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Safety Data Sheet EN

Tris-(2-carboxyethyl)-phosphine hydrochloride

CAS 51805-45-9
EC 629-759-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Tris-(2-carboxyethyl)-phosphine hydrochloride
Product Code
HN95
Chemical Name
Tris-(2-carboxyethyl)-phosphine hydrochloride

Regulatory Identifiers

CAS Number
51805-45-9 Check regulations →
EC Number
629-759-1 Check regulations →

Identified Uses

Laboratory chemical Laboratory and analytical use

Uses advised against

Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin. Do not use for private purposes (household). Food, drink and animal feedingstuffs.

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe, Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

National Poisons Information Service City Hospital

844 892 0111

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H314 Causes severe skin burns and eye damage

Precautionary Statements

P280 Wear protective gloves/eye protection
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER/doctor/...

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Tris-(2-carboxyethyl)-phosphine hydrochloride EC: 629-759-1 51805-45-9 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Skin contact

After contact with skin, wash immediately with plenty of water.

Symptoms: Corrosion

Eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye.

Symptoms: Risk of blindness, Risk of serious damage to eyes

Ingestion

Rinse mouth immediately and drink plenty of water. Call a physician immediately.

Symptoms: If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects).

Immediate Medical Attention

Immediate medical treatment required because corrosive injuries that are not treated are hard to cure. Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

co-ordinate firefighting measures to the fire surroundings! water, foam, dry extinguishing powder, ABC-powder

Unsuitable media

water jet

Specific hazards

Combustible.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

Wear self-contained breathing apparatus. Wear full chemical protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe dust.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Take up mechanically.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle and open container with care. Avoid dust formation. Clear contaminated areas thoroughly.

Storage

Store in a dry place. Keep in a cool place.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.

Fire prevention

Removal of dust deposits.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 °C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. NBR (Nitrile rubber), >0,11 mm, >480 minutes (permeation: level 6)

Eyes

Use safety goggle with side protection. Wear face protection.

Respiratory

Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P1 (filters at least 80 % of airborne particles, colour code: White).

Skin/Body

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
white
Colour Intensity
---
Form
powder, crystalline
Odor
odourless
Odor Threshold
---
Ph
not applicable
Melting Point
176 – 178 °C
Boiling Point
not determined
Flash Point
not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
not determined
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
not determined
Flammability
this material is combustible, but will not ignite readily
Upper Explosive Limit
not determined
Lower Explosive Limit
not determined
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
not relevant
Solubility
---
Partition Coefficient
this information is not available
Solubility In Water
(soluble)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
not relevant
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

The product in the delivered form is not dust explosion capable; the enrichment of fine dust however leads to the danger of dust explosion.

Hazardous reactions

Violent reaction with: strong oxidiser, Bases

Avoid

There are no specific conditions known which have to be avoided.

Incompatible

There is no additional information.

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Shall not be classified as hazardous to the aquatic environment.

12.2 Persistence and degradability

Theoretical Oxygen Demand: 1,228 mg/mg Theoretical Carbon Dioxide: 1,382 mg/mg

12.3 Bioaccumulative potential

Data are not available.

Data are not available.

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

Data are not available.

Data are not available.

12.6 Endocrine disrupting properties

Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

12.7 Other adverse effects

Data are not available.

Data are not available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal

This material and its container must be disposed of as hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3261
Shipping Name
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Transport Class
8
Packing Group
II
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Tris-(2-carboxyethyl)-phosphine hydrochloride?

The signal word is danger.

What is the physical form of Tris-(2-carboxyethyl)-phosphine hydrochloride?

Tris-(2-carboxyethyl)-phosphine hydrochloride is a solid with white color. It has odourless odor.

What is Tris-(2-carboxyethyl)-phosphine hydrochloride used for?

Laboratory chemical Laboratory and analytical use

What are the hazard statements for Tris-(2-carboxyethyl)-phosphine hydrochloride?

This substance has 1 hazard statement:

  • H314: Causes severe skin burns and eye damage

What is the melting point of Tris-(2-carboxyethyl)-phosphine hydrochloride?

The melting point is 176 – 178 °C and the boiling point is not determined.