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Safety Data Sheet EN

Phosphine

CAS 7803-51-2
EC 232-260-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phosphine
Product Code
295647
Chemical Name
phosphine 015-181-00-1

Regulatory Identifiers

CAS Number
7803-51-2 Check regulations →
EC Number
232-260-8 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Gas Cat. 1 H220
Gases under pressure H280
Acute Tox. Cat. 1 H330
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS09 - Environmental hazard

GHS09

Hazard Statements

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H400 Very toxic to aquatic life.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 Wear respiratory protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P363 Wash contaminated clothing before reuse.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Phosphine

Chemical Name CAS Number Concentration Hazardous
phosphine 015-181-00-1 EC: 232-260-8 7803-51-2 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Continue rinsing eyes during transport to hospital. Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Splash contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 120 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Dynamic Viscosity
---
Solidification Point
---
Ph
No data available
Explosive Limits
---
Bulk Density
---
Molecular Weight
---
Physical State Data
gas
Solubility In Fat
---
Softening Point
---
Crystallisation Point
---
Vapor Density
1.17 - (Air = 1.0)
Odor
No data available
Physical State
gaseous
Relative Evaporation Rate
---
Properties Status
---
Density
---
Odor Threshold
No data available
Form
---
Voc Content
---
Colour Intensity
---
Kinematic Viscosity
---
Partition Coefficient
No data available
Metal Corrosion
---
Auto Ignition Temperature
No data available
Melting Point
No data available
Evaporation Rate
No data available
Solubility In Water
No data available
Freezing Point
No data available
Appearance
Form: gaseous
Vapor Pressure
No data available
Relative Density
No data available
Flash Point
No data available
Decomposition Temperature
No data available
State Under Standard Conditions
---
Flammability
No data available
Boiling Point
-87.5 °℃ (-125.5 ºF)
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Solubility
No data available
Colour
---
Cloud Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2199
Shipping Name
Phosphine
Transport Class
2.3
IMDG

F-D, S-U

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Phosphine?

The signal word is danger.

What is the physical form of Phosphine?

Phosphine is a gaseous appearing as form: gaseous . It has no data available odor.

What is the solubility of Phosphine?

No data available

What is Phosphine used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Phosphine?

This substance has 6 hazard statements:

  • H220: Extremely flammable gas.
  • H280: Contains gas under pressure; may explode if heated.
  • H314: Causes severe skin burns and eye damage.
  • H318: Causes serious eye damage.
  • H330: Fatal if inhaled.
  • H400: Very toxic to aquatic life.

What is the melting point of Phosphine?

The melting point is No data available and the boiling point is -87.5 °℃ (-125.5 ºF).

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