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Safety Data Sheet EN

LEAD-ACID BATTERIES (GENERIC)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LEAD-ACID BATTERIES (GENERIC)
Product Code
6669600, 6673865, 7304126, 7306047, 7433918, 7288629, 7223985, 7159404, EK131 (7405262), EB708 (103496801cc)

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

E

Exide Technologies SAS

manufacturer

5 Allée des Pierres Mayettes, 92636 Gennevilliers, France

+33 141 21 23 00

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Composition and Information on the main Ingredients

Chemical Name CAS Number Concentration Hazardous
Lead Grid (metallic lead, lead alloys with possible traces of additives) 7439-92-1 32% Yes
Active Mass (Battery Oxide, inorganic lead compounds) --- 32% Yes
Lead Monoxide 1317-36-6 0.1% Yes
Electrolyte (diluted sulphuric acid with additives) --- 29% No
Plastic Container / Plastic Parts --- 7% No

Dry Batteries/dry cells contain more than 0.1 % of Lead Monoxide. Lead Monoxide (CAS Nr.: 1317-38-8) is listed as a substance of very high concern under EU REACH Regulation. Once the batteries / cells are filled with electrolyte all Lead Monoxide is transformed and the presence of Lead Monoxide has ended.

Notes

Contents may vary due to performance data of the battery/cell. Composition of active mass depends on the state of charge. Density of the electrolyte varies in accordance to the state of charge. Composition of the plastic container may vary due to different customer requirements.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

inhale fresh air

Skin contact

Electrolyte: rinse with water, remove and wash wetted clothing. Lead compounds: clean with water and soap.

Eye contact

rinse under running water for minimum 15 minutes

Ingestion

drink lot of water immediately, don't induce vomiting

Immediate Medical Attention

Seek advice of a medical doctor

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2 is the most effective firefighting agent. Water, foam and dry powder are suitable agents as well. Use of dry powder may cause collateral damages.

Unsuitable media

Water, if the battery voltage is above 120 V

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not allow penetration of electrolyte into the sewage system, into earth or water bodies.

Cleanup methods

use a bonding agent (sand, lime, sodium carbonate) for neutralisation

Materials: sand, lime, sodium carbonate

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Store under a roof in cool ambient temperature range. Batteries should be stored in an upright position. This will help prevent short circuits and damage to the batteries.

Storage

Store under a roof in cool ambient temperature range. For fully charged lead-acid batteries this range is from -40 up to +60°C. If batteries have the possibility to remain discharged in cold conditions, a correction to the lower temperature limit is recommended to prevent freezing: -30°C at 75% state of charge, -20°C at 50% state of charge, and -10°C at 25% state of charge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear protective gloves

Eyes

eye/face protection

Skin/Body

protective clothing

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Kinematic Viscosity
---
Properties Status
---
Voc Content
---
Vapor Density
---
Softening Point
---
Melting Point
---
Lower Explosive Limit
---
Vapor Pressure
N.A.
Solubility In Fat
---
Flash Point
---
Odor Threshold
---
Solubility In Water
very low
Form
solid
Flammability
---
Metal Corrosion
---
Upper Explosive Limit
---
State Under Standard Conditions
---
Solubility
Lead and Lead compounds used in Lead-Acid batteries are poorly soluble in water, Lead can be dissolved in an acidic or alkaline environment only.
Explosive Limits
---
Dynamic Viscosity
---
Crystallisation Point
---
Bulk Density
---
Odor
odourless
Freezing Point
---
Solidification Point
327 °C
Cloud Point
---
Appearance
liquid, colourless, odourless
Evaporation Rate
---
Colour
grey
Colour Intensity
---
Physical State Data
solid
Decomposition Temperature
---
Molecular Weight
---
Relative Evaporation Rate
---
Auto Ignition Temperature
---
Ph
---
Relative Density
---
Density
11.35 g/cm³
Boiling Point
1740 °C
Physical State
solid
Partition Coefficient
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Reactivity

Reacts with metals, producing hydrogen. Vigorous reactions on contact with sodium hydroxide and alkalis.

Hazardous reactions

Vigorous reactions on contact with sodium hydroxide and alkalis.

Incompatible

organic materials such as cardboard, wood, textiles; metals; sodium hydroxide and alkalis.

Decomposition

hydrogen (produced by reaction with metals)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Electrolyte (diluted sulphuric acid)⁶

In order to avoid damage to the sewage system, the acid has to be neutralised by means of lime or sodium carbonate before disposal. Ecological damage is possible by change of pH. The electrolyte solution reacts with water and organic substances, causing damage to flora and fauna. The electrolyte may also contain soluble components of lead that can be toxic to aquatic environments

The electrolyte (diluted sulphuric acid) poses risks to the environment due to pH changes, reactivity with water and organic matter, and potential toxicity from soluble lead components.

12.2 Lead and Lead compounds⁷

Lead and Lead compounds are hardly soluble in water. Lead can be dissolved in an acidic or alkaline environment. Chemical and physical treatment is required for elimination from water. Waste water containing lead must not be disposed of in untreated condition.

Lead and lead compounds exhibit low water solubility but can dissolve in acidic or alkaline environments. Chemical and physical treatment is necessary for removal from wastewater.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Processed at battery recycling facilities. All components of a spent Lead-Acid battery are recycled or re-processed.

Disposal

Spent Lead-Acid batteries are collected separately from other waste streams and processed at battery recycling facilities.

Waste Codes

160601* Spent Lead-Acid batteries EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2794
Shipping Name
BATTERIES, WET, FILLED WITH ACID
Transport Class
8
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Lead-Acid batteries must be marked with a crossed out dust bin, chemical symbol for lead, and ISO return/recycling symbol in accordance with EU Battery Directive and Regulation. Hazard labels (No smoking, no naked flames, no sparks, Shield eyes, Keep away from children's reach, Corrosive, Note operating instructions, Explosive gas) are required.

Chemical Safety Assessment Not performed

Labelling might vary due to application and dimension of the Battery. The manufacturer, respectively the importer of the batteries shall be responsible for placing the symbols. www.exidegroup.com

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LEAD-ACID BATTERIES (GENERIC)?

The signal word is no signal word.

What is the physical form of LEAD-ACID BATTERIES (GENERIC)?

LEAD-ACID BATTERIES (GENERIC) is a solid appearing as liquid, colourless, odourless with grey color. It has odourless odor.

What is the solubility of LEAD-ACID BATTERIES (GENERIC)?

Lead and Lead compounds used in Lead-Acid batteries are poorly soluble in water, Lead can be dissolved in an acidic or alkaline environment only.