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Safety Data Sheet EN

4,4'-Diaminodiphenylmethane

CAS 101-77-9
EC 202-974-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
4,4'-Diaminodiphenylmethane
Product Code
A15645
Chemical Name
4,4'-Diaminodiphenylmethane

Regulatory Identifiers

CAS Number
101-77-9 Check regulations →
EC Number
202-974-4 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar Thermo Fisher Scientific Chemicals, Inc. logo

Alfa Aesar Thermo Fisher Scientific Chemicals, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

800-343-0660

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

During normal business hours (Monday-Friday, 8am-7pm EST)

Carechem 24

(866) 928-0789

After normal business hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Muta. Cat. 2 H341
Carc. Cat. 1A H350
STOT SE Cat. 1 H370
STOT RE Cat. 2 H373
Acute Tox. Cat. 4 H302
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to the kidneys, the liver and the digestive system. Route of exposure: Oral, Inhalative and Dermal.
H373 May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral, Inhalative, Dermal.

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterization: Substances

Chemical Name CAS Number Concentration Hazardous
4,4'-Diaminodiphenylmethane EC: 202-974-4 101-77-9 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm.

Skin contact

Immediately wash with water and soap and rinse thoroughly.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Seek medical treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Material of gloves Nitrile rubber, NBR. Penetration time of glove material (in minutes) 480. Glove thickness 0.4 mm.

Eyes

Safety glasses.

Respiratory

Use suitable respirator when high concentrations are present. Recommended filter device for short term use: Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Not determined
Colour
Brown
Colour Intensity
---
Form
Solid
Odor
Not determined
Odor Threshold
Not determined.
Ph
Not applicable.
Melting Point
92-93 ℃ (198-199 ºF)
Boiling Point
398-399 ℃ (748-750'°F)
Flash Point
221 °C (430 °F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Vapor Pressure
Not applicable.
Vapor Density
Not applicable.
Relative Density
Not determined.
Bulk Density
---
Density
1.15 g/cm3 (9.597 lbs/gal)
Flammability
Not determined.
Upper Explosive Limit
Not determined
Lower Explosive Limit
Not determined
Explosive Limits
---
Auto Ignition Temperature
Not determined.
Decomposition Temperature
Not determined
Solubility
---
Partition Coefficient
Not determined.
Solubility In Water
Not determined
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not applicable.
Kinematic Viscosity
Not applicable.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2651
Shipping Name
4,4'-Diaminodiphenyl methane
Transport Class
6.1
Packing Group
III
ADR

Warning: Toxic substances

IMDG

Special marking with the symbol (fish and tree).

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 4,4'-Diaminodiphenylmethane?

The signal word is danger.

What is the physical form of 4,4'-Diaminodiphenylmethane?

4,4'-Diaminodiphenylmethane is a solid appearing as not determined with brown color. It has not determined odor.

What is 4,4'-Diaminodiphenylmethane used for?

SU24 Scientific research and development

What are the hazard statements for 4,4'-Diaminodiphenylmethane?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed.
  • H317: May cause an allergic skin reaction.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer.
  • H370: Causes damage to the kidneys, the liver and the digestive system. Route of exposure: Oral, Inhalative and Dermal.
  • H373: May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral, Inhalative, Dermal.

What is the melting point of 4,4'-Diaminodiphenylmethane?

The melting point is 92-93 ℃ (198-199 ºF) and the boiling point is 398-399 ℃ (748-750'°F).

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