NextSDS Logo
Safety Data Sheet EN

4,4'-Diaminodiphenylmethane

CAS 101-77-9
EC 202-974-4

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report.

Get Free Audit
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
4,4'-Diaminodiphenylmethane
Product Code
A15645

Regulatory Identifiers

CAS Number
101-77-9 Check regulations →
EC Number
202-974-4 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar logo

Alfa Aesar

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Emergency Contacts

Alfa Aesar

800-343-0660

Monday-Friday, 8am-7pm EST

Carechem 24

(866) 928-0789

After normal business hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Muta. Cat. 2 H341
Carc. Cat. 1A H350
STOT SE Cat. 1 H370
STOT RE Cat. 2 H373
Acute Tox. Cat. 4 H302
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to the kidneys, the liver and the digestive system. Route of exposure: Oral, Inhalative and Dermal.
H373 May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral, Inhalative, Dermal.

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P307 + P311 IF exposed: Call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report

Free Audit
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterization: Substances

Chemical Name CAS Number Concentration Hazardous
4,4'-Diaminodiphenylmethane EC: 202-974-4 101-77-9 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Seek medical treatment.

Immediate Medical Attention

Seek immediate medical advice.

Medical Treatment

Seek medical treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Specific hazards

If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide, Nitrogen oxides (NOx)

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental

Do not allow material to be released to the environment without proper governmental permits.

Cleanup methods

Dispose of contaminated material as waste according to section 13.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly sealed. Open and handle container with care.

Storage

Store in cool, dry place in tightly closed containers.

Fire prevention

No information known.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Material of gloves: Nitrile rubber, NBR. Penetration time of glove material (in minutes): 480. Glove thickness: 0.4 mm.

Eyes

Safety glasses

Respiratory

Use suitable respirator when high concentrations are present. Recommended filter device for short term use: Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Fat
---
Voc Content
---
Density
1.15 g/cm³ (9.597 lbs/gal)
Bulk Density
---
Form
Solid
Appearance
Solid, Brown
Relative Evaporation Rate
---
Colour
Brown
Properties Status
---
Solidification Point
---
State Under Standard Conditions
---
Molecular Weight
---
Lower Explosive Limit
Not determined
Ph
Not applicable.
Boiling Point
398-399 °C (748-750 °F)
Auto Ignition Temperature
Not determined
Colour Intensity
---
Freezing Point
---
Physical State Data
solid
Partition Coefficient
Not determined.
Metal Corrosion
---
Odor
Not determined
Kinematic Viscosity
Not applicable.
Upper Explosive Limit
Not determined
Flammability
Not determined.
Vapor Pressure
Not applicable.
Physical State
Solid
Odor Threshold
Not determined.
Melting Point
92-93 °C (198-199 °F)
Evaporation Rate
Not applicable.
Solubility
Not determined
Decomposition Temperature
Not determined
Softening Point
---
Explosive Limits
---
Vapor Density
Not applicable.
Flash Point
221 °C (430 °F)
Relative Density
Not determined.
Cloud Point
---
Solubility In Water
Not determined
Dynamic Viscosity
Not applicable.
Crystallisation Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No information known.

Hazardous reactions

Reacts with strong oxidizing agents

Avoid

No further relevant information available.

Incompatible

Oxidizing agents

Decomposition

Carbon monoxide and carbon dioxide, Nitrogen oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2651
Shipping Name
4,4'-Diaminodiphenyl methane
Transport Class
6.1
Packing Group
III
ADR

Warning: Toxic substances

IMDG

Warning: Toxic substances

IATA

Warning: Toxic substances

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 4,4'-Diaminodiphenylmethane?

The signal word is danger.

What is the physical form of 4,4'-Diaminodiphenylmethane?

4,4'-Diaminodiphenylmethane is a solid appearing as solid, brown with brown color. It has not determined odor.

What is the solubility of 4,4'-Diaminodiphenylmethane?

Not determined

What is 4,4'-Diaminodiphenylmethane used for?

SU24 Scientific research and development

What are the hazard statements for 4,4'-Diaminodiphenylmethane?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed.
  • H317: May cause an allergic skin reaction.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer.
  • H370: Causes damage to the kidneys, the liver and the digestive system. Route of exposure: Oral, Inhalative and Dermal.
  • H373: May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral, Inhalative, Dermal.

What is the melting point of 4,4'-Diaminodiphenylmethane?

The melting point is 92-93 °C (198-199 °F) and the boiling point is 398-399 °C (748-750 °F).