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Safety Data Sheet EN

KRYLON® Industrial TOUGH COAT™ Acrylic Enamel

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
KRYLON® Industrial TOUGH COAT™ Acrylic Enamel
Product Form
Aerosol
Product Code
A01510007

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Paint or paint related material.

Manufacturers & Suppliers

K

Krylon Products Group

manufacturer

101 Prospect Avenue NW, Cleveland, OH 44115

(800) 247-3266

Emergency Contacts

Emergency Contact

(800) 424-9300

24 hours and 365 days per year

CHEMTREC Mexico

01-800-681-9531

24 hours and 365 days per year

Emergency Contact

(800) 424-9300

24 hours / 365 days a year

SETIQ

01-800-00-214-00

24 hours / 365 days a year

SETIQ

(52) 55-5559-1588

24 hours / 365 days a year

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1
Press. Gas
Eye Irrit. Cat. 2A
Skin Sens. Cat. 1
Carc. Cat. 2
Repr. Cat. 2
STOT SE Cat. 3
STOT SE Cat. 3
STOT RE Cat. 2
Asp. Tox. Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361d Suspected of damaging the unborn child.
H372 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P261 Do not breathe dust or mist.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves.
P281 Wear protective clothing.
P282 Wear eye or face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or physician.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention.
P312 Call a POISON CENTER or physician if you feel unwell.
P314 Get medical attention if you feel unwell.
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P363 Wash contaminated clothing before reuse.
P403 Store in a well-ventilated place.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Acetone 67-64-1 25 - 50% No
Propane 74-98-6 10 - 25% No
Butane 106-97-8 10 - 25% No
Lt. Aliphatic Hydrocarbon Solvent 64742-89-8 10% No
Isobutyl Acetate 110-19-0 5% No
Titanium Dioxide 13463-67-7 5% No
Toluene 108-88-3 3% No
Xylene, mixed isomers 1330-20-7 1% No
Hydrotreated Heavy Petroleum Naphtha 64742-48-9 0.3% No
Methyl Ethyl Ketoxime 96-29-7 0.3% No
Ethylbenzene 100-41-4 0.3% No

Occupational exposure limits, if available, are listed in Section 8.

Notes

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation, watering, redness.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Adverse symptoms may include the following: nausea or vomiting, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Immediate Medical Attention

Get medical attention immediately. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Materials: water, inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

Storage

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
---
State Under Standard Conditions
---
Appearance
---
Colour
---
Colour Intensity
---
Form
Spray
Odor
---
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
---
Flash Point
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
5.6 (butyl acetate = 1)
Vapor Pressure
101.3 kPa (760 mm Hg) [at 20°C]
Vapor Density
1.55 [Air = 1]
Relative Density
0.74
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
Upper: 12.8%
Lower Explosive Limit
Lower: 0.9%
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
Not applicable.
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C (104°F)): <0.205 cm²/s (<20.5 cSt)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame).

Incompatible

No specific data.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Product/ingredient name: Titanium Dioxide Toluene Acute LC50 >1000000 μg/l Marine water - Fish - Fundulus heteroclitus - 96 hours Acute EC50 12500 μg/l Fresh water - Algae - Pseudokirchneriella subcapitata - 72 hours Acute EC50 11600 μg/l Fresh water - Crustaceans - Gammarus pseudolimnaeus - Adult - 48 hours Acute EC50 6000 μg/l Fresh water - Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) - 48 hours Acute LC50 5500 μg/l Fresh water - Fish - Oncorhynchus kisutch - Fry - 96 hours

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

Toxicity

Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | Xylene, mixed isomers | Chronic NOEC 1000 μg/l Fresh water | Daphnia - Daphnia magna | 21 days | | | Acute LC50 8500 μg/l Marine water | Crustaceans - Palaemonetes pugio | 48 hours |

Toxicity

Product/ingredient name | Result | Species | Exposure Methyl Ethyl Ketoxime Ethylbenzene | Acute LC50 13400 μg/l Fresh water | Fish - Pimephales promelas | 96 hours | Acute LC50 843000 μg/l Fresh water | Fish - Pimephales promelas | 96 hours | Acute EC50 4600 μg/l Fresh water | Algae - Pseudokirchneriella subcapitata | 72 hours | Acute EC50 3600 μg/l Fresh water | Algae - Pseudokirchneriella subcapitata | 96 hours | Acute EC50 6.53 mg/l Marine water | Crustaceans - Artemia sp. - Nauplii | 48 hours | Acute EC50 2.93 mg/l Fresh water | Daphnia - Daphnia magna - Neonate | 48 hours | Acute LC50 4200 μg/l Fresh water | Fish - Oncorhynchus mykiss | 96 hours

Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Acetone | - | - | Readily |

Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Toluene | - | - | Readily |

Persistence and degradability

Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability --- | --- | --- | --- Xylene, mixed isomers | - | - | Readily

Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Hydrotreated Heavy | - | - | Readily |

Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Petroleum Naphtha | - | - | Readily |

Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Ethylbenzene | - | - | Readily |

Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Lt. Aliphatic Hydrocarbon Solvent | - | 10 to 2500 | high |

Bioaccumulative potential

Bioaccumulative potential | Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Toluene | - | 90 | low |

Bioaccumulative potential

Bioaccumulative potential | Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Xylene, mixed isomers | - | 8.1 to 25.9 | low |

Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Hydrotreated Heavy | - | 10 to 2500 | high |

Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Petroleum Naphtha | - | | |

Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Methyl Ethyl Ketoxime | - | 2.5 to 5.8 | low |

Mobility in soil

Soil/water partition coefficient (Koc) : Not available.

Other adverse effects

No known significant effects or critical hazards.

Toxicity

Product/ingredient name: Acetone Acute EC50 7200000 μg/l Fresh water | Algae - Selenastrum sp. | 96 hours Acute LC50 6000000 μg/l Fresh water | Crustaceans - Gammarus pulex | 48 hours Acute LC50 6900 mg/l Fresh water | Daphnia - Daphnia magna | 48 hours Acute LC50 5600 ppm Fresh water | Fish - Poecilia reticulata | 96 hours Chronic NOEC 4.95 mg/l Marine water | Algae - Ulva pertusa | 96 hours Chronic NOEC 0.016 ml/L Fresh water | Crustaceans - Daphniidae | 21 days Chronic NOEC 0.1 ml/L Fresh water | Daphnia - Daphnia magna - Neonate | 21 days Chronic NOEC 5 μg/l Marine water | Fish - Gasterosteus aculeatus - Larvae | 42 days

Toxicity

Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | Lt. Aliphatic Hydrocarbon Solvent | Acute LC50 >100000 ppm Fresh water | Fish - Oncorhynchus mykiss | 96 hours |
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1950
Shipping Name
AEROSOLS
Transport Class
2.1
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for KRYLON® Industrial TOUGH COAT™ Acrylic Enamel?

The signal word is danger.

What is the physical form of KRYLON® Industrial TOUGH COAT™ Acrylic Enamel?

KRYLON® Industrial TOUGH COAT™ Acrylic Enamel is a liquid .

What is KRYLON® Industrial TOUGH COAT™ Acrylic Enamel used for?

Paint or paint related material.

What are the hazard statements for KRYLON® Industrial TOUGH COAT™ Acrylic Enamel?

This substance has 10 hazard statements:

  • H222: Extremely flammable aerosol.
  • H280: Contains gas under pressure; may explode if heated.
  • H304: May be fatal if swallowed and enters airways.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.
  • H361d: Suspected of damaging the unborn child.
  • H372: May cause damage to organs through prolonged or repeated exposure.