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Safety Data Sheet EN

Hempel's Antifouling Globic 9000 78952

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hempel's Antifouling Globic 9000 78952
Product Form
antifouling paint self polishing
Product Code
7895251110, 00138780

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial applications, Professional applications, Used by spraying.

Manufacturers & Suppliers

H

HEMPEL A/S

Lundtoftegårdsvej 91 DK-2800 Kgs. Lyngby Denmark

Emergency Contacts

HEMPEL A/S

+45 45 93 38 00

08.00 - 17.00

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT RE Cat. 2 H373
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H302 + H332 Harmful if swallowed or if inhaled.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Do not breathe vapor or spray.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P338 IF IN EYES: Remove contact lenses, if present and easy to do. Continue rinsing.
P351 Rinse cautiously with water for several minutes.
P391 Collect spillage.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
copper (I) oxide EC: 215-270-7 1317-39-1 25 - 50% Yes
xylene EC: 215-535-7 1330-20-7 10 - 20% Yes
zinc oxide EC: 215-222-5 1314-13-2 5 - 10% Yes
white spirit EC: 265-191-7 64742-88-7 5 - 10% Yes
copper pyrithione EC: 238-984-0 14915-37-8 1 - 3% Yes
ethylbenzene EC: 202-849-4 100-41-4 1 - 3% Yes
cupric oxide EC: 215-269-1 1317-38-0 1 - 3% Yes
toluene EC: 203-625-9 108-88-3 0.3% Yes

Active substances: copper (I) oxide (39.8 % by weight), copper pyrithione (2.8 % by weight)

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air and keep at rest in a position comfortable for breathing. Give nothing by mouth. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately.

Skin contact

Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove contaminated clothing and shoes.

Symptoms: Adverse symptoms may include the following: pain or irritation redness blistering may occur

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention/advice.

Symptoms: Adverse symptoms may include the following: pain watering redness

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-enter the mouth and throat.

Symptoms: Adverse symptoms may include the following: stomach pains

Immediate Medical Attention

If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate treatment (first aid). Seek immediate medical attention/advice for eye contact. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

alcohol resistant foam, CO₂, powders, water spray.

Unsuitable media

waterjet.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Cool closed containers exposed to fire with water.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.

Cleanup methods

Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment.

Materials: non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed. Always keep in containers made from the same material as the original one. Appropriate personal protective equipment: see Section 8.

Storage

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Keep out of the reach of children. Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

Hygiene

Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed.

Fire prevention

The product should be used only in areas from which all naked lights and other sources of ignition have been excluded. No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the workstation location.

Hands

Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. The quality of the chemical-resistant protective gloves must be chosen as a function of the specific workplace concentrations and quantity of hazardous substances. Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the appropriate type. Below listed glove(s) should be regarded as generic advice: Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton® May be used: nitrile rubber (>0.3 mm) Short term exposure: neoprene rubber (>0.1 mm), butyl rubber (>0.5 mm), natural rubber (latex) (>0.4 mm), polyvinyl chloride (PVC), nitrile rubber (>0.1 mm), butyl rubber (>0.3 mm)

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Respiratory

When the product is applied by spraying and for continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or compressed air or a full face, powered air purifying filter. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If working areas have insufficient ventilation: When the product is applied by means that will not generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle filter of type P. (EN140) Be sure to use an approved/certified respirator or equivalent.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved handling this product. Wear suitable protective clothing. Always wear protective clothing when spraying. Chemical-resistant apron.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Evaporation Rate
Testing not relevant or not possible due to nature of the product.
Appearance
---
Partition Coefficient
Testing not relevant or not possible due to nature of the product.
Bulk Density
---
Flash Point
25°C (77°F)
State Under Standard Conditions
---
Metal Corrosion
---
Melting Point
Testing not relevant or not possible due to nature of the product.
Upper Explosive Limit
---
Ph
Testing not relevant or not possible due to nature of the product.
Flammability
Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and heat.
Solubility
---
Crystallisation Point
---
Lower Explosive Limit
---
Freezing Point
Testing not relevant or not possible due to nature of the product.
Solubility In Water
---
Auto Ignition Temperature
>220 °C
Colour Intensity
---
Properties Status
---
Vapor Pressure
6.7 mm Hg
Physical State Data
liquid
Cloud Point
---
Solubility In Fat
---
Solidification Point
---
Explosive Limits
---
Softening Point
---
Odor Threshold
---
Molecular Weight
---
Vapor Density
Not available.
Form
---
Dynamic Viscosity
Testing not relevant or not possible due to nature of the product.
Odor
Solvent-like
Voc Content
374.1 g/l
Relative Evaporation Rate
---
Density
1.93 g/cm³
Colour
Brown.
Decomposition Temperature
Testing not relevant or not possible due to nature of the product.
Relative Density
1.93 g/cm3
Kinematic Viscosity
Testing not relevant or not possible due to nature of the product.
Boiling Point
Testing not relevant or not possible due to nature of the product.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible

Highly reactive or incompatible with the following materials: oxidizing materials. Reactive or incompatible with the following materials: reducing materials.

Decomposition

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed: Decomposition products may include the following materials: carbon oxides nitrogen oxides sulfur oxides metal oxide/oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Dispose of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof container.

Disposal

Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable regulations.

Waste Codes

08 01 11* EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2929
Shipping Name
TOXIC LIQUID FLAMMABLE, ORGANIC, N.O.S. (copper pyrithione, xylene)
Transport Class
6.1 3
Packing Group
II
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hempel's Antifouling Globic 9000 78952?

The signal word is danger.

What is the physical form of Hempel's Antifouling Globic 9000 78952?

Hempel's Antifouling Globic 9000 78952 is a liquid. with brown. color. It has solvent-like odor.

What is Hempel's Antifouling Globic 9000 78952 used for?

Industrial applications, Professional applications, Used by spraying.

What are the hazard statements for Hempel's Antifouling Globic 9000 78952?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302 + H332: Harmful if swallowed or if inhaled.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H373: May cause damage to organs through prolonged or repeated exposure.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Hempel's Antifouling Globic 9000 78952?

The melting point is Testing not relevant or not possible due to nature of the product. and the boiling point is Testing not relevant or not possible due to nature of the product..