.

12.1. Toxicity

| LC50 fish | 1.9 mg/l 96 h, Danio rerio | | --- | --- | | EC50 daphnia | 14.43 mg/l 48 h, Daphnia magna | | EC10 algae | 0.43 mg/l 72 h, Raphidocelis subcapitata |

12.1. Toxicity

| 2,2'-ethylenedioxydiethyl dimethacrylate (109-16-0) | | | --- | --- | | LC50 fish | 16.4 mg/l 96 h, Danio rerio | | EC50 algae | > 100 mg/l 72 h, Raphidocelis subcapitata | | NOEC daphnia | 32 mg/l 21 d, Daphnia magna | | NOEC algae | 18.6 mg/l 72 h, Raphidocelis subcapitata |

12.1. Toxicity

| α,α-dimethylbenzyl hydroperoxide, cumene hydroperoxide (80-15-9) | | | LC50 fishes | 3.9 mg/l 96 h, Oncorhynchus mykiss | | EC50 daphnia | 18.84 mg/l 48 h, Daphnia magna | | EC50 algae | 3.1 mg/l 72 h, Desmodesmus subspicatus | | NOEC algae | 1 mg/l 72 h, Desmodesmus subspicatus |

12.2. Persistence and degradability

| 3,3,5-trimethylcyclohexyl methacrylate (7779-31-9) | | | --- | --- | | Persistence and degradability | Not readily biodegradable. | | Biodegradation | 16.8 % 28 d |

Not readily biodegradable.

12.2. Persistence and degradability

2,2'-ethylenedioxydiethyl dimethacrylate (109-16-0) | | Persistence and degradability | Readily biodegradable. | Biodegradation | 85 % 28 d

12.2. Persistence and degradability

Not readily biodegradable. Biodegradation: 3 %, 28 d

Not readily biodegradable.

12.3. Bioaccumulative potential

12.3. Bioaccumulative potential

12.3. Bioaccumulative potential

| 3,3,5-trimethylcyclohexyl methacrylate (7779-31-9) | | | --- | --- | | Log Kow | 5.25, 20 °C |

12.5. Results of PBT and vPvB assessment

Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

The substance does not meet the criteria for PBT or vPvB.

12.6. Endocrine disrupting properties

Endocrine disruption for the environment : The mixture has no endocrine disrupting properties.

The mixture has no endocrine disrupting properties.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of this material and its container at hazardous or special waste collection point.

Disposal

Dispose in a safe manner in accordance with local/national regulations.

Waste Codes

08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (3,3,5-trimethylcyclohexyl methacrylate)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Loctite 270?

The signal word is warning.

What is the physical form of Loctite 270?

Loctite 270 is a liquid with green color. It has characteristic odor.

What is the solubility of Loctite 270?

Water: easy Acetone: Soluble

What is Loctite 270 used for?

Adhesives

What are the hazard statements for Loctite 270?

This substance has 5 hazard statements:

  • H315: Causes skin irritation
  • H317: May cause an allergic skin reaction
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation
  • H411: Toxic to aquatic life with long lasting effects

What is the melting point of Loctite 270?

The melting point is < -30 °C and the boiling point is > 150 °C.