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Safety Data Sheet EN

Morpholine

CAS 110-91-8
EC 203-815-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Morpholine
Product Code
A10355
Chemical Name
morpholine
Synonyms
Tetrahydro-1,4-oxazine

Regulatory Identifiers

CAS Number
110-91-8 Check regulations →
EC Number
203-815-1 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar Thermo Fisher Scientific Chemicals, Inc. logo

Alfa Aesar Thermo Fisher Scientific Chemicals, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

800-343-0660

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

During normal business hours (Monday-Friday, 8am-7pm EST)

Carechem 24

(866) 928-0789

After normal business hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Skin Corr. Cat. 1B H314
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterization: Substances

Chemical Name CAS Number Concentration Hazardous
morpholine EC: 203-815-1 110-91-8 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Symptoms: Harmful if inhaled.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Symptoms: Causes severe skin burns.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Symptoms: Harmful in contact with skin.

Ingestion

Seek medical treatment.

Symptoms: Harmful if swallowed.

Immediate Medical Attention

No further relevant information available.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Penetration time of glove material (in minutes) Not determined

Eyes

Tightly sealed goggles. Full face protection

Respiratory

Use suitable respirator when high concentrations are present. Recommended filter device for short term use: Use a respirator with multi-purpose combination (US) or type ABEK (EN 14387) as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards such as NIOSH (USA) or CEN (EU).

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Ph
Not determined.
Colour
---
Relative Evaporation Rate
---
Voc Content
---
Boiling Point
129 ℃ (264 ºF)
Auto Ignition Temperature
320 °C (608 °F)
Solubility
1 g/l Fully miscible
Molecular Weight
---
Solubility In Water
1 g/l Fully miscible
Solubility In Fat
---
Odor
Amine-like
Appearance
---
Softening Point
---
Form
Liquid
Lower Explosive Limit
1.8 Vol %
Evaporation Rate
Not determined.
Kinematic Viscosity
Not determined.
Bulk Density
---
Relative Density
Not determined.
Odor Threshold
Not determined.
Cloud Point
---
Vapor Pressure
10 hPa (8 mm Hg)
Properties Status
---
Solidification Point
---
Upper Explosive Limit
15.2 Vol %
Freezing Point
---
Melting Point
-5 °C (23 °F)
Partition Coefficient
Not determined.
Flammability
Not determined.
Vapor Density
Not determined.
Crystallisation Point
---
State Under Standard Conditions
---
Colour Intensity
---
Metal Corrosion
---
Explosive Limits
---
Physical State Data
liquid
Decomposition Temperature
Not determined.
Dynamic Viscosity
Not determined.
Physical State
Liquid
Flash Point
35 ℃ (95 °F)
Density
1.007 g/cm3 (8.403 lbs/gal)
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2054
Shipping Name
Morpholine
Transport Class
8
Packing Group
I
IMDG

F-E,S-Č

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Morpholine known by?

Morpholine is also known as: Tetrahydro-1,4-oxazine

What is the hazard signal word for Morpholine?

The signal word is danger.

What is the physical form of Morpholine?

Morpholine is a liquid . It has amine-like odor.

What is the solubility of Morpholine?

1 g/l Fully miscible

What is Morpholine used for?

SU24 Scientific research and development

What are the hazard statements for Morpholine?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H312: Harmful in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H332: Harmful if inhaled.

What is the melting point of Morpholine?

The melting point is -5 °C (23 °F) and the boiling point is 129 ℃ (264 ºF).

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