Chemical Product Identification & Regulatory Data
Official chemical identifiers, CAS numbers, and regulatory compliance information
Basic Product Information
Regulatory Identifiers
Chemical Abstracts Service registry number - unique identifier for chemical substances
Uses Information
Overview
4,4'-Methylenebis(phenyl isocyanate) is a crystalline substance commonly used su24 scientific research and development.
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GHS Hazard Classification & Safety Warnings
Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications
Classification Status
Signal Word
Hazard Classifications
GHS Hazard Pictograms & Safety Symbols
GHS06
GHS07
GHS08
GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions
Hazard Statements
- H330: Fatal if inhaled.
- H315: Causes skin irritation.
- H319: Causes serious eye irritation.
- H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
- H317: May cause an allergic skin reaction.
- H351: Suspected of causing cancer.
- H335: May cause respiratory irritation.
- H373: May cause damage to the lung, the blood and the immune system through prolonged or repeated exposure. Route of exposure: Inhalation, Dermal.
Precautionary Statements
- P260: Do not breathe dust/fume/gas/mist/vapors/spray.
- P280: Wear protective gloves / protective clothing.
- P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P310: Immediately call a POISON CENTER/doctor.
Chemical Manufacturers & Supply Chain
Authorized suppliers, manufacturers, and distribution network information
Alfa Aesar Thermo Fisher Scientific Chemicals, Inc.
manufacturer
24/7 Emergency Response & Poison Control
Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies
Emergency Contact
800-343-0660
Monday-Friday, 8am-7pm EST
After normal business hours, call Carechem
Chemical Composition & Hazardous Ingredients
Detailed component analysis, concentration ranges, and hazardous substance identification
Product Type
substanceChemical Components & Hazardous Substances
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| N/A | 101-68-8 | Not specified | ✓ Non-hazardous |
Emergency First Aid Measures
Critical first aid procedures for chemical exposure incidents and medical emergencies
🫁 Inhalation Exposure
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.
Symptoms:
Fatal if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
🖐️ Skin Contact
Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.
Symptoms:
Causes skin irritation.
👁️ Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Symptoms:
Causes serious eye irritation.
🍽️ Ingestion/Swallowing
Seek medical treatment.
Fire Fighting Measures & Emergency Response
Fire suppression methods, extinguishing media, and firefighting safety procedures
✅ Suitable Extinguishing Media
Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
⚠️ Specific Fire Hazards
If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide, Nitrogen oxides (NOx)
🛡️ Firefighter Protection Equipment
Wear self-contained respirator. Wear fully protective impervious suit.
Accidental Release Measures & Spill Response
Emergency spill cleanup procedures, containment methods, and environmental protection
🚨 Emergency Procedures
Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation.
🌍 Environmental Precautions
Do not allow material to be released to the environment without proper governmental permits.
🧹 Cleanup Methods
Dispose of contaminated material as waste according to section 13.
Related Chemical Substances & Alternative Products
Similar chemicals with comparable safety profiles and industrial applications
Technical Specifications & Material Properties
Physical state, chemical properties, melting point, boiling point, and material characteristics
Safe Handling & Storage Procedures
Industrial handling precautions, storage conditions, and workplace safety requirements
⚠️ Handling Precautions
• Keep container tightly sealed.
• Ensure good ventilation at the workplace.
• Open and handle container with care.
🏪 Storage Conditions
• Store in freezer (-20 ℃).
• Protect from heat.
• Store away from oxidizing agents.
• Keep container tightly sealed.
🔥 Fire Prevention Measures
No information known.
Exposure Controls & Personal Protective Equipment (PPE)
Occupational exposure limits, engineering controls, and required safety equipment
🏭 Engineering Controls
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
🧤 Hand Protection
Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Penetration time of glove material (in minutes) Not determined
👁️ Eye Protection
Safety glasses with side shields / NIOSH (US) or EN 166(EU)
😷 Respiratory Protection
Use self-contained respiratory protective device in emergency situations. Recommended filter device for short term use: Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. 'Only use equipment tested and approved under appropriate government standards.
🦺 Skin/Body Protection
Protective work clothing.
Chemical Stability & Reactivity Data
Chemical stability, hazardous reactions, and incompatible materials information
✅ Chemical Stability
Stable under recommended storage conditions.
⚗️ Reactivity
No information known.
⚠️ Hazardous Reactions
Reacts with strong oxidizing agents
🚫 Conditions to Avoid
No further relevant information available.
🧪 Incompatible Materials
Oxidizing agents, Heat
💨 Hazardous Decomposition Products
Carbon monoxide and carbon dioxide, Nitrogen oxides
Ecological Information & Environmental Impact
Environmental toxicity, biodegradation, bioaccumulation, and ecological effects data
🌱 Toxicity
🌱 Persistence and degradability
🌱 Bioaccumulative potential
🌱 Mobility in soil
🌱 Results of PBT and vPvB assessment
🌱 Endocrine disrupting properties
🌱 Other adverse effects
Waste Disposal & Treatment Methods
Waste disposal procedures, treatment methods, and regulatory compliance requirements
♻️ Waste Treatment Methods
Consult state, local or national regulations to ensure proper disposal.
Transportation & Shipping Information
UN numbers, shipping names, transport classes, and regulatory transport requirements
🏷️ UN Number
UN2811
📦 Proper Shipping Name
Toxic solids, organic, n.o.s. (4,4'-Methylenebis(phenyl isocyanate))
⚠️ Transport Hazard Class
6.1
📋 Packing Group
III
🚛 ADR Transport Precautions
Warning: Toxic substances F-A,S-Ã A
🚢 IMDG Maritime Transport Precautions
Warning: Toxic substances F-A,S-Ã A
✈️ IATA Air Transport Precautions
Warning: Toxic substances F-A,S-Ã A
Regulatory Information & Compliance
Chemical regulations, safety assessments, and regulatory compliance status
📋 Regulatory Summary
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS).
❌ Chemical Safety Assessment
No chemical safety assessment has been performed for this substance.
ℹ️ Additional Regulatory Information
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory and on the Canadian Domestic Substances List (DSL).
Chemical Safety FAQ & Common Questions
Most frequently asked questions about safety, handling, storage, and regulatory compliance
What is the hazard signal word for 4,4'-Methylenebis(phenyl isocyanate)?
The signal word for this substance is "danger".
What is 4,4'-Methylenebis(phenyl isocyanate) used for?
SU24 Scientific research and development
What are the hazard statements for 4,4'-Methylenebis(phenyl isocyanate)?
This substance has 8 hazard statements: H330: Fatal if inhaled. H315: Causes skin irritation. H319: Causes serious eye irritation. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317: May cause an allergic skin reaction. H351: Suspected of causing cancer. H335: May cause respiratory irritation. H373: May cause damage to the lung, the blood and the immune system through prolonged or repeated exposure. Route of exposure: Inhalation, Dermal.
What is the melting point of 4,4'-Methylenebis(phenyl isocyanate)?
The melting point is 41-44 ℃ (106-111 ºF) and the boiling point is 194 ℃ (381 ºF).