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Safety Data Sheet EN

Trifluoroacetic acid

CAS 76-05-1
EC 200-929-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Trifluoroacetic acid
Product Code
44630
Chemical Name
Trifluoroacetic acid

Regulatory Identifiers

CAS Number
76-05-1 Check regulations →
EC Number
200-929-3 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar logo

Alfa Aesar

manufacturer

Thermo Fisher Scientific Chemicals, Inc. 30 Bond Street Ward Hill, MA 01835-8099

800-343-0660

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

Monday-Friday, 8am-7pm EST

Carechem 24

(866) 928-0789

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1A H314
Acute Tox. Cat. 4 H332

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.

Precautionary Statements

P260 Do not breathe dusts or mists.
P301 + P330 + P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Trifluoroacetic acid

Chemical Name CAS Number Concentration Hazardous
Trifluoroacetic acid EC: 200-929-3 76-05-1 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm.

Skin contact

Immediately wash with water and soap and rinse thoroughly.

Eye contact

Rinse opened eye for several minutes under running water.

Immediate Medical Attention

Seek immediate medical advice. Then consult a doctor. Seek medical treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Specific hazards

If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide, Hydrogen fluoride (HF)

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation.

Environmental

Do not allow product to reach sewage system or any water course.

Cleanup methods

Absorb with liquid-binding material

Materials: liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle under dry protective gas. Keep container tightly sealed.

Storage

Store in cool, dry place in tightly closed containers. Store under dry inert gas. Store in cool, dry conditions in well sealed containers.

Fire prevention

No information known.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Material of gloves: Chloroprene rubber, CR. Penetration time of glove material (in minutes): >480. Glove thickness: 0.6 mm

Eyes

Tightly sealed goggles. Full face protection. Safety glasses with side shields / NIOSH (US) or EN 166(EU)

Respiratory

Use suitable respirator when high concentrations are present. Recommended filter device for short term use: Use a respirator with multi-purpose combination (US) or type ABEK (EN 14387) as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards such as NIOSH (USA) or CEN (EU).

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
---
Colour Intensity
---
Form
Liquid
Odor
Pungent
Odor Threshold
Not determined.
Ph
Not determined.
Melting Point
-15 °C (5 °F)
Boiling Point
72-73 °C (162-163 °F)
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined.
Vapor Pressure
11 hPa (8 mm Hg) (at 20 °C (68 °F))
Vapor Density
Not determined.
Relative Density
Not determined.
Bulk Density
---
Density
1.48 g/cm³ (12.351 lbs/gal) (at 20 °C (68 °F))
Flammability
Not determined.
Upper Explosive Limit
Not determined
Lower Explosive Limit
Not determined
Explosive Limits
---
Auto Ignition Temperature
Not determined.
Decomposition Temperature
Not determined.
Solubility
---
Partition Coefficient
Not determined.
Solubility In Water
Fully miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not determined.
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No information known.

Hazardous reactions

Reacts with strong oxidizing agents.

Avoid

No further relevant information available.

Incompatible

Bases, Oxidizing agents, Water/moisture

Decomposition

Carbon monoxide and carbon dioxide, Hydrogen fluoride

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Aquatic toxicity: No further relevant information available.

No further relevant information available.

Persistence and degradability

No further relevant information available.

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

No further relevant information available.

Mobility in soil

No further relevant information available.

No further relevant information available.

Results of PBT and vPvB assessment

PBT: Not applicable. vPvB: Not applicable.

The substance is not considered to be PBT or vPvB.

Endocrine disrupting properties

Other adverse effects

No further relevant information available.

No further relevant information available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2699
Shipping Name
Trifluoroacetic acid
Transport Class
8
Packing Group
I
ADR

Warning: Corrosive substances

IMDG

Warning: Corrosive substances; Segregation groups: Acids; Stowage Category: B; Stowage Code: SW1 Protected from sources of heat. SW2 Clear of living quarters.; Handling Code: H2 Keep as cool as reasonably practicable

IATA

Warning: Corrosive substances

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

For use only by technically qualified individuals.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Trifluoroacetic acid?

The signal word is danger.

What is the physical form of Trifluoroacetic acid?

Trifluoroacetic acid is a liquid . It has pungent odor.

What is Trifluoroacetic acid used for?

SU24 Scientific research and development

What are the hazard statements for Trifluoroacetic acid?

This substance has 2 hazard statements:

  • H314: Causes severe skin burns and eye damage.
  • H332: Harmful if inhaled.

What is the melting point of Trifluoroacetic acid?

The melting point is -15 °C (5 °F) and the boiling point is 72-73 °C (162-163 °F).