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Safety Data Sheet EN

THINNER 21-06

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
THINNER 21-06
Product Form
Liquid
Product Code
00334837
Synonyms
65 THINNER / HT#11

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Consumer applications, Professional applications, Used by spraying. Thinner.

Uses advised against

Not applicable.

Manufacturers & Suppliers

P

PPG Industries, Inc.

manufacturer

One PPG Place Pittsburgh, PA 15272

888-977-4762

Emergency Contacts

Emergency Contact

(412) 434-4515

Emergency Contact

(514) 645-1320

SETIQ

800-00-214-00

SETIQ

(55) 5559-1588

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Carc. Cat. 2
Repr. Cat. 2
STOT SE Cat. 3
STOT RE Cat. 2
Asp. Tox. Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 May cause damage to organs through prolonged or repeated exposure. (hearing organs)

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P235 Keep cool.
P241 Use explosion-proof electrical, ventilating or lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Do not breathe vapor.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, protective clothing and eye or face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice or attention.
P312 Call a POISON CENTER or doctor if you feel unwell.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice or attention.
P337 + P313 If eye irritation persists: Get medical advice or attention.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
xylene 1330-20-7 75 - 85% Yes
ethylbenzene 100-41-4 10 - 17% Yes
toluene 108-88-3 1% Yes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Harmful if inhaled. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Symptoms: Causes skin irritation. Defatting to the skin. Adverse symptoms may include the following: irritation, redness, dryness, cracking, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Eye contact

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Symptoms: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation, watering, redness.

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: May be fatal if swallowed and enters airways. Adverse symptoms may include the following: nausea or vomiting, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Immediate Medical Attention

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. If swallowed, seek medical advice immediately and show this container or label. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Materials: inert dry material, sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Not available.
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
Not available.
Ph
Not applicable.
Melting Point
Not available.
Boiling Point
>37.78°C (>100°F)
Flash Point
Closed cup: 27.22°C (81°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
0.63 (butyl acetate = 1)
Vapor Pressure
0.85 kPa (6.4 mm Hg)
Vapor Density
---
Relative Density
0.87
Bulk Density
---
Density
7.26 lbs/gal
Flammability
Not available.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Not soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
<14 mm²/s (<14 cSt)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

When exposed to high temperatures may produce hazardous decomposition products. Refer to protective measures listed in sections 7 and 8.

Incompatible

Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids.

Decomposition

Depending on conditions, decomposition products may include the following materials: carbon oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Toxicity | Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | ethylbenzene | Acute EC50 1.8 mg/l Fresh water | Daphnia | 48 hours | | | Chronic NOEC 1 mg/l Fresh water | Daphnia - Ceriodaphnia dubia | - |

12.1 Toxicity

Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | toluene | EC50 3.78 mg/l | Daphnia | 48 hours | | | LC50 5.5 mg/l | Fish | 96 hours |

Persistence and degradability

Product/ingredient name | Test | Result | Dose | Inoculum | | --- | --- | --- | --- | --- |

12.1 Toxicity

12.2 Persistence and degradability

Product/ingredient name: ethylbenzene; Test: -; Result: 79 % - Readily - 10 days; Dose: -; Inoculum: -

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.2 Persistence and degradability

Readily

12.2 Persistence and degradability

ethylbenzene: Readily

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

Product/ingredient name: xylene, LogP_ow: 3.12, BCF: 7.4 to 18.5, Potential: Low

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

LogP_ow: 3.6, BCF: 79.43, Potential: Low

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

Product/ingredient name: toluene, LogP_ow: 2.73, BCF: 90, Potential: Low

12.4 Mobility in soil

Soil/Water partition coefficient: Not available.

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal

The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1307
Shipping Name
XYLENES
Transport Class
3
Packing Group
III
IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is THINNER 21-06 known by?

THINNER 21-06 is also known as: 65 THINNER / HT#11

What is the hazard signal word for THINNER 21-06?

The signal word is danger.

What is the physical form of THINNER 21-06?

THINNER 21-06 is a liquid. with not available. color. It has characteristic. odor.

What is THINNER 21-06 used for?

Consumer applications, Professional applications, Used by spraying. Thinner.

What are the hazard statements for THINNER 21-06?

This substance has 9 hazard statements:

  • H226: Flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.
  • H361: Suspected of damaging fertility or the unborn child.
  • H372: May cause damage to organs through prolonged or repeated exposure. (hearing organs)

What is the melting point of THINNER 21-06?

The melting point is Not available. and the boiling point is >37.78°C (>100°F).