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Safety Data Sheet EN

3-Methyl-1-phenyl-2-pyrazolin-5-one

CAS 89-25-8
EC 201-891-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
3-Methyl-1-phenyl-2-pyrazolin-5-one
Product Code
127460000; 127460050; 127461000; 127465000
Chemical Name
3-Methyl-1-phenyl-2-pyrazolin-5-one
Synonyms
2,4-Dihydro-5-methyl-2-phenyl-3H-pyrazol; 3-Methyl-1-phenyl-5-pyrazolone; 3-Methyl-1-phenyl-4,5-dihydro-1H-pyrazol-5-one; Norphenazone

Regulatory Identifiers

CAS Number
89-25-8 Check regulations →
EC Number
201-891-0 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

national supplier

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

T

Thermo Fisher Scientific

national supplier

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed

Precautionary Statements

P264 Wash face, hands and any exposed skin thoroughly after handling
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P312 Call a POISON CENTER or doctor if you feel unwell

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
3-Methyl-1-phenyl-2-pyrazolin-5-one EC: 201-891-0 89-25-8 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Materials: suitable containers

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Nitrile rubber, Neoprene, Natural rubber, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Particle filtering: EN149:2001 When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Powder Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Light yellow
Colour
---
Colour Intensity
---
Form
---
Odor
Odorless
Odor Threshold
No data available
Ph
No information available
Melting Point
127 - 131 °C / 260.6 - 267.8 °F
Boiling Point
287 °C / 548.6 °F @ 265 mmHg
Flash Point
No information available Method - No information available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable - Solid
Vapor Pressure
No data available
Vapor Density
Not applicable
Relative Density
---
Bulk Density
No data available
Density
No data available
Flammability
No information available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
1.71
Solubility In Water
3 g/l water (20°C)
Solubility In Fat
---
Molecular Weight
174.2
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not applicable
Kinematic Viscosity
Not applicable
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous Polymerization No information available.

Incompatible

Strong oxidizing agents.

Decomposition

Nitrogen oxides (NOx). Carbon monoxide (CO). Carbon dioxide (CO2)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecotoxicity effects

12.2. Persistence and degradability

Persistence Soluble in water, Persistence is unlikely, based on information available.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely | Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- |

12.3. Bioaccumulative potential

| Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- | | 3-Methyl-1-phenyl-2-pyrazolin-5-one | 1.71 | No data available |

12.4. Mobility in soil

The product is water soluble, and may spread in water systems. Will likely be mobile in the environment due to its water solubility. Highly mobile in soils

The product is water soluble and highly mobile in soils, with the potential to spread in water systems.

12.5. Results of PBT and vPvB assessment

No data available for assessment.

No data available for assessment.

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

This product does not contain any known or suspected endocrine disruptors

12.7. Other adverse effects

Persistent Organic Pollutant Ozone Depletion Potential This product does not contain any known or suspected substance This product does not contain any known or suspected substance

This product does not contain any known or suspected substance regarding Persistent Organic Pollutant and Ozone Depletion Potential.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Disposal

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 3-Methyl-1-phenyl-2-pyrazolin-5-one known by?

3-Methyl-1-phenyl-2-pyrazolin-5-one is also known as: 2,4-Dihydro-5-methyl-2-phenyl-3H-pyrazol; 3-Methyl-1-phenyl-5-pyrazolone; 3-Methyl-1-phenyl-4,5-dihydro-1H-pyrazol-5-one; Norphenazone

What is the hazard signal word for 3-Methyl-1-phenyl-2-pyrazolin-5-one?

The signal word is warning.

What is the physical form of 3-Methyl-1-phenyl-2-pyrazolin-5-one?

3-Methyl-1-phenyl-2-pyrazolin-5-one is a powder solid appearing as light yellow . It has odorless odor.

What is 3-Methyl-1-phenyl-2-pyrazolin-5-one used for?

Laboratory chemicals.

What are the hazard statements for 3-Methyl-1-phenyl-2-pyrazolin-5-one?

This substance has 1 hazard statement:

  • H302: Harmful if swallowed

What is the melting point of 3-Methyl-1-phenyl-2-pyrazolin-5-one?

The melting point is 127 - 131 °C / 260.6 - 267.8 °F and the boiling point is 287 °C / 548.6 °F @ 265 mmHg.