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Safety Data Sheet EN

COOLELF SUPRA

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
COOLELF SUPRA

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Antifreezes Coolants

Manufacturers & Suppliers

T

TotalEnergies Lubrifiants

manufacturer

562 Avenue du Parc de L'ile, 92029 Nanterre Cedex, FRANCE

+33 (0)1 41 35 40 00

T

TotalEnergies Marketing Services

distributor

Direction Afrique, 24 cours Michelet, 92800 PUTEAUX, FRANCE

+33 (0)1 41 35 40 00

Emergency Contacts

Emergency Contact

+44 1235 239671

Emergency Contact

+44 1235 239670

PT, ES

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 5
STOT RE Cat. 2

GHS Pictograms

GHS08 - Serious health hazard

GHS08

Hazard Statements

H303 May be harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure. (kidneys)

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P261 Do not breathe gas, vapor or spray.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
ethylene glycol 107-21-1 25 - 50% Yes

Product with ethylene-glycol base. This product contains an approved repellant (bitter), for the purpose of avoiding the risk of accidental ingestion.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if feeling unwell. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: No known significant effects or critical hazards.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell.

Symptoms: No known significant effects or critical hazards.

Ingestion

Take victim immediately to hospital SYMPTOMS MAY NOT APPEAR IMMEDIATELY. Wash out mouth with water. Remove dentures if any. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: May be harmful if swallowed. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. nausea or vomiting abdominal cramps and pain convulsive seizures Can cause central nervous system (CNS) depression.

Immediate Medical Attention

If unconscious, place in recovery position and get medical attention immediately. Take victim immediately to hospital

Medical Treatment

Rinse mouth. Induce vomiting, but only if victim is fully conscious. Ingestion, depending on the dose, can cause i.a. abnormal behaviour, unconsciousness, convulsions, respiratory paralysis, pulmonary oedemas, as well as damages to liver and kidneys and can lead, in the worst case, to death. A quick treatment of an ethylene-glycol intoxication, when necessary with haemodialysis, may reduce the toxical effects. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).

Unsuitable media

Do not use water jet.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage.

Materials: water, inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
limpid
Colour
Yellow.
Colour Intensity
---
Form
---
Odor
Mild.
Odor Threshold
Not available.
Ph
8 to 8.4
Melting Point
-25.2°C (-13.4°F) [EN ISO 3016]
Boiling Point
109°C (228.2°F) [EN ISO 3405]
Flash Point
Open cup: Not applicable.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not applicable. [50°C]
Vapor Density
Not available.
Relative Density
1.058 [ISO EN 3675]
Bulk Density
---
Density
1.058 g/cm³ [20°C] [ISO EN 3675]
Flammability
Not applicable.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Easily soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (see Section 7).

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Incompatible

Strong oxidizing agents, strong acids, nitrates, peroxides, chlorates

Decomposition

carbon monoxide, carbon dioxide, Ketone., Aldehyde.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

| Product/substance | Result | Species | Exposure | Test | | --- | --- | --- | --- | --- | | ethylene glycol | Acute EC10 >1995 mg/l | Micro-organism - Activated sludge | 30 minutes | ISO 8192 | | | Acute EC50 6500 to 13000 mg/l | Algae - Selenastrum capricornutum | 96 hours | EPA | | | Acute EC50 13900 to 57600 mg/l Fresh water | Daphnia | 48 hours | OECD 202 | | | Acute LC50 49000 mg/l Fresh water | Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) | 96 hours | ASTM | | | Acute LC50 72860 mg/l | Fish - Pimephales promelas | 96 hours | OECD 203 | | | Chronic EC10 100 mg/l | Algae - Selenastrum capricornutum | - | - | | | Chronic NOEC 8590 mg/l | Crustaceans - Ceriodaphnia dubia | 7 days | EPA 600/4-89/001 | | | Chronic NOEC 15380 mg/l | Fish - Pimephales promelas | 7 days | EPA 600/4-89/001 |

Persistence and degradability

| Product/substance | Test | Result | | Dose | Inoculum | | --- | --- | --- | --- | --- | --- | | ethylene glycol | OECD 301A | 90 % - Readily - 10 days | | - | Activated sludge | | | | | | | | | Product/substance | Aquatic half-life | | Photolysis | | Biodegradability | | ethylene glycol | - | | - | | Readily |

Bioaccumulative potential

| Product/substance | LogK_{ow} | BCF | Potential | | --- | --- | --- | --- | | ethylene glycol | -1.36 | - | Low |

Mobility in soil

**Soil/water partition coefficient (K_{oc})** : Not available. **Mobility in soil** : Given its physical and chemical characteristics, the product is generally mobile in the ground the product may evaporate Soluble in water

Results of PBT and vPvB assessment

Not available.

Endocrine disrupting properties

Not available.

Other adverse effects

Other adverse effects : No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The information stated in this section relates solely to the conformity of the chemical product with the countries Inventories. The information used to confirm the inventory status of this product may be based on additional data to the chemical composition shown in Section 3. Other regulations may apply for importation or marketing authorizations.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for COOLELF SUPRA?

The signal word is warning.

What is the physical form of COOLELF SUPRA?

COOLELF SUPRA is a liquid. appearing as limpid with yellow. color. It has mild. odor.

What is COOLELF SUPRA used for?

Antifreezes Coolants

What are the hazard statements for COOLELF SUPRA?

This substance has 2 hazard statements:

  • H303: May be harmful if swallowed.
  • H373: May cause damage to organs through prolonged or repeated exposure. (kidneys)

What is the melting point of COOLELF SUPRA?

The melting point is -25.2°C (-13.4°F) [EN ISO 3016] and the boiling point is 109°C (228.2°F) [EN ISO 3405].